Simulations of accidental coal immersion

Coal is currently becoming an increasingly interesting fossil energy resource and that is the reason why its maritime transport, and hence the risk of collier accidents, increase. In this work, the environmental impact of an accidental coal immersion at sea is studied: the physicochemical effects are estimated using innovative experimental setups – a laboratory seawater canal called “polludrome” is used to evaluate the behaviour of coal particles submitted to a seawater flow, and a specifically designed tub is used to study the physicochemical consequences induced when coal is introduced into continuously renewed seawater. When coal is introduced into seawater, the most easily visible consequences are physical: fine coal particles reduce the daylight penetration up to 100% and move along with the flow, and coal chunks accumulate on the floor. Chemical effects are also measured: humic matters are dissolved from coal into seawater (up to 2 mg L⁻¹), but no release of polycyclic aromatic hydrocarbons is evidenced. Some inorganic compounds are dissolved, among which manganese, whose concentrations can reach 1 μg L⁻¹. Fortunately, the results show that the environmental impact of this type of accident would remain limited.     

High‐Mg# Olivine,Clinopyroxene and Orthopyroxene Reference Materials for In Situ Oxygen Isotope Determination

Secondary ion mass spectrometry (SIMS) requires matrix‐matched reference materials to calibrate mass fractionation during oxygen isotope measurement. Over one thousand SIMS oxygen isotope measurements were conducted on eleven natural mineral samples (five olivines, three clinopyroxenes and three orthopyroxenes) in nineteen sessions using CAMECA IMS 1280 SIMS instruments to evaluate their potential as SIMS reference materials. The obtained results reveal oxygen isotope homogeneity of these samples. No matrix effect was measured for the same variety of mineral samples with limited Mg‐number variations (89.6–94.2, 90–91.9 and 90.1–92.1 for olivine, clinopyroxene and orthopyroxene, respectively). The recommended oxygen isotope compositions of these samples were determined using laser fluorination. These samples are therefore suitable to be used as reference materials for in situ oxygen isotope microanalysis.     

Petrogenetic implications of uranium abundances in volcanic rocks from southern Peru

The content of uranium of andesitic rocks of southern Peru varies according to the distance from the Peru-Chile trench, as has been observed for other trace elements geochemically associated with K. The highest contents found in these rocks may exceed the estimated U content of the upper crust. This enrichment may be related to a variable degree of partial melting and/or crustal contamination of the same source material.     

Geochemical morphology of the North Mid-Atlantic Ridge, 10°–24°N: Trace element-isotope complementarity

The new data presented here from a 10–24°N segment of the North Mid-Atlantic Ridge show that this segment is the most depleted of the 10–70°N ridge section. They also show the existence of: (1) a geochemical gradient from the 14°N anomaly to 17°10′N; (2) a very depleted mantle source (the lowest Sr isotopic ratios found so far in the North Atlantic); and (3) a geochemical limit located at about 17°10′N without any obvious relation with any structural feature. The 15°20′N fracture zone does not show any relationship with respect to this gradient. The basalts located north of 17°10′N have very homogeneous features, which allow their characteristics to be averaged (i.e., ⁸⁷Sr/⁸⁶Sr= 0.70238 ± 0.00004, (Nb/Zr)_N = 0.28 ± 0.1) and they are defined as normal mid-ocean ridge basalts. The basaltic glasses located south of 17°10′N present a wide spectrum of isotopic compositions and extended rare earth element patterns (from depleted to enriched). Despite this, they have a constant K/Nb of 233 ± 9 (1s_M, n = 18) whereas this ratio is 344 ± 29 north of 17°10′N. These observations illustrate the strong coherence of behaviour between K and Nb (Ta) during the petrogenic processes involved in the generation of these mid-ocean ridge basalts and also their fractionation during previous mantle processes. Possible interpretations of mixing processes are discussed and sources at the ridge segment scale are favoured. However, when looking in detail, local heterogeneities are still common and can even be traced back off-axis to 115 my.

Placed in the context of the North Atlantic Ridge from 10° to 70°N, the Sr isotopic ratios reveal the Azores superstructure (23–50°N), whereas the trace element ratios (La/Sm-Nb/Zr) trace the second-order structures (33–40°N, 42–48°N) superimposed on the superstructure. This study illustrates the complementarity of information given by certain well chosen trace element ratios on the one hand and by isotopic ratios on the other. Since there is evidence of decoupling between isotopic ratios and/or trace element ratios, it introduces the notion of complementary “chemical memory” as recorded by a given type of trace element ratio or a given type of isotopic ratio     

Evolution of organic matter indicators in response to major environmental changes: The case of a formerly cut-over peat bog (Le Russey, Jura Mountains, France)

To assess whether the biochemical characteristics of peat can provide clues for past ecosystem changes or not, a study was carried out combining elemental analysis, micro-morphological counts and neutral monosaccharide determination of peat organic matter (OM) and the dominant living plants from a formerly cut-over peat bog in the Jura Mountains. Peat profiles (up to 50 cm depth) from two distinctive zones (bare peat, FRA and a regenerating stage, FRC) were compared with the reference profile (FRD) taken from an unexploited area of the bog. The results show contrasting OM composition along the profiles. In the upper sections of the FRD and FRC profiles, high C/N ratios and sugar contents (in the same range as in the source plants) and the large predominance of well preserved plant tissues indicate good preservation of primary biological inputs. In contrast, in peat from the FRA profile and deeper levels of the FRC profile, lower C/N ratios, lower amounts of sugars and a predominance of amorphous OM and mucilage suggest more extensive OM degradation. These features delineate a clear threshold between an uppermost “new” regenerating peat section and an “old” catotelm peat below. Nevertheless, even in the latter, the sugar contents remain relatively high (>80 mg/g) compared with other organic and mineral soils. Analysis of typical peat-forming plants and of bulk peat and fine grained fractions allowed identification of the following source indicators: xylose and arabinose for Cyperaceae; rhamnose, galactose and mannose for mosses; and ribose (and to a lesser extent, hemicellulosic glucose) possibly for microbial synthesis.     

