Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

超低频电磁声源非线性动力学建模与分析

电磁声源输出力大、体积小、易于实现超低频输出,在无人反水雷作战中具有显著优势。其动力学行为受到机械回复力和电磁力的耦合作用影响,当施加电流超过坍塌电流,电磁力将超过机械回复力, 就会发生吸和,造成声源的损坏。为准确描述电磁声源非线性动力学特性,预先评估坍塌电流,建立考虑动态漏磁系数的声源非线性动力学模型。通过三维有限元仿真计算动铁芯运动到不同位置处气隙的漏磁系数, 拟合得到动态漏磁系数。根据等效磁路法建立声源的改进电磁力模型,进而建立电磁声源非线性动力学模型。 通过 Runge-Kutta 算法计算得到阶跃激励下声源振动的位移和速度,绘制相平面图。研究稳定与失稳 2 种情况下的相轨迹的动态变化规律,为电磁声源的设计和控制提供理论支撑。     

基于YOLO算法的海洋中尺度涡三维结构构建

海洋中尺度涡是一种常见的中尺度海洋现象,研究海洋中尺度涡的分布及运动特性对航运、气候、军事等具有重要作用,海洋中尺度涡的识别是海洋学和计算机科学领域的一个热门研究课题。运用深度学习的方法和框架,对中尺度涡的二维识别和三维结构构建展开研究分析。首先,获取全球海洋再分析数据并进行流线可视化,构建涡旋流线数据集;其次,利用YOLO v5s卷积神经网络对涡旋流线数据集进行训练,并对南海区域中尺度涡进行有效检测。实验结果表明,YOLO v5s训练后得到最优模型经过测试,平均检测精度均值达到了86.10%;最后,根据涡旋检测结果,对检测出的同时刻不同深度的涡旋判断是否属于同一涡旋,确定后进行该涡旋的三维结构构建。     

Effect of the Initial Vortex Structure on Intensity Change During Eyewall Replacement Cycle of Tropical Cyclones: A Numerical Study

This study investigates the effect of the initial tropical cyclone (TC) vortex structure on the intensity change during the eyewall replacement cycle (ERC) of TCs based on two idealized simulations using the Weather Research and Forecasting (WRF) model. Results show that an initially smaller TC with weaker outer winds experienced a much more drastic intensity change during the ERC than an initially larger TC with stronger outer winds. It is found that an initially larger TC vortex with stronger outer winds favored the development of more active spiral rainbands outside the outer eyewall, which slowed down the contraction and intensification of the outer eyewall and thus prolonged the duration of the concentric eyewall and slow intensity evolution. In contrast, the initially smaller TC with weaker outer winds corresponded to higher inertial stability in the inner core and weaker inertial stability but stronger filamentation outside the outer eyewall. These led to stronger boundary layer inflow, stronger updraft and convection in the outer eyewall, and suppressed convective activity outside the outer eyewall. These resulted in the rapid weakening during the formation of the outer eyewall, followed by a rapid re-intensification of the TC during the ERC. Our study demonstrates that accurate in- itialization of the TC structure in numerical models is crucial for predicting changes in TC intensity during the ERC. Additionally, monitoring the activity of spiral rainbands outside the outer eyewall can help to improve short-term intensity forecasts for TCs experiencing ERCs.     

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

川西理塘第四纪盆地沉积体系、演化及古气候分析

理塘第四纪盆地以河湖相沉积为主，其形成于747ka，消亡于179～180ka。盆地内不同地点的沉积物的时空分布，揭示出古湖泊演化属于一种不连续的扩展型，在其演化过程中存在着多次的消失或萎缩时期；盆地内孢粉组合表明，其形成于一种温热湿润的气候环境，当时的海拔高度在2000m左右，以后高原气候由热变温；冰川发育加剧了古无量河的溯源侵蚀作用，最终切穿盆地，致使湖水外泄，湖泊消亡。理塘盆地的演化历程为研究青藏高原的古气候变化提供了重要证据。