Organic tracers in sediments from the coastal zone of Ras Abu el-Darag,Gulf of Suez

Sediment samples from the coastal zone of the Gulf of Suez contain a variety of organic compounds from anthropogenic and natural sources. A total of 12 surface samples of bottom sediments were collected with an Ekman grab sampler along an off-shore transect south of Ras Abu el-Darag. The samples were extracted with a mixture of dichloromethane and methanol (3:1 v/v) after drying and sieving through 250 μm mesh. The extracts were derivatized and analyzed by gas chromatography–mass spectrometry in order to characterize the chemical composition and sources of the organic components. Marine with minor terrestrial biota were the major natural sources of organic tracers and included n-alkanoic acids, sterols and saccharides (5.7–76.7%). Anthropogenic sources, from petroleum related activities, detergent usage for spill cleaning and littering, are indicated by the presence of n-alkanes with carbon preference index ≤1.0, hopanes, steranes, unresolved complex mixture of branched and cyclic hydrocarbons, alkyl nitriles, alkamides and plasticizers. Their total relative concentrations ranged from 23.3 to 97.3% of the total extracts. Petroleum residues from natural seepage may also be part of these hydrocarbons. The levels of anthropogenic inputs decrease from about 94% in coastal zone sediments to about 20% in sediments from the reef front.     

Eliminierung und Rückgewinnung von Metallionen aus Abwässern — eine Übersicht

The present state and the trends of the recovery of heavy metals from wastewaters are presented. The classical precipitation techniques are insatisfactory due to increases of solubility in the presence of impurity ions and/or complexing agents. At present, ion-exchange processes constitute the most frequently used method of metal recycling with an effective enrichment of metal ions. For the effective separation of metals from solutions of a low concentration the electrolytic reduction demands large electrode surface areas. In cells with fixed-bed or fluidized cathodes one can obtain specific electrode surface areas of some 10³ m²/m^m3. For the future, processes of extraction and especially membrane separation will gain in importance. In the past few years, a large number of highly selective metal extracting agents as well as the liquid membrane permeation with suitable carriers were developed. Combinations of membrane separation processes with chemical reactions may attain the same importance, as e.g. ultrafiltration in connection with the fixation of metal ions to watersoluble polymers. In the long run, especially techniques will prevail which will not only result in metal enrichment but also in the recovery of the raw material water.     

Magnetometer Array Study in North-Northeast Brazil: Conductivity Image Building and Functional Induction Modes

—Magnetovariational fields recorded by an array of magnetometers in the equatorial region of north-northeast Brazil are analyzed to infer the configuration of internal induced currents in and around the extensive intracratonic Parnaíba basin. Only nighttime magnetovariational fields were used because of the prevailing uniform source field conditions. For periods exceeding 40 min. the vertical fields at all inland sites are dominated by the effects of electric currents originating in the northeast, in the deep Atlantic Ocean. Below this period, although best developed in the 12–15 min. period range, the anomalous signatures are principally controlled by two distinct continental current paths. The first is associated with a N60°E trending graben-like structure in the southeastern part of the basin (named the Parnaíba Basin Conductivity Anomaly—PBCA) and the second appears as a subsurface sedimentary channel, from the NW corner of the array to the central part of the basin. This is named the LINK anomaly, as it connects the northwestern Marajó basin with the Parnaíba basin. While the PBCA is shown to highlight the importance of basement tectonics in the geological evolution of the Parnaíba basin, the LINK anomaly provides strong geophysical evidence of the direction of the sea intrusion into the region of the basin and possibly indicates the connectivity of the Parnaíba basin to the adjoining Amazon basin through the Marajó basin. Frequency and polarization dependence suggest that the induction response of individual structures is not determined by the local conductivity alone but also by their interconnectivity as well as by their linkage to the continental shelf and deep oceanic region.     

Problems in the calibration of an acoustic device for the observation of bedload transport

Developments in theoretical and empirical modelling of bedload transport processes are hindered by the lack of an adequate data base for testing or establishing the models. Conventional methods of measuring bedload transport rates fail to provide the necessary continuous or frequent record of variations at a single section. Acoustic techniques have the potential to overcome this deficiency, but their application has been very limited. Some of the problems of calibrating an acoustic device in the field and in a laboratory flume are discussed, and a possible circuit design described which might minimize calibration difficulties by automatically subtracting the noise generated by flow turbulence.     

