Trends In U.S. Hazardous Materials Transportation Spills

This paper examines historical and spatial trends in hazardous materials transportation spills from 1971 to 1991. While the number of spills Inc.reased steadily during the 1970s, peaking in 1978–1979, there has been a decline in frequency sInc.e then largely due to modifications in reporting. Monetary damages have the opposite temporal pattern, with major Inc.reases recorded from 1982 onward. Death and injury statistics are more variable. Spatially, accidents are more prevalent in the Rust Belt extending from the Northeast corridor westward to the Great Lakes states, as well as in the Southeast. The greatest potential risk to the public is found in smaller, more densely populated industrial states such as New Jersey, Delaware, and Maryland. The spatial distribution, however, has not changed. Potential risk sources (e.g., chemical industry, number of hazardous waste facilities, number of railroad miles) are the best predictors of hazmat Inc.ident frequency. Mitigation efforts (statewide regulatory and/or management policies) also help explain the variability in hazmat Inc.idents.     

金塔绿洲主要特征量的数值模拟

 采用RAMS模式模拟了金塔绿洲非均匀地表的空气温度、湿度、风速、地表能量。结果表明,绿洲地表温度明显比周围戈壁和沙漠低,空气湿度明显比周围戈壁和沙漠大,近地层感热通量最大值约为戈壁和沙漠的1/3,近底层潜热通量比戈壁和沙漠大20倍左右。模拟结果与观测值的对比表明,RAMS对绿洲、戈壁和沙漠不同下垫面近地面温度、湿度、感热通量和潜热通量的模拟与实测基本一致。由于湍流的随机性,风速的模拟偏差比较大,这种偏差有一多半是由于非线性偏差造成的。     

On the behaviour of the hydrogen Lyman series in flares

The Lyman spectrum of hydrogen has been computed for a number of flare models, characterized by the column density of hydrogen atoms in the ground state (N ₁), the electron density (n _e) and the electron temperature (T _e). Broadening by the thermal Doppler effect and by Stark effect has been accounted for. The source functions for the individual lines of the series have been derived from non-LTE calculations of the excitation in hydrogen flares. The aim of the investigation is to evaluate the use of the intensities in between two successive Lyman lines for a determination of the value for N ₁, which is a physical parameter of the flare for which only indirect determinations are available. Whilst in principle this method could give reliable results, its practical application meets with difficulties which hardly can be overcome. Therefore, one probably has to base the N ₁ determination on the highest line resolvable in the spectrum.     

A photometric search for solar giant convection cells

We limit the photometric contrast of solar giant convection cells using 525.6 nm continuum images obtained on 15 days in May 1985. The r.m.s. of the giant cell intensity pattern must be less than or equal to the observed r.m.s. on spatial scales 80 to 240 Mm which is 0.023% or, equivalently, 0.33 K. However, the spatial scale and time-scale dependence of the variance demonstrate that giant cells are not the source of the observed variance. Consequently, a tighter constraint on the r.m.s. of the giant cell pattern may be placed, namely 0.016% or 0.23 K. This limit is consistent with temperature perturbations estimated from recent nonlinear simulations of global-scale solar convection. We use this limit on the r.m.s. of the giant cell pattern to estimate that the contribution of giant cells to the fluctuation of the solar irradiance on a one-month time-scale is less than 3 × 10^–5 S.     

