云南省新平县哀牢山地区富硒土壤成因及其影响因素研究

以云南省新平县者竜—戛洒地区1∶5万土地质量地球化学调查评价结果为基础,对该地区富硒土壤的成因及其影响因素进行分析,结果表明,研究区土壤硒平均含量为0.38 mg/kg,高于全国土壤硒平均含量0.29 mg/kg,按0.4 mg/kg相似文献   

Granite is an Effective Helium Source Rock: Insights from the Helium Generation and Release Characteristics in Granites from the North Qinling Orogen,China

Global helium(He) shortage is a challenging problem; however, the types of helium source rock and the mechanisms of He generation and release therein remain still poorly understood. In this study, in order to evaluate the potential of granite as an effective helium source rock, we collected granitic samples from the North Qinling Orogen, Central China, in the south of the helium-rich Weihe Basin. The helium generation and release behaviors in granite were studied through analysis of U and Th concentrations, EMPA images, and He and Ar concentrations and isotopic ratios extracted by crushing and stepwise heating. The results indicate that Ar has a better retention and a lower mobility than He. 3 He/4 He ratios released by crushing and stepwise heating are 0.016–0.056 RA and 0.003–0.572 RA, respectively, where RA is the atmospheric 3 He/4 He of 1.4×10-6, reflecting a crustal and radiogenic source. Helium concentrations extracted by the two ways are 0.13–0.95 ucm3 STP/g and 7.82–115.62 ucm3 STP/g, respectively, suggesting that matrix-sited He accounts for more than 98% of total helium preserved in granite. In addition, the total generated He amounts in granites are calculated based on the measured U and Th concentrations in granitic samples. Dividing the preserved He quantities by the generated He amounts, it turned out that less than 10% of He produced since the formation of the granite is preserved in the rock over geological time, suggesting that more than 90% generated He can be transferred to the Weihe Basin. Temperature and fracture are the two critical factors controlling He release. Based on the relationship between He diffusivity of granites and temperature and the He closure temperatures of a variety of U-and Th-rich minerals(27–250°C), we estimate that He can be partially released out of granite at the depths 400 m and totally released at the depths 7800 m. Fractures provide effective transfer of free He from deep source rocks to shallow reservoirs. Finally, a model on granite as an effective helium source rock is established. We suggest exploring He resources in hydrocarbon basins with granitic basement(or adjacent to granite bodies), high geothermal field, and young active fractures.     

松辽盆地北部上二叠统林西组地球化学特征及地质意义

为探讨松辽盆地北部林西组地球化学特征、沉积环境及构造背景,对该区黑富地1井所钻遇的上二叠统林西组暗色泥质板岩进行主量元素、微量元素和稀土元素测试分析,结果表明：样品主量元素平均质量分数SiO₂为65.05%、Al₂O₃为17.23%、CaO为2.58%、Na₂O为2.84%、K₂O为3.29%,K₂O/Na₂O值为0.20~3.48,A1₂O₃/（CaO+Na₂O）值为0.41~8.01;稀土元素w（∑REE）值介于80.68×10^-6~215.59×10^-6之间,平均值为173.41×10^-6,δEu值介于0.61~0.88之间,平均值为0.70,表现为Eu的负异常,δCe值介于0.91×10^-6~1.01×10^-6之间,为微弱的Ce负异常,LREE富集,HREE亏损;微量元素以亏损Nb、Ta、Sr,相对富集Rb、Ba、La、Ce、Pb、Nd、Sm为特征。样品元素分析和物源w（TiO₂）-w（Ni）、La/Th-w（Hf）等判别图解表明,林西组沉积物源具有多样性,主要来源于上地壳长英质物源,还有少量来自中、基性岩火成岩物源区。样品微量元素标准化蛛网图,稀土元素球粒陨石标准化配分模式图,K₂O/Na₂O-w（SiO₂）、Th-Co-Zr/10、F₂-F₁构造背景判别图及地球化学参数对比结果表明,松辽盆地北部林西组物源构造背景主要为活动大陆边缘和大陆岛弧,可能形成于靠近大陆岛弧的活动大陆边缘构造背景。林西组应形成于海陆过渡相到陆相环境,水体由半咸水逐渐转变为淡水。     

