Seal capacity estimation from subsurface pore pressures

A cap rock's capacity to seal hydrocarbons depends on its wettability and the sizes of the pore throats within the interconnected pore system that the leaking hydrocarbons must penetrate. These critical pore throat sizes are often poorly constrained in hydrocarbon exploration, partly because measurements of pore throat sizes have not been performed, and partly because pore throat measurements on a few individual samples in the cap rock may not be representative for the seal capacity of the top seal as a whole. To the contrary, the presence of formation overpressure can normally be estimated in drilled exploration targets. The presence of overpressure in reservoirs testifies to small pore throats in the cap rocks, as large pore throats will result in sufficiently high cap rock permeability to bleed off the overpressure. We suggest a stepwise procedure that enables quantification of top seal capacities of overpressured traps, based on subsurface pressure information. This procedure starts with the estimation of cap rock permeabilities, which are consistent with observed overpressure gradients across the top seals. Knowledge of burial histories is essential for these estimations. Relationships between pore throat size and permeability from laboratory experiments are then applied to estimate critical pore throat diameters in cap rocks. These critical pore throat diameters, combined with information of the physical properties of the pore fluids, are then used to calculate membrane seal capacity of cap rocks. Estimates of top seal capacity based on this procedure are rather sensitive to the vertical fluid velocity, but they are also to some extent sensitive to inaccuracies of the pore throat/permeability relationship, overpressure gradient, interfacial tensions between pore fluids, hydrocarbon density and water viscosity values. Despite these uncertainties, applications of the above‐mentioned procedure demonstrated that the mere presence of reservoir overpressures testifies to sufficient membrane seal capacity of cap rocks for most geological histories. Exempt from this statement are basins with rapid and substantial sediment compaction in the recent past.     

Current states of stress in the northern Andes as indicated by focal mechanisms of earthquakes

Systematic inversion of double couple focal mechanisms of shallow earthquakes in the northern Andes reveals relatively homogeneous patterns of crustal stress in three main regions. The first region, presently under the influence of the Caribbean plate, includes the northern segment of the Eastern Cordillera of Colombia and the western flank of the Central Cordillera (north of 4°N). It is characterized by WNW–ESE compression of dominantly reverse type that deflects to NW–SE in the Merida Andes of Venezuela, where it becomes mainly strike–slip in type. A major bend of the Eastern thrust front of the Eastern Cordillera, near its junction with the Merida Andes, coincides with a local deflection of the stress regime (SW–NE compression), suggesting local accommodation of the thrust belt to a rigid indenter in this area. The second region includes the SW Pacific coast of Colombia and Ecuador, currently under the influence of the Nazca plate. In this area, approximately E–W compression is mainly reverse in type. It deflects to WSW–ENE in the northern Andes south of 4°N, where it is accommodated by right-lateral displacement of the Romeral fault complex and the Eastern front of the northern Andes. The third, and most complex, region is the area of the triple junction between the South American, Nazca and Caribbean plates. It reveals two major stress regimes, both mainly strike–slip in type. The first regime involves SW–NE compression related to the interaction between the Nazca and Caribbean plates and the Panama micro-plate, typically accommodated in an E–W left-lateral shear zone. The second regime involves NW–SE compression, mainly related to the interaction between the Caribbean plate and the North Andes block which induces left-lateral displacement on the Uramita and Romeral faults north of 4°N.Deep seismicity (about 150–170 km) concentrates in the Bucaramanga nest and Cauca Valley areas. The inversion reveals a rather homogeneous attitude of the minimum stress axis, which dips towards the E. This extension is consistent with the present plunge of the Nazca and Caribbean slabs, suggesting that a broken slab may be torn under gravitational stresses in the Bucaramanga nest. This model is compatible with current blocking of the subduction in the western northern Andes, inhibiting the eastward displacement of slabs, which are forced to break and sink in to the asthenosphere under their own weight.     

Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

The possible escape of electron cyclotron maser radiation from hot stellar coronas through a window of transparency

The main argument against the idea that the intense radio emission observed from active regions on the Sun and flare stars is electron-cyclotron maser (ECM) radiation is that such radiation should be strongly absorbed in higher-lying layers where the condition for the cyclotron resonance at harmonics of the electron gyrofrequency is fulfilled. Cyclotron absorption lowers the efficiency of ECM radiation virtually to zero for a broad range of angles between the direction of propagation of the radiation and the magnetic field. Less severe absorption is possible only in narrow angular “windows” along (for ordinary and extraordinary waves) and perpendicular to (for ordinary waves) the magnetic field. However, the ECM radiation that is generated does not fall into these windows of transparency due to the kinematic conditions corresponding to coronal magnetic traps. We investigate the efficiency of induced scattering of ECM radiation on ions in the equilibrium plasma in the source. Under certain conditions, induced scattering leads to the formation of a condensate of ECM radiation with the direction of its wave vectors approximately along the magnetic field, enabling the escape of the radiation through windows of transparency. The most favorable conditions for this phenomenon are realized for ordinary waves. We estimate the optical depths of the sources of the ECM radiation to the scattering and the angular width of the condensate for ordinary and extraordinary waves for the cases of the flare radio emission of the star AD Leo and the sources of type I noise storms in the solar corona. In both cases, the polarization of the emergent radiation should correspond to the ordinary wave.     

Salinisation des nappes côtières : cas de la nappe nord du Sahel de Sfax,Tunisie

The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005).     

Low-order stabilized finite element for the full Biot formulation in soil mechanics at finite strain

This article presents a novel finite element formulation for the Biot equation using low-order elements. Additionally, an extra degree of freedom is introduced to treat the volumetric locking steaming from the effective response of the medium; its balance equation is also stabilized. The accuracy of the proposed formulation is demonstrated by means of numerical analyses.     

Air–sea CO2 fluxes in the north-eastern shelf of the Gulf of Cádiz (southwest Iberian Peninsula)

An intra-annual investigation of the fugacity of CO₂ (fCO₂) has been conducted in surface waters of the north-eastern shelf of the Gulf of Cádiz (SW Iberian Peninsula) in four cruises made in 2006 and 2007. Intra-annual variability of fCO₂ was assessed and is discussed in terms of mixing, temperature and biology. In the study area of the shelf, thermodynamic control over fCO₂ predominates from early May to late November, and this is opposite and similar in magnitude to the net biological effect. However, biological control over fCO₂ predominates during winter. The results suggest that surface waters in the coastal area are under-saturated with respect to atmospheric CO₂ during most of the year; therefore they represent a sink for atmospheric CO₂ between November and May (? 1.0 mmol m^? 2 day^? 1), but a weak source in June (1.3 mmol m^? 2 day^? 1). In contrast, the coastal ecosystems studied (the lower estuary of Guadalquivir Estuary and Bay of Cádiz) acted as a weak sink for atmospheric CO₂ during February (? 1.3 mmol m^? 2 day^? 1) and as a source between May and November (2.6 mmol m^? 2 day^? 1). The resulting mean annual CO₂ flux in the north-eastern shelf of the Gulf of Cádiz was ? 0.07 mol m^? 2 year^? 1 (? 0.2 mmol m^? 2 day^? 1), indicating that the area acts as a net sink on an annual basis.