Bismuth and 208Pb microdistributions in enstatite chondrites

Polished sections of 5 enstatite chondrites have been irradiated with 30 MeV ⁴He ions to produce the alpha-radioactive nuclei ²¹¹At and ²¹⁰Po from ²⁰⁹Bi and ²⁰⁸Pb, respectively. The distribution of alpha activity can be mapped, using cellulose nitrate as an alpha track detector, to give the corresponding Bi or Pb distributions in the meteorite. No strong localization of Bi or ²⁰⁸Pb was found; relatively uniform track distributions were observed. In particular, metal or sulfide grains are not enriched in Bi or Pb (relative to bulk), which is in agreement with the predictions of nebular condensation calculations. While the track distributions appear uniform, the results of detailed, track-by-track mappings of the Bi detectors indicate that the Bi is not totally randomly distributed; the statistical fluctuations in the observed track density are different for the cases where the Bi is totally randomly distributed and where the Bi is localized in point sources. Assuming that the Bi in a given sample is localized in identical point sources which are uniformly distributed throughout the sample, the observed relative population densities of clusters (‘stars’) of small numbers of tracks (2–5) corresponds to Bi being localized, with ~90% in grains with about 10^?16g-Bi (~3 × 10⁵Biatoms), and with ~10% in 4 × 10^?14 g-Bi sources. If these are elemental Bi, as predicted theoretically, they are ~ 10² Å and 10³ Å in size, respectively.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).     

Evidence of ancient life at 207 m depth in a granitic aquifer

The results of electron-microscopy investigations of calcite precipitated in a water-conducting fracture in a ca. 1800 Ma granitic rock from 207 m below sea level at the island of Aspo on the southeastern (Baltic) coast of Sweden are compared with measurements of carbon, oxygen, and sulfur isotope composition of the calcite and embedded pyrite. Parts of the calcite had extremely low delta 13C values, indicative of biological activity, and contained bacteria-like microfossils occurring in colonies and as typical biofllms. X-ray microanalysis demonstrated these fossils to be enriched in carbon. Our results provide evidence for ancient life in deep granitic rock aquifers and suggest that the modern microbial life found there is intrinsic. Modeling historical and present geochemical processes in deep granitic aquifers should, therefore, preferably include biologically catalyzed reactions. The results also suggest that the search for life on other planets, e.g., Mars, should include subsurface material.     

The pattern of supergranular in a solar active region and the formation of filaments

The formation of filaments in solar bipolar active regions is investigated, giving particular attention to the relationship between this process and the pattern of supergranular convection. SOHO MDI and Kitt Peak magnetograms and Hα filtergrams are used. The large decaying active region NOAA 8525 is considered over the period May 4–7, 1999. The boundaries of supergranules are identified as concentrations of the line-of-sight photospheric field in magnetograms. Filaments in the central part of the active region are studied; as a whole, they are aligned with the supergranule boundaries. Variations in the magnetic field in this period were manifest primarily in the form of “cancellations” and spatial-redistribution processes consistent with the pattern of developing supergranules. These factors created the conditions necessary for the formation of a filament stretched across the entire active region; i.e., the straightening of the polarity-inversion line and reduction of the horizontal gradients of the magnetic field. One possible explanation of the results is that the magnetic-field component along the filament axis is associated with the vortical structure of horizontal flows in the supergranulation cells.     

Sulfur contents of the parental metallic cores of magmatic iron meteorites

Magmatic iron meteorites are thought to be samples of the central metallic cores of asteroid-sized parent bodies. Sulfur is believed to have been an important constituent of these parental cores, but due to the low solubility of S in solid metal, initial S-contents for the magmatic groups cannot be determined through direct measurements of the iron meteorites. However, experimental solid metal-liquid metal partition coefficients show a strong dependence on the S-content of the metallic liquid. Thus, by using the experimental partition coefficients to model the fractional crystallization trends within magmatic iron meteorite groups, the S-contents of the parental cores can be indirectly estimated. Modeling the Au, Ga, Ge, and Ir fractionations in four of the largest magmatic iron meteorite groups leads to best estimates for the S-contents of the parental cores of 12 ± 1.5 wt% for the IIIAB group, 17 ± 1.5 wt% for the IIAB group, and 1 ± 1 wt% for the IVB group. The IVA elemental fractionations are not adequately fit by a simple fractional crystallization model with a unique initial S-content. These S-content estimates are much higher than those recently inferred from crystallization models involving trapped melt. The discrepancy is due largely to the different partition coefficients that are used by the two models. When only partition coefficients that are consistent with the experimental data are used, the trapped melt model, and the low S-contents it advocates, cannot match the Ge and Ir fractionations that are observed in IIIAB iron meteorites.     

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.