Antimony deposits in the Variscan Armorican belt,a link with mafic intrusives?

The Variscan Armorican belt was the World leading producer of antimony at the beginning of the twentieth century. However, geological controls on the deposits remain unconstrained. Here, we illustrate the field setting of mineralisations and perform a statistical analysis using Geographical Information System software, geophysical and geological data. The analysis shows that Sb deposits are spatially correlated with high‐density and magnetic zones. This may reflect the presence of mafic/ultramafic bodies at depth – a suggestion that is further supported by numerous occurrences of doleritic dykes throughout the region. Future antimony prospecting should focus on the high‐density and high‐magnetic zones which comprise about 18% of the Armorican massif. Links between Sb deposits and mafic intrusions are recognised elsewhere in the West European Variscan belt, emphasising that these may be key for antimony prospecting in deformation belts.     

Three‐dimensional transient thermo‐hydro‐mechanical fundamental solutions of unsaturated soils

The governing differential equations of unsaturated soils considering the thermo‐poro‐mechanical behaviour consist of equilibrium, moisture air and heat transfer equations. In this paper at first, following some necessary simplifications, the thermal three‐dimensional fundamental solution for an unsaturated deformable porous medium with linear elastic behaviour in Laplace transform domain is presented. Subsequently, the closed‐form time domain fundamental solutions are derived by analytical inversion of the Laplace transform domain solutions. Then a set of numerical results are presented, which demonstrate the accuracies and some salient features of the derived analytical transient fundamental solutions. Finally, the closed‐form time domain fundamental solution will be verified mathematically by comparison with the previously introduced corresponding fundamental solution. Copyright © 2009 John Wiley & Sons, Ltd.     

A variable source area for groundwater evapotranspiration: impacts on modeling stream flow

Evapotranspiration (ET) plays a crucial role in catchment water budgets, typically accounting for more than 50% of annual precipitation falling within temperate deciduous forests. Groundwater ET is a portion of total ET that occurs where plant roots extend to the capillary fringe above the phreatic surface or induce upward movement of water from the water table by hydraulic redistribution. Groundwater ET is spatially restricted to riparian zones or other areas where the groundwater is accessible to plants. Due to the difficulty in measuring groundwater ET, it is rarely incorporated explicitly into hydrological models. In this study, we calibrated Topographic Model (TOPMODEL) using a 14‐year hydrograph record and added a groundwater ET pathway to derive a new model, Groundwater Evapotranspiration TOPMODEL (GETTOP). We inspected groundwater elevations and stream flow hydrographs for evidence of groundwater ET, examined the relationship between groundwater ET and topography, and delineated the area where groundwater ET is likely to take place. The total groundwater ET flux was estimated using a hydrological model. Groundwater ET was larger where the topography was flat and the groundwater table was shallow, occurring within about 10% of the area in a headwater catchment and accounting for 6 to 18% of total annual ET. The addition of groundwater ET to GETTOP improved the simulation of stream discharge and more closely balanced the watershed water budget. Copyright © 2013 John Wiley & Sons, Ltd.     

Hillslope groundwater discharges provide localized stream ecosystem buffers from regional per- and polyfluoroalkyl substances contamination

Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study, we used a combination of streambed temperature push-probe and thermal infrared methods to guide a discharge-zone-oriented sample collection along approximately 6 km of a coastal trout stream on Cape Cod, MA. Eight surface-water locations and discharging groundwater from 24 streambed and bank seepages were analysed for dissolved oxygen (DO), specific conductance, stable water isotopes, and a range of PFAS compounds, which are contaminants of emerging concern in aquatic environments. The results indicate a complex system of groundwater discharge source flowpaths, where the sum of concentrations of six PFAS compounds (corresponding to the U.S. Environmental Protection Agency third Unregulated Contaminant Monitoring Rule “UCMR 3”) showed a median concentration of 52 ± 331 (SD) ng/L with two higher outliers and three discharges with PFAS concentrations below the quantification limit. Higher PFAS concentration was related (− 0.66 Spearman rank, p < .001) to discharging groundwater that showed an evaporative signature (deuterium excess), indicating flow through at least one upgradient kettle lake. Therefore, more regional groundwater flowpaths originating from outside the local river corridor tended to show higher PFAS concentrations as evaluated at their respective discharge zones. Conversely, PFAS concentrations were typically low at discharges that did not indicate evaporation and were adjacent to steep hillslopes and, therefore, were classified as locally recharged groundwater. Previous research at this stream found that the native brook trout spawn at discharge points of groundwater recharged on local hillslopes, likely in response to generally higher levels of DO. Our study shows that by targeting high oxygen discharges the trout may thereby be avoiding emerging contaminants such as PFAS in groundwater recharged farther from the stream.     