Environmental perceptions and practices of livestock keepers on the Namaqualand Commons challenge conventional rangeland management

In South Africa, interventions in communal rangelands proposed by most agriculture-sector institutions are still dominated by the belief that communal herders have little technical skills and by the tenets of “the tragedy of the Commons”, assuming that individual livestock keepers are selfish, norm free, and aiming at maximising short-term offtake and that there is no consistent management of the commons. In this study we show that practices of a diversity of livestock keepers on the Leliefontein Commons of Namaqualand are at odds with this viewpoint: access to rangeland and its use are structured by collective norms and concerns regarding both the sharing of resources and their long-term sustainability. We also show that part of the management of the commons relies on grazing practices which involve tacit and formalised technical knowledge that can be described and modelled. Livestock keepers assess the heterogeneity of the grazing quality of the commons. They are aware of the toxicity and unpalatability of some plants, of the way this differs according to the amount ingested and the availability of other forage, and of the variations of these two factors over seasons of grazing. They classify grazing areas and decide on daily grazing routes according to a complex set of criteria. Carrying capacity of each area is not considered as a fixed parameter but rather as a variable dependant on rainfall. Seasonal movements between areas are designed accordingly. These findings offer a new perspective for research agendas on technical models and extension measures for communal rangeland management particularly in arid and semi-arid areas.     

Technosols made with various urban wastes showed contrasted performance for tree development during a 3-year experiment

Vegetation in urban areas is generally living in a stress-inducing environment. Sustaining good soil quality is crucial to improve tree development and heath in such (artificial) environment. This study investigates the dynamics of the physico-chemical properties of Technosol, and compares tree development performances in various waste mixtures. A 3-year experiment was conducted with Acer platanoïdes L. grown in three distinct constructed soils, in three replicates, in 0.480-m³ lysimeters in Angers (France). Four combinations of artefacts were studied either as “growing material” (GM) or “structural material” (SM). Three different SMs were used: (1) a mixture of fine mineral material, demolition rubble and green waste (SM-DR/GW), (2) a mixture of fine mineral material, track ballast and sewage sludge (SM-TB/SS), and (3) the SM currently used by Angers city for green space settlements (SM-CT). Waste characteristics and mixing proportions both affected tree development. Physical properties were not a limiting factor for tree development, despite a relatively low soil water reservoir due to high stone content. Moreover, the chemical properties of the materials, more particularly low water pH and CEC, led to poor tree development in SM-CT, whereas the other two SMs did not affect tree development. SM-TB/SS was the most suitable constructed soil after 3 years because it exhibited satisfactory soil nutrient contents that promoted the best tree crown quality. Waste mixtures can sustain soil functions for tree development. As for urban street tree pits that are 2–8 m³ in volume, soil water, and nutrient autonomy should satisfactorily sustain tree development.     

Apatite Reference Materials for SIMS Microanalysis of Isotopes and Trace Elements

Twelve apatite samples have been tested as secondary ion mass spectrometry (SIMS) reference materials. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis shows that the SLAP, NUAN and GR40 apatite gems are internally homogeneous, with most trace element mass fractions having 2 standard deviations (2s) ≤ 2.0%. BR2, BR5, OL2, AFG2 and AFB1, which have U > 63 μg g^-1, ²⁰⁶Pb/²⁰⁴Pb > 283, and homogeneous SIMS U-Pb data, have respective isotope dilution thermal ionisation mass spectrometry (ID-TIMS) ages of 2053.83 ± 0.21 Ma, 2040.34 ± 0.09 Ma, 868.87 ± 0.25 Ma, 478.71 ± 0.22 Ma and 473.25 ± 0.09 Ma. Minor U-Pb heterogeneity exists and accurate SIMS results require correction with the 3D Concordia-constrained common Pb composition. Among the studied samples, AFG2 and BR5 are the most homogeneous U-Pb reference materials. The SIMS sulfur isotopic compositions of eight of the apatites shows they are homogeneous, with 2s for both 10³δ³⁴S and 10³δ³³S < 0.55‰. One apatite, BR96, has Δ³³S = -0.36 ± 0.2‰. The apatite samples have ID-TIMS ⁸⁷Sr/⁸⁶Sr between 0.704214 ± 0.000030 and 0.723134 ± 0.000035.     

Reworking of intra-oceanic rocks in a deep sea basin: example from the Bou-Maiza complex (Edough massif,eastern Algeria)

Metagabbros and amphibolites exposed in the Bou-Maïza area of the Edough massif (northeast Algeria) are described in detail. Field and petro-structural observations point to the syn-sedimentary emplacement of gabbros as clasts, blocks and lenses of polymictic gabbroic breccias. Associated amphibolites display fine-scale parallel sedimentary bedding and represent mafic epiclastites, litharenites and mafic greywackes. The mafic beds and lenses are intercalated with aluminous pelitic schists of continental origin, quartzite and marble. It is concluded that all mafic rocks from this locality derive from the erosion of an oceanic plutono-volcanic complex of MORB affinity that was reworked in a block matrix mélange and emplaced as turbidites and debris flows during the Mesozoic. We propose a convergent plate margin setting for these formations connected with the subducted Calabrian branch of the Tethyan slab.