A 30 million year cycle in Arctic volcanism?

Arctic perimeters volcanism has pulsed to a maximum approximately every 30 million years. This periodicity is similar to that observed on a global scale.     

Evaluation of magnitudes using USSR and US (NOS) techniques

Summary WWSSN seismograms for the Caucasus earthquake of May 14, 1970, and the Alma-Ata earthquake of June 5, 1970, were scaled form _b using techniques employed by USSR (P amplitude during first 20 seconds) and USA (P amplitude during first few cycles). USSR seismograms will be used in a second phase of this study. Using both techniques, the scatter at each station form _b (SPZ) was 0.0–0.3 with half of the stations having no scatter. The scatter among all of the stations was over 1 unit. Using both techniques, the scatter at each station form _b (LPZ) was zero except for NUR on May 14. The scatter among all of the stations was 1 unit on May 14 and 0.4 on June 5. This preliminary study indicates the scaling techniques have no effect in computingm _b (SPZ) andm _b (LPZ) but the differences are more likely related to source functions, crust and upper mantle response functions, and instrumental band pass.NOS Seismology personnel were transferred to NOAA-ESL in 1971.     

Robustness of pattern scaled climate change scenarios for adaptation decision support

Pattern scaling offers the promise of exploring spatial details of the climate system response to anthropogenic climate forcings without their full simulation by state-of-the-art Global Climate Models. The circumstances in which pattern scaling methods are capable of delivering on this promise are explored by quantifying its performance in an idealized setting. Given a large ensemble that is assumed to sample the full range of variability and provide quantitative decision-relevant information, the soundness of applying the pattern scaling methodology to generate decision relevant climate scenarios is explored. Pattern scaling is not expected to reproduce its target exactly, of course, and its generic limitations have been well documented since it was first proposed. In this work, using as a particular example the quantification of the risk of heat waves in Southern Europe, it is shown that the magnitude of the error in the pattern scaled estimates can be significant enough to disqualify the use of this approach in quantitative decision-support. This suggests that future application of pattern scaling in climate science should provide decision makers not just a restatement of the assumptions made, but also evidence that the methodology is adequate for purpose in practice for the case under consideration.     

The effects of thin layer sand renourishment on tidal marsh processes: Masonboro Island, North Carolina

The objective of this study was to determine if the placement of dredged material on sediment-starved back barrier marshes in southeastern North Carolina could offset submergence without negatively affecting function. Clean sediment was placed in thickness from 0 to 10 cm, on deteriorated and non-deteriorated marsh plots. Original stem densities were greater, in non-deteriorated plots (256 stems m⁻²) compared to deteriorated sites (149 stems m⁻²). By the second growing season (after sediment additions), stem densities in the deteriorated plots (308 stems m⁻²) approached levels in the non-deteriorated plots (336 stems m⁻²). Sediment additions to, both nos-deteriorated and deteriorated plots resulted in a higher redox potential with plots receiving the most sediment exhibiting the highest E_h values. In deteriorated plots, placement of dredged material had the greatest effect on plant density, but also affected soil oxidation-reduction potential and sediment deposition (or mobility). Following sediment placement, substrate texture and composition incrementally returned to prefill conditions due to a combination of bioturbation and sedimentation. Where infaunal differences occurred, they were generally less abundant in deteriorated plots, but responses to sediment addition were variable. Sediment addition had little effect on the non-deteriorated plots, suggesting that the disposal of certain types of dredged material in marshes may be useful to mitigate the effects of marsh degradation without adversely affecting non-deteriorating marsh.     

