Tracing the inputs and fate of marine and terrigenous organic matter in Arctic Ocean sediments: A multivariate analysis of lipid biomarkers

An understanding of the carbon cycle within arctic sediments requires discrimination between the terrigenous and marine components of organic carbon, insight into the removal mechanisms for labile carbon during burial and appreciation of shelf-to-basin processes. Using a large data set of multiple molecular organic markers (alkanes, alkanols, sterols, saturated and unsaturated fatty acids, dicarboxylic acids), we apply (1) principal components analysis (PCA) to obtain a robust comparison of biomarker compositions in Arctic Ocean sediments, (2) geometric mean (GM) linear regression of the PCA variables to estimate the relative contributions of labile/marine and stable/terrigenous sources to each biomarker and (3) the slope of the GM regression of each biomarker with TOC to provide a novel measure of the removal rate of each biomarker relative to phytol. The PCA- and TOC-based indices generally increase together: biomarkers with very high TOC-based removal rates such as the saturated and unsaturated n-alkanoic acids generally have a high labile/marine content from PCA, while the sterols have low removal rates, but exhibit a range of labile/marine content values and the n-alkanes and n-alkanols have low values for both. A dominant feature of all PCA models examined is a progressive decrease in the autochthonous/marine biomarkers with each increase in sediment core depth, which points to a universal diagenetic alteration of organic carbon with depth in the cores. The PCA model also displays a shelf to basin trend that is non-diagenetic and implies the ongoing (centuries or more) delivery of long-chain n-alkanes, n-alcohols and n-alkanoic acids in a matrix that is pre-formed and well-preserved within the sediments. Terrigenous biomarker distributions within the PCA model suggest that atmospheric transport of plant waxes in aerosols and the water borne transport of very fine plant macerals likely have significant roles in the export of these vascular plant biomarkers to the basins. Biomarker ratios and profiles of the PCA-based labile/marine content with core depth indicate that the PCA model is more strongly influenced by the biomarker lability than the marine content, while increases in the marine content are largely responsible for the shifts in composition for near-surface core sections.     

New Development of Eastern Mediterranean Circulation based on Hydrological Observations and Current Measurements

Abstract. A number of recent studies based on hydrographic observations and modelling simulations have dealt with the major climatic shift that occurred in the deep circulation of the Eastern Mediterranean. This work presents hydrographic observations and current measurements conducted from 1997 to 1999, which reveal strong modifications in the dynamics of the upper, intermediate and deep layers, as well as an evolution of the thermohaline characteristics of the deep Aegean outflow since 1995. The reversal of the circulation in the upper layer of the north/central Ionian is worthy of note. The observations indicate a reduction of Atlantic Water in the northern Ionian with an increase on the eastern side of the basin. In the intermediate layer, the dispersal path of the Levantine Intermediate Water (LIW) is altered. Highly saline (>39.0) and well-oxygenated intermediate waters were found near the Western Cretan Arc Straits. They flow out from the Aegean, thus interrupting the traditional path of the LIW, and spread prevalently northwards into the Adriatic Sea. In the deep layer, dense waters, exiting from the Adriatic (σ_ø−29.18 kg · m⁻³), flow against the western continental margin in the Ionian Sea at a depth of between 1000–1500 m. Dense waters of Aegean origin (> 29.20 kg · m⁻³), discharged into the central region of the Eastern Mediterranean during the early stages of the transient, propagate prevalently to the east in the Levantine basin and to the west in the northern Ionian Sea. Near-bottom current measurements conducted in the Ionian Sea reveal unforeseen aspects of deep dynamics, suggesting a new configuration of the internal thermohaline conveyor belt of the Eastern Mediterranean.     

