Generation of Porphyritic and Equigranular Mafic Enclaves During Magma Recharge Events at Unzen Volcano, Japan

Mafic to intermediate enclaves are evenly distributed throughoutthe dacitic 1991–1995 lava sequence of Unzen volcano,Japan, representing hundreds of mafic recharge events over thelife of the volcano. This study documents the morphological,textural, chemical, and petrological characteristics of theenclaves and coexisting silicic host lavas. The eruptive productsdescribed in this study appear to be general products of magmamingling, as the same textural types are seen at many othervolcanoes. Two types of magmatic enclaves, referred to as Porphyriticand Equigranular, are easily distinguished texturally. Porphyriticenclaves display a wide range in composition from basalt toandesite, are glass-rich, spherical and porphyritic, and containlarge, resorbed, plagioclase phenocrysts in a matrix of acicularcrystals and glass. Equigranular enclaves are andesitic, non-porphyritic,and consist of tabular, medium-grained microphenocrysts in amatrix glass that is in equilibrium with the host dacite magma.Porphyritic enclaves are produced when intruding basaltic magmaengulfs melt and phenocrysts of resident silicic magma at theirmutual interface. Equigranular enclaves are a product of a moreprolonged mixing and gradual crystallization at a slower coolingrate within the interior of the mafic intrusion. KEY WORDS: mafic enclaves; quenched mafic inclusions; magma mingling; Unzen volcano; Unzen Scientific Drilling Project; resorbed plagioclase     

Seasonal δS variations in two high elevation snow pits measured by S-S double spike thermal ionization mass spectrometry

δ³⁴S and sulfate concentrations were determined in snow pit samples using a thermal ionization mass spectrometric technique capable of 0.2‰ accuracy and requires ≈5 μg (0.16 μmol) natural S. The technique utilizes a ³³S-³⁶S double spike for instrumental mass fractionation correction, and has been applied to snow pit samples collected from the Inilchek Glacier, Kyrgyzstan and from Summit, Greenland. These δ³⁴S determinations provide the first high-resolution seasonal data for these sites, and are used to estimate seasonal sulfate sources. Deuterium (δD) and oxygen (δ¹⁸O) isotope data show that the Inilchek and Summit snow pit samples represent precipitation over ≈20 months.The δ³⁴S values for the Inilchek ranged from +2.6 ± 0.4‰ to +7.6 ± 0.4‰ on sample sizes ranging from 0.3 to 1.8 μmol S. δ³⁴S values for Greenland ranged from +3.6 ± 0.7‰ to +13.3 ± 5‰ for sample sizes ranging from 0.05 to 0.29 μmol S. The concentration ranged from 92.6 ± 0.4 to 1049 ± 4 ng/g for the Inilchek and 18 ± 9 to 93 ± 6 ng/g for the Greenland snow pit. Anthropogenic sulfate dominates throughout the sampled time interval for both sites based on mass balance considerations. Additionally, both sites exhibit a seasonal signature in both δ³⁴S and concentration. The thermal ionization mass spectrometric technique has three advantages compared to gas source isotopic methods: (1) sample size requirements of this technique are 10-fold less permitting access to the higher resolution S isotope record of low concentration snow and ice, (2) the double spike technique permits δ³⁴S and S concentration to be determined simultaneously, and (3) the double spike is an internal standard.     

Tracing groundwater flow and sources of organic carbon in sandstone aquifers using fluorescence properties of dissolved organic matter (DOM)

The fluorescence properties of groundwaters from sites in two UK aquifers, the Penrith Sandstone of Cumbria and the Sherwood Sandstone of South Yorkshire, were investigated using excitation–emission matrix (EEM) fluorescence spectroscopy. Both aquifers are regionally important sources of public supply water and are locally impacted by pollution. The Penrith Sandstone site is in a rural setting while the Sherwood Sandstone site is in suburban Doncaster. Fluorescence analysis of samples from discrete sample depths in the Penrith Sandstone shows decreasing fulvic-like intensities with depth and also shows a good correlation with CFC-12, an anthropogenic groundwater tracer. Tryptophan-like fluorescence centres in the depth profile may also provide evidence of rapid routing of relatively recent applications of organic slurry along fractures. Fluorescence analysis of groundwater sampled from multi-level piezometers installed within the Sherwood Sandstone aquifer also shows regions of tryptophan-like and relatively higher fulvic-like signatures. The fluorescence intensity profile in the piezometers shows tryptophan-like peaks at depths in excess of 50 m and mirrors the pattern exhibited by microbial species and CFCs highlighting the deep and rapid penetration of modern recharge due to rapid fracture flow. Fluorescence analysis has allowed the rapid assessment of different types and relative abundances of dissolved organic matter (DOM), and the fingerprinting of different sources of organic C within the groundwater system. The tryptophan:fulvic ratios found in the Penrith Sandstone were found to be between 0.5 and 3.0 and are characteristic of ratios from sheep waste sources. The Sherwood Sandstone has the lowest ratios (0.2–0.4) indicating a different source of DOM, most likely a mixture of terrestrial and microbial sources, although there is little evidence of pollution from leaking urban sewage systems. Results from these two studies suggest that intrinsic fluorescence may be used as a proxy for, or complementary tool to, other groundwater investigation methods in helping provide a conceptual model of groundwater flow and identifying different sources of DOM within the groundwater system.     

