Geophysical exploration on the subsurface geology of La Garrotxa monogenetic volcanic field (NE Iberian Peninsula)

We applied self-potential (SP) and electrical resistivity tomography (ERT) to the exploration of the uppermost part of the substrate geology and shallow structure of La Garrotxa monogenetic volcanic field, part of the European Neogene–Quaternary volcanic province. The aim of the study was to improve knowledge of the shallowest part of the feeding system of these monogenetic volcanoes and of its relationship with the subsurface geology. This study complements previous geophysical studies carried out at a less detailed scale and aimed at identifying deeper structures, and together will constitute the basis to establish volcanic susceptibility in La Garrotxa. SP study complemented previous smaller-scale studies and targeted key areas where ERT could be conducted. The main new results include the generation of resistivity models identifying dykes and faults associated with several monogenetic cones. The combined results confirm that shallow tectonics controlling the distribution of the foci of eruptive activity in this volcanic zone mainly correspond to NNW–SSE and accessorily by NNE–SSW Neogene extensional fissures and faults and concretely show the associated magmatic intrusions. These structures coincide with the deeper ones identified in previous studies, and show that previous Alpine tectonic structures played no apparent role in controlling the loci of this volcanism. Moreover, the results obtained show that the changes in eruption dynamics occurring at different vents located at relatively short distances in this volcanic area are controlled by shallow stratigraphical, structural and hydrogeological differences underneath these monogenetic volcanoes.     

Comparison of response of moss,lichens and attic dust to geology and atmospheric pollution from copper mine

Different sampling media (moss, lichen and attic dust) were used for monitoring the distribution of 15 elements, including certain trace elements, in the vicinity of an intensively exploited copper mine in the east of the Republic of Macedonia. Moss species (Hypnum cupressiforme and Campothecium lutescens), epiphytic lichens (Hypogymnia physodes and Evernia prunastri) and attic dust were collected for comparative analysis for monitoring air pollution. In both cases (lithological and anthropogenic affected areas) for the distribution of elements, the sampling media follows the expression capabilities: attic dust > moss > lichens. Enrichment factors M/L—moss vs. lichen, for plant response to elements distribution and D/L—attic dust vs. lichen, for historical response of elements distribution were significant for Cu and Ni, which were singled out as the main markers for anthropogenic and geogenic distribution. The factor analysis highlighted geogenic (F1: Ni-Cr-Cd-Fe-Al-K-Mn-Zn) and anthropogenic (F2: As-Cu-Pb) association of elements from three types of media samples. For anthropogenic affected areas, T value and F value for Cu content were significant at p < 0.05 and higher enrichment factors were obtained for lichen, moss and attic dust media (3.8, 5.0 and 5.7, respectively). Spatial distribution for element deposition (with emphasis on Cu and Ni) is not disturbed by the significant differences in the sampling media matrix. Treated sample materials (attic dust, moss, lichen) are shown to be useful in determining an anthropogenic impact, as well as the chemical properties or geological background on orographic diverse terrain in the presence of complex geological structure.     

A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.     

Technical, financial and location criteria for the design of land application system treatment

Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain.     

Salt and nitrate exports from the sprinkler-irrigated Malfarás creek watershed (Ebro river valley,Spain) during 2010

Irrigated agriculture is a clear source of non-point pollution by salts and nitrogen species. The impact of such pollution should be quantified according to specific cases. The case of the Malfarás creek basin, a sprinkler irrigation district located in the semiarid Ebro valley in northeast Spain, has been evaluated. The main crops in the district were corn, barley and alfalfa, occupying 93 % of the irrigated area. The fate of water, salts and nutrients was evaluated by a daily water balance developed at a field scale for the natural year 2010. The yearly data of the whole set of 101 irrigated fields plus the non-irrigated area compared to the measured drainage produced a basin water balance with a low degree of error. The basin consumed 90 % of the total water input of which 68 % was used for crop evapotranspiration and the rest was lost due to non-productive uses. 16 % of the incoming water left the irrigation area as drainage water. The irrigated area was responsible for 87 % of the drainage. The average volume of drained water was 152 mm year^?1 for the whole basin area. The irrigated area drained 183 mm year^?1. The basin exported 473 kg of salt per hectare during 2010. This value was the lowest of the sprinkler irrigation areas in the Ebro valley, mainly due to the lower soil salinity. All the crops except barley received a nitrogen surplus of 10–50 % above their needs. The extra nitrogen entered the water cycle increasing the nitrate concentration in the aquifer water (150 mg L^?1) and drainage water (98 mg L^?1). In 2010 the mass of nitrogen exported by drainage was 49 kg per irrigated hectare. This value is too high for this type of irrigation system and implies that 17 % of nitrogen applied as a fertilizer was lost to drainage water. The key to decreasing the nitrogen leaching and pollution that it causes could be appropriate time-controlled fertigation along with better irrigation scheduling.     

Sandstone alterations triggered by fire-related temperatures

The aim of the study was to identify and describe changes in two different sandstone types when undergoing different environmental and extreme temperature regimes to assess the possibility of finding insolation weathering and how these sandstones would behave during and after a fire. The first step was the simulation in the laboratory of temperature regimes up to 60 °C which would correspond to extreme events that could be found in insolation cycles even in Central Europe and the second one was the temperature above 200 °C simulating in laboratory conditions the thermal regime of a potential fire situation at temperatures up to 200, 400, 600 and 800 °C. Heating the samples above 400 °C led to gradual changes in mineral composition, colour, surface roughness and physical properties reaching, eventually, total rock breakdown through spalling and granular disaggregation. The different behaviour of sandstones exposed to high temperatures is mainly caused by their different mineral composition with various ratios of minerals that are more or less chemically stable at high temperatures as well as by the differences in the porosity.     

Monitoring of heat transmission from buildings into geological environment and evaluation of soil deformation consequences in foundation engineering

In engineering geology a number of factors affecting foundation conditions are taken into consideration during engineering-geological investigations. This article deals with the factor of heat sourced from a structure (brick kiln) as a restrictive factor in foundation engineering in clay soils and introduces a documentation of soil deformation observations as an impact of the heat transmission into the geological environment. It was carried out in Southern Moravia in the Czech Republic, where the dominant foundation soils are Neogeneous clays where differential settlements of a tunnel kiln structure occurred as a result of ignoring the boundary conditions of temperature changes in the soil environment. The brick kilns caused heterogeneous spatial changes in the subsoil temperatures. This consequently resulted in differential settlements due to temperature changes originating from the kilns. The differential settlements reached as much as 150 mm. The major objective of the article is to highlight the importance of the heat transmission from buildings into the geological environment as a factor which should be considered in engineering geology and its application in planning. A new procedure for reducing or elimination of ground movements sourced from underlying clayey soils depending on the heat changes was also suggested in this context.     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.