Surface water–groundwater interaction at restored streams and associated reference reaches

Stream restoration goals include improving habitat and water quality through reconstruction of morphological features found at analogous, pristine stream reaches. Enhancing hyporheic exchange may facilitate achieving these goals. Although hyporheic exchange at restoration sites has been explored in a few previous studies, comparative studies of restored versus reference or control streams are largely absent. We hypothesized that restoration cross‐vanes enhance hyporheic exchange, resulting in biogeochemical alteration of stream water chemistry in the streambed. Two streams restored using cross‐vanes to control erosion and improve habitat were compared with their associated reference reaches, which provided the basis for the restoration design. Thirteen temperature profile rods with vertically stacked sensors were installed at each site for 2 weeks. Heat tracing was used to quantify vertical flux in the streambed from the diurnal temperature fluctuations in the subsurface. Stream water and bed pore waters from mini‐piezometers were analysed for ion and nutrient chemistry. In general, mean vertical flux rates through the streambed were small throughout reference sites (?0.3 to 0.3 m/day) and at most locations at restored sites. Immediately adjacent to cross‐vanes, vertical flux rates were larger (up to 3.5 m/day). Geochemistry of pore waters shows distinct differences in the sources for the reference and restored sites. Strong downwelling zones adjacent to cross‐vanes showed high dissolved oxygen (10.75 mg/l) and geochemistry in the streambed similar to surface water. Reference sites had lower dissolved oxygen in the streambed (0.66–5.14 mg/l), and geochemical patterns suggest a mixture of discharging groundwater and surface water in the hyporheic zone. Restored sites also clearly show sulfate and nitrate reduction occurring in the streambed, which is not observed at the reference sites. The stream restoration sites studied here enhance rapid hyporheic exchange, but upwelling of groundwater has a stronger influence on streambed geochemistry at reference sites. Copyright © 2012 John Wiley & Sons, Ltd.     

Probabilistic evaluation of seismic performance of 3‐story 3D one‐ and two‐way steel moment‐frame structures

This paper presents the results of a probabilistic evaluation of the seismic performance of 3D steel moment‐frame structures. Two types of framing system are considered: one‐way frames typical of construction in the United States and two‐way frames typical of construction in Japan. For each framing system, four types of beam–column connections are considered: pre‐Northridge welded‐flange bolted‐web, post‐Northridge welded‐flange welded‐web, reduced‐beam‐section, and bolted‐flange‐plate connections. A suite of earthquake ground motions is used to compute the annual probability of exceedence (APE) for a series of drift demand levels and for member plastic‐rotation capacity. Results are compared for the different framing systems and connection details. It is found that the two‐way frames, which have a larger initial stiffness and strength than the one‐way frames for the same beam and column volumes, have a smaller APE for small drift demands for which members exhibit no or minimal yielding, but have a larger APE for large drift demands for which members exhibit large plastic rotations. However, the one‐way frames, which typically comprise a few seismic frames with large‐sized members that have relatively small rotation capacities, may have a larger APE for member failure. The probabilistic approach presented in this study may be used to determine the most appropriate frame configuration to meet an owner's performance objectives. Copyright © 2008 John Wiley & Sons, Ltd.     

Palaeogeographic,climatic and tectonic change in southeastern Australia: the Late Neogene evolution of the Murray Basin