Simulating wetland impacts on stream flow in southern Africa using a monthly hydrological model

The processes that occur in wetlands and natural lakes are often overlooked and not fully incorporated in the conceptual development of many hydrological models of basin runoff. These processes can exert a considerable influence on downstream flow regimes and are critical in understanding the general patterns of runoff generation at the basin scale. This is certainly the case for many river basins of southern Africa which contain large wetlands and natural lakes and for which downstream flow regimes are altered through attenuation, storage and slow release processes that occur within the water bodies. Initial hydrological modelling studies conducted in some of these areas identified the need to explicitly account for wetland storage processes in the conceptual development of models. This study presents an attempt to incorporate wetland processes into an existing hydrological model, with the aim of reducing model structural uncertainties and improving model simulations where the impacts of wetlands or natural lakes on stream flow are evident. The approach is based on relatively flexible functions that account for the input–storage–output relationships between the river channel and the wetland. The simulation results suggest that incorporating lake and wetland storage processes into modelling can provide improved representation (the right results for the right reason) of the hydrological behaviour of some large river basins, as well as reducing some of the uncertainties in the quantification of the original model parameters used for generating the basin runoff. Copyright © 2013 John Wiley & Sons, Ltd.     

From discrete to continuum modelling of boundary value problems in geomechanics: An integrated FEM-DEM approach

Double-scale numerical methods constitute an effective tool for simultaneously representing the complex nature of geomaterials and treating real-scale engineering problems such as a tunnel excavation or a pressuremetre at a reasonable numerical cost. This paper presents an approach coupling discrete elements (DEM) at the microscale with finite elements (FEM) at the macroscale. In this approach, a DEM-based numerical constitutive law is embedded into a standard FEM formulation. In this regard, an exhaustive discussion is presented on how a 2D/3D granular assembly can be used to generate, step by step along the overall computation process, a consistent Numerically Homogenised Law. The paper also focuses on some recent developments including a comprehensive discussion of the efficiency of Newton-like operators, the introduction of a regularisation technique at the macroscale by means of a second gradient framework, and the development of parallelisation techniques to alleviate the computational cost of the proposed approach. Some real-scale problems taking into account the material spatial variability are illustrated, proving the numerical efficiency of the proposed approach and the benefit of a particle-based strategy.     

The loess sequence of Dolní Věstonice,Czech Republic: A new OSL‐based chronology of the Last Climatic Cycle

The Dolní Věstonice loess section in the Czech Republic is well known for its high‐resolution loess–palaeosol sequence of the last interglacial–glacial climatic cycle (Upper Pleistocene). The loess section is situated in a climatic transition zone between oceanic and continental climates and is therefore of great value in reconstructing past regional climate conditions and their interaction with climate systems, in particular that of the North Atlantic. Based on a combination of optically stimulated luminescence (OSL) ages, stratigraphic field observations and magnetic susceptibility measurements, a chrono‐climatic interpretation of the Dolní Věstonice loess section is presented. To establish a reliable Upper Pleistocene chronology, a quartz OSL approach was applied for equivalent dose (D_e) determination. Monomineralic quartz extracts of three distinct grain sizes, fine (4–11 μm), middle (38–63 μm) and coarse (90–200 μm), were used and compared. Within error limits, the calculated OSL ages are the same for the different grain sizes, and the OSL ages are in stratigraphic order. The established OSL chronology is in agreement with a Weichselian litho‐ and pedostratigraphy. The Dolní Věstonice loess section is characterized by four pedosedimentary subsequences. At the base of the profile, subsequence I is characterized by a distinct Early Glacial soil complex, OSL‐dated to c. 110 to 70 ka, representing one of the most complete records of environmental change in the European loess belt. Subsequence II is allocated to the Lower Pleniglacial and is characterized by laminated sandy loess. Middle Pleniglacial subsequence III is represented by a brown soil complex, and is followed by the uppermost subsequence IV, characterized by a thick body of laminated sandy loess, indicating strong wind activity and a high sedimentation rate of more than ～1 mm a^?1 during the Upper Pleniglacial. According to the OSL chronology, as well as to the sedimentological and palaeopedological investigations, it is likely that the sequence at Dolní Věstonice has recorded most of the climatic events expressed in the NGRIP δ¹⁸O reference record between 110 and 70 ka.     

Petrographical and geochemical characterization of Comblanchien limestone (Bourgogne,France): A fingerprint of the building stone provenance

The Comblanchien limestone is a well-known building stone that deserves a quantitative characterization in order to be able to certify its origin. We compare petrographical and geochemical characteristics of limestones commercialized under the name of Comblanchien to those of one of their competitors (VATC, a Portuguese coated grain-bearing limestone). From macroscopic and microscopic observations, the distinction is somehow difficult but the coated grain-bearing Comblanchien samples have δ¹³C values (from +1.75 to +2.25‰) different from those of the VATC sample (negative δ¹³C value). As an example of application of these results, three samples from a building site near Paris are also studied in order to verify their provenance. We conclude that they do not come from quarries from the Comblanchien area, but likely from Portugal. The study shows that a detailed analysis of building limestones may provide a robust tool for discriminating between currently mined stones of different provenances, and thus open the possibility to attach to a given limestone a fingerprint, an identity card, and if required a commercial label.