The role of salinity in fluvio-deltaic morphodynamics: A long-term modelling study

Salinity difference between terrestrial river discharge and oceanic tidal water plays a role in modifying the local flow field and, as a consequence, estuarine morphodynamics. Although widely recognized, recent numerical studies exploring the long-term morphological evolution of river-influenced estuaries with two-dimensional, depth-averaged models have mostly neglected salinity. Using a three-dimensional morphodynamic model, we aim to gain more insight into the effect of salinity on the morphodynamics of fluvio-deltaic systems. Model results indicate that the resultant estuarine morphology established after 600 years differs remarkably when a salinity gradient is included. A fan-shaped river-mouth delta exhibits less seaward expansion and is cut through by narrower channels when salinity is included. The inclusion of salinity tends to generate estuarine circulation, which favours landward sediment transport and hence limits the growth of the delta while enhancing the development of intertidal areas. The formation of deltaic channel–shoal patterns resulting from morphodynamic evolution tends to strengthen salinity stratification, which is characterized by an increased gradient Richardson number. The direction of the depth-averaged residual sediment transport over a tide may be opposite to the direction of residual velocity, indicating the significant influence of baroclinic effects on the net sediment transport direction (and hence morphological change). The effect of salinity on morphological evolution becomes less profound when the strength of tidal or fluvial forcing is dominant over the other. The effects of sediment type and flocculation, which are particularly important when salinity gradients are present, are also discussed. Overall, this study highlights that neglecting salinity to simulate long-term estuarine morphodynamics requires more careful justification, particularly when the environment is characterized by fine sediment types (favouring suspended transport), and relatively large river discharge and estuarine depth (favouring baroclinic effects). © 2020 John Wiley & Sons, Ltd.     

Assessing the relative contributions of the flood tide and the ebb tide to tidal channel network dynamics

Flood and ebb currents provide different contributions to the initiation and evolution of tidal channel networks, generating diverse network structures and channel cross-sections. In order to separate the effects of these contributions, a physical model of a sloping tidal-flat basin was set up in the laboratory. Depending on the degree of tidal asymmetry imposed offshore, either flood or ebb currents can be enhanced. The experimental results show that the ebb current has a higher capability to initiate and shape tidal networks than the flood current. Headward erosion is mainly induced by the ebb flow. The slightly inclined flat surface tends to reduce the energy of the flood current and to enhance the ebb current, thus prolonging the duration of morphodynamic activity as well as sediment motion. Overall, flood-dominated tides favour the formation of small-scale channel branches in the upper basin zone, while long lasting ebb-dominated tides result in more complex, wider and deeper tidal networks. © 2019 John Wiley & Sons, Ltd.     

强震作用下铁路隧道横通道交叉结构抗震措施研究

依托四川茂县跃龙门铁路隧道工程,以主线单线隧道与横通道正交结构为研究对象,通过ABAQUS建立有限元分析模型。选取El-Centro地震波数据,通过应用扩展有限元理论,对横通道与主隧道交叉结构在最不利地震条件下的裂损进行研究,并提出减震层结合柔性接头的抗震措施。研究分析得到:减震层结合柔性接头的设置减小并抑制了交叉结构隧道在强震作用下的开裂范围。柔性接头的设置阻止了纵向裂缝的扩展,在交叉口处中部设置环向柔性接头能完全阻止交叉部位拱顶的裂缝生成;在初期支护和二次衬砌之间设置减震层,给予衬砌更大变形空间,使二次衬砌不易受初期支护变形受力影响而开裂。     

微囊藻CO2-浓缩机制基因型的动态变化及其对CO2的竞争效应

由于具有高效的CO₂-浓缩机制,蓝藻在低CO₂浓度条件下具有竞争优势。然而,随着大气中CO₂浓度急剧增加,蓝藻CO₂-浓缩机制如何响应的研究较少。因此,本文以常见水华蓝藻——微囊藻为研究对象,通过对滇池微囊藻水华动态及不同CO₂-浓缩机制基因型进行监测,探讨蓝藻CO₂-浓缩机制基因的微进化特征及其动态变化。同时,设置高(0.08%)、中(0.04%)、低(0.02%)CO₂浓度(V/V)进一步揭示微囊藻不同CO₂-浓缩机制基因微进化对CO₂的竞争效应。结果表明:滇池无机碳浓度在4个采样点存在空间差异性,均呈现先降低后升高的趋势,并以HCO₃^-为主要无机碳存在形式。调查期间,东大河、观音山、洛龙河和生态所4个采样点的微囊藻均以sbtA基因型占绝对优势,相对丰度远高于bicA基因型。在不同水华时期,bicA基因型和sbtA基因型呈现相反的变化趋势,即从...     