A 36Cl age determination for Mystery Creek rock avalanche and its implications in the context of hazard assessment, British Columbia, Canada

The Sea to Sky Corridor has experienced hundreds of historic and prehistoric landslides. The most common types of historical landslides are rock falls and debris flows, which are relatively small in volume but can be damaging. These types of failures are more common in the southern part of the corridor, between Horseshoe Bay and Porteau, where infrastructure has been built in close proximity to steep slopes. Farther north, fewer landslides have been reported historically, but those that have been recorded are usually large and date to prehistoric time (e.g., Cheekye fan and Mystery Creek rock avalanche). As part of a Geological Survey of Canada surficial geology and landslide inventory mapping study, Mystery Creek rock avalanche, near Whistler, British Columbia, was sampled for ³⁶Cl dating. Samples were collected from three large flat boulders of quartz diorite in the rock avalanche deposit to test a correlation with the previously reported radiocarbon age of 800 ± 100 years BP on charcoal. One sample revealed a mean age of 2,400 years and the other two, 4,300 and 4,800 years, respectively. These new results point to four possible interpretations: (1) Mystery Creek landslide is about 800 years old; (2) Based on the overlapping 2σ uncertainties, the rock avalanche took place between 2,200 and 3,600 years ago; (3) The rock avalanche deposit is 2,400 years old and the other two blocks are too old; and (4) The rock avalanche is between 4,300 and 4,800 years old. Although there is strength in numbers and it is likely that the age varies between 4,300 and 4,800 years, we favor the second interpretation where the age range is broader and statistically significant for all three samples. Moreover, at this time, we favor discounting the radiocarbon age based on a greater number of samples analyzed for ³⁶Cl analysis and lack of detailed information on the charcoal sampling. The causes and triggers of the Mystery Creek rock avalanche remain unknown, but direct glacial debuttressing can be ruled out. Some of the causes are likely a combination of the regional tectonic setting which produced preferential planes of weakness reflected in the trend of major faults, headscarp, and reverse scarps. Yearly cycles of freezing and thawing are considered a plausible cause based on present-day climate records. Finally, a large earthquake still remains a possible trigger because of the active tectonic setting and the presence of potentially contemporaneous landslides in the same area. Mystery Creek rock avalanche and other historic and pre-historic landslides contributed to validation of a heuristic rock fall/rock slide/rock avalanche susceptibility mapping study, in which their headscarps correlated well with medium-high to high susceptibility zones. In terms of hazard assessment, Mystery Creek rock avalanche, although pre-historic in age, occurred in present-day climatic and geological conditions. This poses a threat to infrastructure such as the Sea to Sky Highway, railway, and power line.     

Recent Tectonic Rupturing on the Mud Volcano of Mount Karabetova,Taman Peninsula

Doklady Earth Sciences - In October 2019, extremely impressive, fresh ruptures of the surface on the mud volcano of Mount Karabetova were discovered. The ruptures are represented by all the main...     

Some observations from the data taken in and around Kharagpur during the onset of the monsoon, 1990

During MONTBLEX 1990, various observational platforms were operated at Kharagpur and the nearby Kalaikunda Air Base. Using the data from all the platforms, one can draw the following conclusions. The temperature and wind data obtained from various sensors have overall compatibility. Sodar wind data indicate the presence of a low level jet at around 300 m above ground. The inversion height may be evaluated from the vertical profile of the sodar back-scatter echo intensity. The sub-synoptic or synoptic scale convergence modulates the inversion height and the presence of cloud-base within the inversion height in turn modulates the sensible heat and momentum fluxes.     

Petrology of the tin-bearing granite-leucogranites of the Piaoak Massif, Northern Vietnam

The Piaoak tin-bearing granite-leucogranites located in the Caobang Province of Northern Vietnam compose a stock-like hypabyssal body. Host rocks are represented by Early Devonian carbonate sequences and Early Triassic ??black?? shales. The geochronological age of the Piaoak granite-leucogranites corresponds to the Late Cretaceous: T = 83.5 ± 6.2 Ma, ⁸⁷Rb/⁸⁶Sr method; T = 89.7 ± 1.0 Ma, ³⁹Ar/⁴⁰Ar method. The massif has a simple basic to acid order: two-mica and muscovite granite-leucogranite ?? raremetal aplites, pegmatites ?? tin-bearing greisens and hydrothermal veins. The petrographic and microstructural studies revealed a sharp change in crystallization conditions of the granite-leucogranite magma at the late magmatic stage and formation of muscovite via incongruent melting of protolithionite. The study of melt and coexisting fluid inclusions showed that solidus crystallization occurred under fluid-saturated conditions at 635?C600°C. In composition, the granite-leucogranites of the Piaoak Massif correspond to the raremetal-plumasite geochemical type (according to L.V. Tauson), and reach Li-F facies in terms of their rare-element composition. The composition of aplites and pegmatites demonstrates that granite-leucogranite magma did not accumulate lithophile and volatile components in the residual melt during differentiation, but was initially enriched in rare-metals. It is most probable that the melt was generated from Proterozoic lithotectonic complexes and overlaying Lower Triassic ??black?? shales.