Estimating Runoff Using Hydro-Geodetic Approaches

Given the continuous decline in global runoff data availability over the past decades, alternative approaches for runoff determination are gaining importance. When aiming for global scale runoff at a sufficient temporal resolution and with homogeneous accuracy, the choice to use spaceborne sensors is only a logical step. In this respect, we take water storage changes from Gravity Recovery And Climate Explorer (grace) results and water level measurements from satellite altimetry, and present a comprehensive assessment of five different approaches for river runoff estimation: hydrological balance equation, hydro-meteorological balance equation, satellite altimetry with quantile function-based stage–discharge relationships, a rudimentary instantaneous runoff–precipitation relationship, and a runoff–storage relationship that takes time lag into account. As a common property, these approaches do not rely on hydrological modeling; they are either purely data driven or make additional use of atmospheric reanalyses. Further, these methods, except runoff–precipitation ratio, use geodetic observables as one of their inputs and, therefore, they are termed hydro-geodetic approaches. The runoff prediction skill of these approaches is validated against in situ runoff and compared to hydrological model predictions. Our results show that catchment-specific methods (altimetry and runoff–storage relationship) clearly outperform the global methods (hydrological and hydro-meteorological approaches) in the six study regions we considered. The global methods have the potential to provide runoff over all landmasses, which implies gauged and ungauged basins alike, but are still limited due to inconsistencies in the global hydrological and hydro-meteorological datasets that they use.     

Identification of the principal patterns of summer moisture transport in South America and their representation by WCRP/CMIP3 global climate models

The goal of this study is to assess the ability of a set of global climate models (GCMs) to represent the main regional spatial patterns of austral summer moisture transport in South America in order to evaluate if one of the possible causes of GCMs misestimating summer precipitation in this region could be associated with an erroneous representation of these patterns. For this purpose, NCEP/NCAR reanalysis and 20 GCMs from the WCRP/CMIP3 multi-model dataset for the period 1960–1999 were considered. Extreme cases of moisture transport patterns were selected to assess their association with rainfall anomalies. Results obtained indicate that only some aspects of water vapor transport and convergence in South America as well as the associated precipitation anomalies can be reproduced adequately by GCMs. Finally, a case study is presented showing that one of the moisture transport patterns identified was observed during December 2008–February 2009.     

Process-based forward numerical ecological modeling for carbonate sedimentary basins

Nowadays, numerical modeling is a common tool used in the study of sedimentary basins, since it allows to quantify the processes simulated and to determine interactions among them. One of such programs is SIMSAFADIM-CLASTIC, a 3D forward-model process-based code to simulate the sedimentation in a marine basin at a geological time scale. It models the fluid flow, siliciclastic transport and sedimentation, and carbonate production. In this article, we present the last improvements in the carbonate production model, in particular about the usage of Generalized Lotka-Volterra equations that include logistic growth and interaction among species. Logistic growth is constrained by environmental parameters such as water depth, energy of the medium, and depositional profile. The environmental parameters are converted to factors and combined into one single environmental value to model the evolution of species. The interaction among species is quantified using the community matrix that captures the beneficial or detrimental effects of the presence of each species on the other. A theoretical example of a carbonate ramp is computed to show the interaction among carbonate and siliciclastic sediment, the effect of environmental parameters to the modeled species associations, and the interaction among these species associations. The distribution of the modeled species associations in the theoretical example presented is compared with the carbonate Oligocene-Miocene Asmari Formation in Iran and the Miocene Ragusa Platform in Italy.     

Superposition of tectonic structures leading elongated intramontane basin: the Alhabia basin (Internal Zones,Betic Cordillera)

International Journal of Earth Sciences - The relief of the Betic Cordillera was formed since the late Serravallian inducing the development of intramontane basins. The Alhabia basin, situated in...     

Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.     

Thermodynamic properties of wadsleyite with anharmonic effect

The thermodynamic properties of crystals can be routinely calculated by density functional theory calculations combining with quasi-harmonic approximation.Based on the method developed recently by Wu and Wentzcovitch(Phys Rev B 79:104304, 2009) and Wu(Phys Rev B 81:172301, 2010), we are able to further ab initio include anharmonic effect on thermodynamic properties of crystals by one additional canonical ensemble with numbers of particle, volume and temperature fixed(NVT) molecular dynamic simulations. Our study indicates that phonon–phonon interaction causes the renormalized phonon frequencies of wadsleyite decrease with temperature. This is consistent with the Raman experimental observation. The anharmonic free energy of wadsleyite is negative and its heat capacity at constant pressure can exceed the Dulong–Petit limit at high temperature. The anharmonicity still significantly affects thermodynamic properties of wadsleyite at pressure and temperature conditions correspond to the transition zone.