1988-2016年洞庭湖大型底栖动物群落变化及驱动因素分析

洞庭湖是我国第二大淡水湖泊,其水文条件对湖泊湿地生态系统健康的维系发挥着不可替代的作用.近年来,水环境恶化日益威胁湖区水生态系统健康.然而,有关底栖动物水生态健康评价的研究仍然停留在物种群落结构方面,缺乏底栖动物群落功能对水污染响应的研究,尤其在较长时间尺度上.因而,本研究分析了19882016年近30 a来洞庭湖的水质和底栖动物群落数据,探寻底栖动物群落功能对水环境恶化的响应规律.结果表明,洞庭湖水体总氮浓度是威胁底栖动物物种和功能群落变动的主要因素.此外,不断恶化的水环境驱动底栖动物物种和功能群落结构改变,表现为敏感水生昆虫的比例下降,寡毛类、小型软体动物比例的上升,并伴随着体长为1.00~1.99 cm、背扁型、侧扁型、不移动等功能性状类别比例的下降.同时,水环境恶化降低物种丰富度、功能丰富度和劳氏二次熵多样性.基于距离的冗余分析结果显示,水体氮营养盐、重金属离子和有机污染物共同驱动底栖动物物种群落结构的变异,而营养盐类与无/有机污染物决定着其功能群落结构的变异.鉴于洞庭湖水质不断恶化的状况,本研究建议采取一系列措施,包括合理管控湖区周边废水直排入湖、取缔湖区内的非法采砂以及调控枯水季洞庭湖水位等.生物监测和评价方面,建议将底栖动物物种和功能群落一并纳入评价体系,且优先选用物种丰富度、功能丰富度和劳氏二次熵指数评估换水周期较短的大型浅水湖泊水质变化对底栖动物物种和功能多样性的影响.     

汤东活动断裂带土壤H2、Rn地球化学特征

为研究汤东断裂带土壤气体地球化学特征及其所反映的构造地球化学背景, 采用野外监测的方法分析了张河村与邢李庄村两条测线的土壤H₂、 Rn分布特征。 结果表明, 张河村H₂浓度、 Rn活度浓度的分布范围分别为0.24×10^-6～174.7×10^-6、 13.3～69.8 kBq·m^-3, 背景值分别为14.26×10^-6, 24.8 kBq·m^-3。 邢李庄测线H₂浓度、 Rn活度浓度的分布范围11.8×10^-6～67.06×10^-6、 43.6～72.6 kBq·m^-3, 背景值分别为37.13×10^-6、 72.6 kBq·m^-3。 张河村测线在90～105 m处, H₂、 Rn出现强烈高值异常, 而120～150 m处出现高值异常。 异常值位于断裂带附近, H₂、 Rn气体测值对断裂位置具有良好的指示作用。 气体异常主要受汤东活动断裂构造控制, 汤东断裂下方的深大断裂和汤阴地堑中下地壳的低速体对深部气体释放有重要作用。     

Innovative Techniques for Measuring the Oil Content of Oil-Contaminated Porous Media

The oil content of oil-contaminated porous media is an important parameter for the assessment and remediation of oil pollution in soil and groundwater. However, an accurate measurement method is not available. In this study, we propose a new equation to calculate the oil content of water-bearing media based on traditional extraction–ultraviolet spectroscopy. Further, an improved experimental method was developed. The results indicate that the pure solid weight and oil content of oil-contaminated media can be accurately determined by introducing the oil drying loss coefficient (γ). The average relative errors of the improved method range from −0.14% to −0.96%. They are much smaller than errors of −4.49% to −10.97% of the original methods, indicating that the accuracy of measured oil content is enhanced. In addition, the accuracy of the new method does not depend on oil volatility and oil content.