The Murray Basin is a low-lying but extensive intracratonic depocentre in southeastern Australia, preserving an extraordinary record of Late Neogene sedimentation. New stratigraphic and sedimentologic data allow the long-term evolution of the basin to be re-evaluated and suggest a significant role for: (1) tectonism in controlling basin evolution, and (2) progressive and step-wise climatic change beginning in the early Pleistocene. Tectonic change is associated with regional uplift, occurring at approximately the same rate from the early Pliocene until the present day, and possibly associated with changing mantle circulation patterns or plate boundary processes. This uplift led to the defeat and re-routing of the Murray River, Australia’s major continental drainage system. Key to our interpretation is recognition of timing relationships between four prominent palaeogeographic features – the Loxton-Parilla Sands strandplain, the Gambier coastal plain, palaeo megalake Bungunnia and the Kanawinka Escarpment. Geomorphic and stratigraphic evidence suggest that during the Early Pliocene the ancestral Murray River was located in western Victoria, flowing south along the Douglas Depression. Relatively small amounts of regional uplift (<200 m) defeated this drainage system, dramatically changing the palaeogeography of southeastern Australia and forming Plio-Pleistocene megalake Bungunnia. At its maximum extent Lake Bungunnia covered more than 50,000 km², making it one of the largest known palaeo- or modern-lakes in an intracontinental setting. Magnetostratigraphic constraints suggest lake formation c. 2.4 Ma. The formation of Lake Bungunnia influenced the Pliocene coastal dynamics, depriving the coastline of a sediment source and changing the coastal system from a prograding strandline system to an erosional one. Erosion during this period formed the Kanawinka Escarpment, a palaeo sea-cliff and one of the most prominent and laterally extensive geomorphic features in southeastern Australia. Marine sediments c. 800 ka to c. 1.16 Ma represent the time of re-establishment of depositional coastal dynamics and of a permanent outlet for the Murray River. This age range is consistent with our best estimate of the age of the youngest Lake Bungunnia sediments and points towards an early Pleistocene age for the demise of the lake system. The youngest Lake Bungunnia sediment, present on a number of distinct terraces, suggests that progressive, step-wise climatic change played a role in the demise of the lake. However, in order for the ancestral Murray River system to have been able to breach the pre-existing tectonic dam, it is likely that tectonic change and/or temporarily enhanced discharge was also significant. This scenario indicates that the modern Murray River has only been in existence for at most 700 ka.     

New evidence of sea‐level lowstands and paleoenvironment during MIS 6 and 4 in the Cantabrian coastal karst: the Cobiheru cave (North Iberia)

The geomorphological evolution of the Cobiheru Cave shows the influence of the non‐carbonate coastal mountain ranges on coastal karst evolution, as well as the temporal distribution of the cold‐adapted fauna sites in the Cantabrian Coast. Geomorphological observation and uranium/thorium (U/Th) dating lead to the construction of an evolution model. The model comprises two episodes of cave deposition occurring at c. 60–70 and 130–150 ka, linked to cold climate conditions, global sea‐level lowstands and the erosion of alluvial fans that covered the karst. Moreover, the comparison between the Cobiheru record and some raised beaches identified in previous studies sets the beginning of the sea‐level lowering in the Cantabrian Sea during the marine isotope stages (MIS) 5–4 transition. Two palaeoenvironments are inferred based on finding Equus ferus and Elona quimperiana. A wet deciduous forest would have developed on the emerged marine terrace of the Cobiheru Cave since at least the Middle Pleistocene, and an open landscape with scarce vegetation would have been present at c. 65 ka. The erosional event identified in the Cobiheru Cave helps to understand the temporal distribution of cold‐adapted mammals located in the Asturias region. The probable sites of cold‐adapted fauna developed in caves and alluvial fans would have disappeared after 65 ka. Therefore, palaeontological and palaeoclimate research based on cold‐adapted mammals suggests the occurrence of an hiatus in the palaeontological record prior to 50 ka. Copyright © 2017 John Wiley & Sons, Ltd.     

Oil Extraction and Benefit Sharing in an Illiberal Context: The Nenets and Komi-Izhemtsi Indigenous Peoples in the Russian Arctic

ABSTRACT

How can indigenous communities in illiberal regimes benefit from oil production? This paper compares the experience of two indigenous peoples in the Russian Arctic, the Nenets and the Komi-Izhemtsi, in their quest for environmental protection and the development of benefit-sharing arrangements with Lukoil, a Russian oil company. The Nenets people, recognized by the Russian state as indigenous, are marginalized political actors who identified a route to receiving compensation for loss of land and damage to the environment as well as economic benefits under the auspices of Russian law and Lukoil’s corporate policies. In contrast, the Komi-Izhemtsi, despite indigenous status in global institutions including the United Nations and the Arctic Council, are unrecognized as indigenous domestically and initially received no compensation. Their path to benefit sharing was more challenging as they partnered with local nongovernmental organizations and global environmentalists to pressure Lukoil to sign a benefit-sharing agreement. Ultimately, the comparison illustrates how transnational partnerships can empower indigenous people to gain benefits from natural resource exploitation even in illiberal political systems.