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61.
The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H2O2 and NH3 in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.  相似文献   
62.
When fine particles are involved, cohesive properties of sediment can result in flocculation and significantly complicate sediment process studies. We combine data from field observations and state-of-the-art modeling to investigate and predict flocculation processes within a hypertidal estuary. The study site is the Welsh Channel located at the entrance of the Dee Estuary in Liverpool Bay. Field data consist of measurements from a fixed site deployment during 12–22 February 2008. Grain size, suspended sediment volume concentration, and current velocity were obtained hourly from moored instruments at 1.5 m above bed. Near-bottom water samples taken every hour from a research vessel are used to convert volume concentrations to mass concentrations for the moored measurements. We use the hydrodynamic model Proudman Oceanographic Laboratory Coastal Ocean Modelling System (POLCOMS) coupled with the turbulence model General Ocean Turbulence Model (GOTM) and a sediment module to obtain three-dimensional distributions of suspended particulate matter (SPM). Flocculation is identified by changes in grain size. Small flocs were found during flood and ebb periods—and correlate with strong currents—due to breakup, while coarse flocs were present during slack waters because of aggregation. A fractal number of 2.4 is found for the study site. Turbulent stresses and particle settling velocities are estimated and are found to be related via an exponential function. The result is a simple semiempirical formulation for the fall velocity of the particles solely depending on turbulent stresses. The formula is implemented in the full three-dimensional model to represent changes in particle size due to flocculation processes. Predictions from the model are in agreement with observations for both settling velocity and SPM. The SPM fortnight variability was reproduced by the model and the concentration peaks are almost in phase with those from field data.  相似文献   
63.
A method is presented for characterizing the spatial variability of water infiltration and soil hydraulic properties at the transect and field scales. The method involves monitoring a set of 10 Beerkan runs distributed over a 1-m length of soil, and running BEST (Beerkan estimation of soil transfer parameters) methods to derive hydraulic parameters. The Beerkan multi-runs (BMR) method provides a significant amount of data at the transect scale, allowing the determination of correlations between water infiltration variables and hydraulic parameters, and the detection of specific runs affected by preferential flow or water repellence. The realization of several BMRs at several transects on the same site allows comparison of the variation between locations (spatial variability at the field scale) and at the transect scale (spatial variability at the metre scale), using analysis of variance. From the results, we determined the spatial variability of water infiltration and hydraulic parameters as well as its characteristic scale (transect versus field).  相似文献   
64.
This study investigates the possible correspondence between catchment structure, as represented by perceptual hydrological models developed from fieldwork investigations, and mathematical model structures, selected on the basis of reproducing observed catchment hydrographs. Three Luxembourgish headwater catchments are considered, where previous fieldwork suggested distinct flow‐generating mechanisms and hydrological dynamics. A set of lumped conceptual model structures are hypothesized and implemented using the SUPERFLEX framework. Following parameter calibration, the model performance is examined in terms of predictive accuracy, quantification of uncertainty, and the ability to reproduce the flow–duration curve signature. Our key research question is whether differences in the performance of the conceptual model structures can be interpreted based on the dominant catchment processes suggested from fieldwork investigations. For example, we propose that the permeable bedrock and the presence of multiple aquifers in the Huewelerbach catchment may explain the superior performance of model structures with storage elements connected in parallel. Conversely, model structures with serial connections perform better in the Weierbach and Wollefsbach catchments, which are characterized by impermeable bedrock and dominated by lateral flow. The presence of threshold dynamics in the Weierbach and Wollefsbach catchments may favour nonlinear models, while the smoother dynamics of the larger Huewelerbach catchment were suitably reproduced by linear models. It is also shown how hydrologically distinct processes can be effectively described by the same mathematical model components. Major research questions are reviewed, including the correspondence between hydrological processes at different levels of scale and how best to synthesize the experimentalist's and modeller's perspectives. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
65.
66.
Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).  相似文献   
67.
Based upon a re-interpretation of previous data and a new field campaign, a structural evolution is proposed for the early history of Piton de la Fournaise volcano from 500,000 to 50,000 years. Conceptually, it is shown that the formation of a caldera in which lava flows are contained inside the caldera depression, gives time for erosion to excavate deep canyons on the external slopes of the volcano, for example, the Rivière des Remparts, the Rivière Langevin and the Rivière de l'Est canyons on Piton de la Fournaise volcano. These canyons are infilled when lavas, filling the caldera and overflowing its rim, are able again to flow on the external slopes of the volcano. In the past, this excavating/infilling process has occurred twice following the formation of the Rivière des Remparts and Morne Langevin calderas. The formation of the third caldera, the Plaine des Sables caldera, was followed by the excavation of the current canyons. In addition to this process, two large landslides have been documented in the field. The first, which happened about 300,000 years ago, is apparently the first episode of the break up of Piton de la Fournaise volcano, predating the formation of the four large calderas. The second landslide, which occurred 150,000 years ago and is considered to be less extensive, has carried away the entire southern flank of the Rivière des Remparts caldera.  相似文献   
68.
The biological origin of organic matter in the oldest siliceous sediments (cherts) is still debated. To address this issue, the insoluble organic matter (kerogen) was isolated from a chert of the Warrawoona group. The chemical structure of the kerogen was investigated through a combination of analytical techniques including solid-state 13C nuclear magnetic resonance and pyrolysis. Although dominated by aromatic hydrocarbons, the pyrolysate comprises a homologous series of long chain aliphatic hydrocarbons characterized by odd-over-even carbon number predominance. This distribution is only consistent with a biological origin. As kerogen must be contemporaneous of the solidification of the chert, this observation should be regarded as an evidence for the presence of life on Earth, 3.5 By ago.  相似文献   
69.
Abstract

This paper aims at revisiting the use of non-dimensional representations for catchment change and model robustness analysis. As well as being helpful for catchment classification according to hydroclimatic conditions, the Turc-Budyko representation enables visualization of temporal changes in these conditions and/or modification of the hydrological behaviour of the catchment. This brings a new perspective to hydrological analysis, different from the classical time series plots, which helps when interpreting catchment functioning with respect to hydroclimatic constraints. These tools do not require statistical analyses of observed series and are therefore very simple to implement. Four case studies are considered here to illustrate the use of the Q/P = f(P/Ep) graph. When combined with the inter-annual Turc-Mezentsev formula, this visual framework enables anticipation of potential difficulties for models based on the same hypotheses, solely using the analysis of observed data.  相似文献   
70.
In this study, the GLUE methodology is applied to establish the sensitivity of flood inundation predictions to uncertainty of the upstream boundary condition and bridges within the modelled region. An understanding of such uncertainties is essential to improve flood forecasting and floodplain mapping. The model has been evaluated on a large data set. This paper shows uncertainty of the upstream boundary can have significant impact on the model results, exceeding the importance of model parameter uncertainty in some areas. However, this depends on the hydraulic conditions in the reach e.g. internal boundary conditions and, for example, the amount of backwater within the modelled region. The type of bridge implementation can have local effects, which is strongly influenced by the bridge geometry (in this case the area of the culvert). However, the type of bridge will not merely influence the model performance within the region of the structure, but also other evaluation criteria such as the travel time. This also highlights the difficulties in establishing which parameters have to be more closely examined in order to achieve better fits. In this study no parameter set or model implementation that fulfils all evaluation criteria could be established. We propose four different approaches to this problem: closer investigation of anomalies; introduction of local parameters; increasing the size of acceptable error bounds; and resorting to local model evaluation. Moreover, we show that it can be advantageous to decouple the classification into behavioural and non-behavioural model data/parameter sets from the calculation of uncertainty bounds.  相似文献   
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