Hydrological Modeling and Prehistoric Settlement on Santa Rosa Island,California, USA

Fresh water availability was an important variable that influenced prehistoric human settlement on California's northern Channel Islands. Previous attempts to understand settlement on the islands use watershed size as a proxy for water at canyon mouths. In semi‐arid regions, this approach has limitations because streams may lose much or all of their flow to groundwater. We developed a distributed hydrological model for Santa Rosa Island that incorporates geospatial and temporal data for climate (precipitation, solar radiation, wind speed, relative humidity, temperature), soils, vegetation, and topography to simulate the complex land‐surface‐groundwater behavior of island hydrology for hypothetical wet, dry, and median centuries. Our simulations show that water flow is greatest in drainages on the northwest and east coasts of the island. This correlates with some of the earliest and most persistent settlement on the island. During the most extreme droughts of the last 2000 years during the Medieval Climatic Anomaly (1150–600 cal BP), island populations contracted to a small number of large coastal villages. We argue that this was related in part to the greater availability of surface water at these locations. This study expands the theoretical and methodological scope of past studies that have applied hydrological simulation to archaeological investigations.     

Modifications in the solubility and precipitation behavior of various metals as a result of their interaction with sedimentary humic acid

The sedimentary humic acid or its acid-hydrolysate, consisting of various amino acids, was found effective in dissolving unusually large quantities of metals (up to 682 mg/g of organic matter) from their insoluble salts. The presence of humic acid in the reaction media which had favorable conditions for the precipitation of metals as carbonates, hydroxides or sulfides, prevented the formation of insoluble metal salts. Infrared analysis suggests that the metals added to various anionic systems and humic acid do not react with the anion. The most likely mechanism of reaction appears to be a complex formation between metals and organic matter which keeps the metal in solution.The enhanced solubility and consequent decrease in precipitation of metals under the influence of humic compounds, as evidenced in these studies should play a leading role in the accumulation of metals in sedimentary deposits.     

Mercury mobility and bioavailability in soil from contaminated area

The mobility and bioavailability of mercury in the soil from the area near a plant using elemental mercury for manufacturing thermometers, areometers, glass energy switches and other articles made of technical glass has been evaluated. Mercury has been determined by sequential extraction method and with additional thermo desorption stage to determine elemental mercury. The procedure of sequential extraction involves five subsequent stages performed with the solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH and aqua regia. The mean concentration of total mercury in soil was 147 ± 107 μg g⁻¹ dry mass (range 62–393), and the fractionation revealed that mercury was mainly bound to sulfides 56 ± 8% (range 45–66), one of the most biounavailable and immobile species of mercury in the environment. The fractions that brought lower contribution to the total mercury content were semi-mobile humic matter 22 ± 9% (range 11–34) and elemental mercury 17 ± 5% (range 8–23). The contributions brought by the highly mobile and toxic organomercury compounds were still lower 2.3 ± 2.7% (range 0.01–6.5). The lowest contributions brought the acid-soluble mercury 1.5 ± 1.3% (range 0.1–3.5) and water-soluble mercury 1.0 ± 0.3% (range 0.6–1.7). The surface layer of soil (0–20 cm) was characterized by higher mercury concentrations than that of the subsurface soil (60–80 cm), but the fractional contributions were comparable. The comparison of mercury fractionation results obtained in this study for highly polluted soils with results of fractionation of uncontaminated or moderately contaminated samples of soil and sediments had not shown significant statistical differences; however, in the last samples elemental mercury is usually present at very low concentrations. On the basis of obtained correlation coefficients it seems that elemental mercury soils from “Areometer” plant are contaminated; the main transformation is its vaporization to atmosphere and oxidation to divalent mercury, probably mainly mediated by organic matter, and next bound to humic matter and sulfides.     

Assessing PAH exposure in feral finfish from the Northwest Atlantic

Polycyclic aromatic hydrocarbon (PAH) concentrations were examined in small finfish (<30 cm) represented by capelin, sand lance, American plaice, yellowtail flounder and herring collected opportunistically in various NAFO divisions. Analyses were performed on whole fish and in a portion of the samples; concentrations in internal organs were compared to the rest of the carcass. The effect of pool size, size differences within and between species, lipid content and location were examined to interpret PAH concentrations. Measurements were carried out before the development of the Hibernia oil fields and represent baseline levels for future comparison. Limits in assessing future risk that could be due to discharges of produced water or accidental oil spills are also discussed. Increasing knowledge on the bioaccumulation of PAH, on the production of bile metabolites, the formation of DNA-adducts and of the potential toxic effects associated with PAH will lead to better ecosystem management and protection for future generations.