Early diagenesis of phytyl esters in a contemporary temperate intertidal sediment

Analysis of a sediment core for hydrolysed chlorins (acidic chlorins e.g. pheophorbide a) and non-acidic chlorins, and free, bound and esterified alcohols have been performed and the results have been interpreted in terms of input and sedimentary interconversions. There is an association of the acidic chlorin input with an input of unesterified aliphatic n-alkanols (> C₂₀), and subsequent degradation of the chlorins with depth. Input of phytol to the anoxic region of the sediment is not associated with the n-alkanols:phytol in the sediment is derived largely from chlorophyll-a input to the surface layers as intact microalgae. Degradation with depth involves conversion of the chlorophyll-a to non-chlorin, colourless phytyl esters prior to incorporation of the phytol into a bound fraction. At depth this bound phytol is hydrolysed resulting in release of free phytol.     

Thinking outside the framework: equitable research partnerships for environmental research in Australia

Many environmental science research programmes now adopt community-based philosophies and designs, although there are few applications in Australian Indigenous communities. This research describes the development and testing of a framework of engagement to guide collaboration between Indigenous and non-Indigenous Australians during an environmental sciences research project. That project aimed to assess trepang (sea cucumber) stocks in Aboriginal waters, and determine the commercial harvest potential of the resource to local people. Its objectives were to undertake trepang survey and mapping, integrate Indigenous knowledge about the resource, and model the existing catch data of commercial fishers operating in the region. The framework of engagement developed to guide the research process comprised a goal, research stages, and a number of guiding principles for collaboration, which were constructed from content analysis of available guidelines and literature and from data gathered during expert interviews. Further data were gathered using participant observation, while implementing the trepang research in accordance with this framework of engagement, and these data were analysed to test and evaluate the framework. Findings indicate discursive and reflective approaches such as action research or adaptive management may better facilitate equitable research partnerships for sustainable development.     

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

Application of sodars in the study and monitoring of the environment

Summary Application of acoustic sounders (sodars) to study the atmospheric boundary layer (ABL) began in the early 1970s. During the last two decades the scope of sodars applications enlarged considerably. The proceedings of eleven symposia of the International Society for Remote Acoustic Sensing of the Atmosphere and Oceans (ISARS) are a unique collection of papers, where all directions of the sodar use since 1981 are presented. In this paper, a review of sodar applications to atmospheric research is presented based on materials published in these proceedings in the following fields: conditions of microwave and light propagation; regional climatology of the ABL; air pollution meteorology and weather forecast; mesoscale phenomena under stable and unstable stratification; micrometeorology; peculiarities of the ABL in remote and complex terrain.     

The effect of sampling scale on actualistic sandstone petrofacies

Empirical correlations between plate tectonic setting and sand/sandstone composition have been the basis for large scale petrological models. These models do not explicitly treat sampling scale. Four areas from the western USA with diverse tectonic settings and rock types provide a natural laboratory for sampling sand at three different scales: talus piles to small drainages (first order), streams and rivers draining mountain ranges (second order), and large rivers and marine environments (third order). Existing plate tectonic petrofacies models should only be applied to third order settings because the data were derived from studies of such settings. This is especially true in tectonic settings with diverse source rocks (e.g. continental rifts and transform settings). On the other hand, some settings, such as active magmatic arcs and foreland fold-thrust belts, provide uniform results at any sampling scale because of homogeneity of source rocks. The Rio Grande drainage area is especially complex, with diverse igneous, metamorphic and sedimentary source areas. Some components (e.g. basalt) are destroyed with minimal transport, whereas others (e.g. quartz) are relatively enriched with greater transport. In this complex continental rift setting, first and second order sand is diverse and heterogeneous due to input from tributaries. The Santa Clara River of southern California also has heterogeneous sand due to diverse source rocks in this transform setting. It is only after considerable homogenization and stabilization due to weathering and mixing with more stable components, and/or considerable transport, that homogeneous compositions are produced in these two settings. In contrast, the Cascade magmatic arc and the Canadian Rocky Mountain fold-thrust belt have uniform source rocks (dominantly volcanic in the former and dominantly sedimentary in the latter). Uniform sand composition that is unique to each of these tectonic settings results at any sampling scale in these two cases. Uniformity of data collection and analysis is essential for reproducible results. Use of the Gazzi-Dickinson point counting method allows direct comparison among source rocks (zero order samples), modern sand of any order and ancient sandstone of unknown provenance. Lack of recognition of the effect of sampling scale in the development of actualistic petrofacies models has led to incorrect rejection of many existing models. Third order sands are excellent predictors of plate tectonic setting, but first and second order sands can provide ambiguous plate tectonic interpretations in many settings. More complex actualistic petrofacies models based on diverse sampling scales are needed.     

The impact of rural land management changes on soil hydraulic properties and runoff processes: results from experimental plots in upland UK

To develop an evidence base to help predict the impacts of land management change on flood generation, four experimental sites were established on improved grassland used for sheep grazing at the Pontbren catchment in upland Wales, UK. At each site, three plots were established where surface runoff was measured, supplemented by measurements of soil infiltration rates and soil and vegetation physical properties. Following baseline monitoring, treatments were applied to two of the plots: exclusion of sheep (ungrazed) and exclusion of sheep and planting with native broadleaf tree species (tree planted), with the third plot acting as a control (grazed pasture). Due to a particularly dry summer that occurred pre‐treatment, the soil hydrological responses were initially impacted by the effects of the climate on soil structure. Nevertheless, treatments did have a clear influence on soil hydrological response. On average, post‐treatment runoff volumes were reduced by 48% and 78% in ungrazed and tree‐planted plots relative to the control, although all results varied greatly over the sites. Five years following treatment application, near‐surface soil bulk density was reduced and median soil infiltration rates were 67 times greater in plots planted with trees compared to grazed pasture. The results illustrate the potential use of upland land management for ameliorating local‐scale flood generation but emphasise the need for long‐term monitoring to more clearly separate the effects of land management from those of climatic variability. Copyright © 2013 John Wiley & Sons, Ltd.     

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Eignung mikrobieller Biotests für gebundene Schadstoffe Suitability of Microbial Bioassays for Bound Contaminants

Toxicity of soil spiked with water soluble and insoluble contaminants was assessed with bacteria. Three bioassays were used with common soil bacteria. Water soluble fractions from the soils were estimated in microtiterplates via dehydrogenase activity of B. cereus and growth of P. putida. A new method was developed using B. cereus to include effects of soil particles with bound contaminants. As contaminants p-nitrophenol and 2-naphthol were tested in these systems. Results indicated that the concentration of the contaminants in the soil solution is determined by soil properties. Toxicity of water soluble fractions was not only a result of the toxicant's concentration but further modified by soluble components of the soils. It is not possible to assess soil pollution from toxicity of the water soluble fraction in general, because unknown factors of the soluble soil fraction can influence toxicity greatly. The newly developed contact bioassay with B. cereus showed clearly higher toxicity of 2-naphthol estimated in soil suspension than did the comparable test system with the same bacteria using water soluble fractions only. The results stress the importance of including soil particles into bioassay procedures. It was shown that also water insoluble, bound contaminants can act as toxicants. For an estimation of toxicity under conditions more relevant for the environment, the suggested test system can provide useful information to bioavailability of bound contaminants.