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排序方式: 共有158条查询结果,搜索用时 31 毫秒
31.
Sarah Gilbert Leonid Danyushevsky Philip Robinson Cora Wohlgemuth‐Ueberwasser Norman Pearson Dany Savard Marc Norman Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64
A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs. 相似文献
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34.
Sergey Konovalov Anatoliy Samodurov Temel Oguz Leonid Ivanov 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):273
New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σt16.2) and anoxic layers (σt16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σt16.2±0.2 kg m−3. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σt16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate. 相似文献
35.
On the basis of our multiwavelength observations made with the one-dimensional RATAN-600 radio telescope, we study the inversion
of the circular polarization in the solar microwave emission at different frequencies. The inversion is detected in the emission
of flare-producing active regions (FPARs) at various stages of their development, starting from the pre-flare stage. During
the latest 23rd solar cycle maximum, numerous FPARs revealed spectral inhomogeneities in their polarized microwave radiation
(Bogod and Tokhchukova, 2003, Astron. Lett.
29, 263). Here, we discuss a particular case of such inhomogeneities, the frequency-dependent double inversion of the sign of
circular polarization, which probably reflects some essential processes in FPARs. We consider several mechanisms for the double
inversion: linear interaction of waves in the region of a quasitransverse magnetic field, the propagation of waves through
a region of zero magnetic field, the scattering of radio waves on waves of high-frequency plasma turbulence, the influence
of the current fibrils on the propagation of the radio emission, and the magnetic “dips,” in which the direction of magnetic
field lines changes the sign relative to the observer. All of them have shortcomings, but the last mechanism explains the
observations the best. 相似文献
36.
Leonid V. Zamana 《中国地质》2010,37(3):607-613
本文通过对在外贝加尔大骨节病区水文地球化学研究结果表明,该地区天然水呈现出高浓度的磷(高达3.5 me/L),同时,锰、硅、铅等元素也呈现出高浓度的地球化学特征.分析水文地球化学数据,认为大骨节病可能与生物地球化学性质的多种因素有关系.进一步研究大骨节病的成因机制需要新的可靠的环境地球化学数据. 相似文献
37.
We consider a simplified reaction mechanism from tropospheric chemistryconsisting ofsix chemical species involved in ten dynamic processes. The concentrations of all six speciesundergo temporal oscillation for some parameter values. An asymptoticapproach to reduction of the original six-variable model to a four-variable version is considered together with detailed explanation of the procedure as well as discussion of conditions under whichthe reduction is possible. The reduced system nearly quantitatively represents the oscillating behavior of thefull model and allows elucidation of its basic dynamical features. This approach also can be used to compare various small models of atmospheric chemistry, and to determine their underlying dynamic structure. The method can be systematically appliedto larger atmospheric models. 相似文献
38.
Innokenty Kantor Leonid Dubrovinsky Catherine McCammon Anastasia Kantor Sakura Pascarelli Giuliana Aquilanti Wilson Crichton Maurizio Mattesini Rajeev Ahuja Jailton Almeida Vadim Urusov 《Physics and Chemistry of Minerals》2006,33(1):35-44
Combined X-ray powder diffraction, Mössbauer, and XANES spectroscopy in situ experiments revealed the transformation of cubic (Mg0.8Fe0.2)O ferropericlase to a rhombohedrally distorted phase at 35(1) GPa and room temperature. The Mössbauer spectroscopy results show that the rhombohedral distortion does not involve magnetic ordering. Combined with data from the literature, our results imply that the cubic to rhombodedral transition occurs in (Mg,Fe)O under conditions of non-hydrostatic stress over a wide range of composition (0.2≤x Fe≤1). 相似文献
39.
Immiscible silicate liquid partition coefficients: implications for crystal-melt element partitioning and basalt petrogenesis 总被引:2,自引:1,他引:2
Ilya V. Veksler Alexander M. Dorfman Leonid V. Danyushevsky Jakob K. Jakobsen Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,152(6):685-702
This study investigates partitioning of elements between immiscible aluminosilicate and borosilicate liquids using three synthetic mixtures doped with 32 trace elements. In order to get a good spatial separation of immiscible liquids, we employed a high-temperature centrifuge. Experiments were performed at 1,050–1,150°C, 1 atm, in sealed Fe and Pt containers. Quenched products were analysed by electron microprobe and LA ICP-MS. Nernst partition coefficients (D’s) between the Fe-rich and Si-rich aluminosilicate immiscible liquids are the highest for Zn (3.3) and Fe (2.6) and the lowest for Rb and K (0.4–0.5). The plots of D values against ionic potential Z/r in all the compositions show a convex upward trend, which is typical also for element partitioning between immiscible silicate and salt melts. The results bear upon the speciation and structural position of elements in multicomponent silicate liquids. The ferrobasalt–rhyolite liquid immiscibility is observed in evolved basaltic magmas, and may play an important role in large gabbroic intrusions, such as Skaergaard, and during the generation of unusual lavas, such as ferropicrites. 相似文献
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