Measurements of carbon dioxide and heat fluxes during monsoon-2011 season over rural site of India by eddy covariance technique

An increase in carbon dioxide (CO₂) concentrations in the atmosphere due to anthropogenic activities is responsible for global warming and hence in recent years, CO₂ measurement network has expanded globally. In the monsoon season (July–September) of year 2011, we carried out measurements of CO₂ and water vapour (H₂O) concentrations along with wind and air temperature over a tropical site in south-east India having rural topography. To collect these observations, the instrumentations used were the sonic anemometer for wind and temperature, and the open path H₂O/CO₂ infrared gas analyzer for CO₂ and H₂O concentrations. Using these observations, we explored the diurnal variability of CO₂ flux along with sensible and latent heat. The CO₂ flux was positive during night-time and negative during daytime and in phase with convective instability. The CO₂ flux relationships with the meteorological parameters such as wind speed, temperature and heat fluxes have been analysed. The seasonal (monsoon) half hour mean of CO₂ flux which was ?3.55 μmol m^???2 s^???1 indicated the experimental site as a CO₂ sink region (net seasonal uptake). An increase in CO₂ concentrations during weekends was not observed due to unavailability of heavy vehicular traffic.     

Searching for hidden Wolf–Rayet stars in the Galactic plane – 15 new Wolf–Rayet stars

We report the discovery of 15 previously unknown Wolf–Rayet (WR) stars found as part of an infrared (IR) broad-band study of candidate WR stars in the Galaxy. We have derived an empirically based selection algorithm which has selected ∼5000 WR candidate stars located within the Galactic plane drawn from the Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (mid-IR) and Two-Micron All-Sky Survey (near-IR) catalogues. Spectroscopic follow-up of 184 of these reveals 11 nitrogen-rich (WN) and four carbon-rich (WC) WR stars. Early WC subtypes are absent from our sample and none shows evidence for circumstellar dust emission. Of the candidates which are not WR stars, ∼120 displayed hydrogen emission-line features in their spectra. Spectral features suggest that the majority of these are in fact B supergiants/hypergiants, ∼40 of these are identified Be/B[e] candidates.
Here, we present the optical spectra for six of the newly detected WR stars, and the near-IR spectra for the remaining nine of our sample. With a WR yield rate of ∼7 per cent and a massive star detection rate of ∼65 per cent, initial results suggest that this method is one of the most successful means for locating evolved, massive stars in the Galaxy.     

Planet Four: Craters—Optimizing task workflow to improve volunteer engagement and crater counting performance

Virtual citizen science platforms allow nonscientists to take part in scientific research across a range of disciplines, including planetary science. What is required of the volunteer can vary considerably in terms of task type, variety, judgment required, and autonomy—even when the overall goal is unchanged. Through analysis of our live Zooniverse Planet Four: Craters citizen science platform, the effects of task workflow design factors including volunteer autonomy, task variety, task type, and judgment required on volunteer engagement and crater marking performance were investigated. Website analytics showed volunteers using the Full interface (most autonomy and variety) were more likely to return to the platform, although the amount of time spent per visit was unaffected by the interface used. However, analysis of performance suggested that how this time was used did differ. The interface involving the least complex task resulted in the greatest amount of data and rate of collection, although this also coincided with a greater number of false positives when compared with the expert. Performance in terms of agreement, both between participants and with the expert judgment, was significantly improved when using the Stepped interface for crater position and the Ramped (Mark) when measuring diameter—interfaces that both directly measured the metric with a specific, delineated task. The implications for planetary scientists considering the citizen science route is that there is a balancing act to perform, weighing the importance of volunteer engagement with scientists' data needs and the resources that can be committed to data validation.     

Iodine differentiation between different sized fractions in natural waters

Membrane filtration technique was applied to study the distribution of iodine and some other chemical elements (iron, manganese, aluminum, and silicon) in natural waters between different sized fractions (>0.45, 0.45–0.22, 0.22–0.1, and <0.1 μm). The paper presents analysis of factors able to modify the proportions of the adsorbed and dissolved species of the elements in waters. It is proved that up to 90% of the total amount of the iodine ion occurs in aquatic environments in the form of dissolved species (according to the current standard, in the fraction < 0.45 μm), with approximately 49% of the total concentration corresponding to the fraction of <0.10 μm. An increase in the acidity of the waters and their enrichment in finely divided organic and mineral material, and also an increase in Fe and Mn concentrations, may increase in the concentrations of the trace element in the particulate matter (up to 26% of the total iodide concentration). The greatest variations in iodine distribution between different fractions are found in the surface waters.     

The agricultural utility of lithic-mulch gardens: Past and present

The mulching of agricultural fields and gardens with stones, pebbles, volcanic ash and similar lithic materials is a variant agricultural strategy uniquely suited to the constraints of a dryland environment. While the agricultural literature contains reports on limited experiments with stone or gravel mulch, data regarding the employment of lithic mulch are lacking. This paper works to bridge this gap by comparing empirical data collected from prehistoric pebble-mulch gardens in the Galisteo Basin (New Mexico) to contemporary agricultural experiments with lithic mulch. Such past-present and experimental-real world comparisons allow us to more fully address the effectiveness of lithic mulching as an agricultural strategy. It is affirmed that lithic mulch is applied to garden plots, especially during periods of drought, in order to reduce soil erosion from wind and water, increase soil temperature to extend the growing season, increase water infiltration, and reduce the evaporative loss of water from wind and sun. The cumulative effect of this soil and water conserving technique is an increase in crop biomass and crop yield.