Holocene overbank deposition in the drainage basin of Lake Khanka

Overbank deposits in the Komissarovka River valley consist of alternating silt, clay silt, sand, and soils produced by lacustrine, alluvial, and aeolian deposition and by soil formation. Silt and sand layers in the lower part of the section correlate with the events of Early Holocene transgression and Middle Holocene regression of Lake Khanka. Deposition in the lowermost reaches of the Komissarovka River provides a faithful record of local Holocene landscapes controlled by level changes in Lake Khanka.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Water equivalent method for city phytostructure of Indonesia

This paper proposed a simple method and rapid to carry out for organizing city phytostructure. Carbon dioxide sequestration was addressed and referred to population number instead of city area. The unit storage of carbon dioxide, which was nothing less than greenspace area, was determined using equivalent method of determining unit storage of water. For various population number (P) of city area in Indonesia, the greenspace unit (GU) was 29P^?0.3 ? 3.2, and the greenspace area (GA) was 29P⁰⁷–3.2P. Greenspace distribution was preferably on wetlands, river lines, top ground level, and north south direction.     

Threshold of sediment motion under unidirectional currents

Carefully selected data for the threshold of sediment movement under unidirectional flow conditions have been utilized to re-examine the various empirical curves that are commonly employed to predict this threshold. After a review of the existing data, we employed only that data obtained from open channel flumes with parallel sidewalls where flows were uniform and steady over flattened beds of unigranular, rounded sediments. Without these restrictions, an unmanageable amount of scatter is introduced. This selected data is used to develop a modified Shields-type threshold diagram that extends the limits of the original diagram by three orders of magnitude in the grain-Reynolds number. The equally general but more easily employed Yalin diagram for sediment threshold is also examined. Although the Shields and Yalin diagrams are general in that they apply to a wide range of different liquids, in both cases somewhat different curves are obtained for threshold under air than for the liquids. The often used empirical curves of the friction velocity u_*, the velocity 100 cm above the bed u₁₀₀, the bottom stress θ_t, and Shields’ relative stress θ_t, all versus the grain diameter D, are limited in their ranges of application to certain combinations of grain density, fluid density, fluid viscosity and gravity. These conditions must be selected before the curves are generated from either the more general Shields or Yalin curves. For example, on the basis of the data selected for use in this paper, empirical threshold relationships for quartz density material in water are where the velocity u₁₀₀ measured 100 cm above the sediment bed is given in cm/sec and the grain diameter D is in cm. The limitations on any of the threshold relationships are severe. These limitations should be properly understood so that the empirical curves and relationships are not improperly employed.     

Patterns in the hydrogen and trace element compositions of mantle olivines

 The concentrations of hydrogen and the other trace elements in olivines from mantle xenoliths have been determined by secondary ion mass spectrometry (SIMS) for clarifying the incorporation mechanism and the behavior of the hydrogen. The hydrogen contents in olivines from mantle xenoliths range from 10 to 60 ppm wt. H₂O and the concentration range is consistent with the previous infrared (IR) spectroscopic data. IR spectra of the olivine crystals show no effects of the weathering or secondary alteration. The hydrogen is distributed homogeneously among olivine grains in each mantle xenolith. However, the hydrogen contents of the olivine crystals are less than those for the olivine phenocrysts crystallized from the host magma. Olivine inclusions in diamonds also show similar hydrogen contents to the xenolithic olivines. Thus the hydrogen content of xenolithic olivines does not attain equilibrium with water in the host magma during the transportation from the Earth's mantle to the surface, and is taken as a reflection of the hydrogen condition in the mantle. Correlations of hydrogen with trivalent cation contents in garnet peridotitic olivines indicate the incorporation of hydrogen into mantle olivines by a coupled substitution mechanism, with the hydrogen present in the form of hydroxyl in oxygen positions adjacent to the M site vacancies. The hydrogen content of xenolithic olivines increases with pressure but decreases with increasing temperature, suggesting importance of olivine as a water reservoir at low temperature regions such as in subducting slabs. Received August 15, 1995/Revised, accepted November 19, 1996     

Catagenesis and burial metamorphism of terrigenous and volcanic sequences (section recovered by the En-Yakhinskaya parametric borehole SG-7)

Secondary alterations of Cretaceous, Jurassic, and Triassic terrigenous complexes recovered by borehole SG-7 were studied from the depth of 3620 m to 6920 m (roof of basalts). Down to the depth of ∼6770 m, the section shows a gradual intensification of catagenetic alterations of sandy rocks: the formation of pressure dissolution textures and regeneration of clastic quartz. Intensification of the transformation of clay minerals is not observed in this mineral. Variations in the contents of illite, hydromicas, mixed-layer minerals, smectite, chlorite, and kaolinite at different depths of the recovered section are related to changes in the provenance during the accumulation of sedimentary complexes. The Middle Triassic coarse-grained sandy rocks (suprabasalt sequence) are more intensely transformed: they are marked by microstylolitic textures of pressure dissolution, recrystallization blastesis of clastic quartz grains, and newly formed zoisite. The composition of clay minerals is also characterized by variation: micas are represented by sericite with ΔD = 0; Fe-chlorite and kaolinite are noted. These features suggest the absence of linear positive correlation of T and P with the subsidence depth of sedimentary complexes. Intense heating (up to 200–300°C) of the Middle Triassic suprabasalt rocks is likely caused by trap activity (intense effusion of basalt lavas). Investigation of secondary minerals in basalts recovered by borehole SG-7 revealed that the grade of their transformation matches the medium-temperature subfacies of the greenschist facies.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

苏丹穆格莱德盆地福拉凹陷油气成藏特征及勘探启示

福拉凹陷下白垩统Abu Gabra组发育有湖相好—极好烃源岩,但热演化程度低、成藏主控因素不确定,勘探潜力不明。通过地层层序划分、构造分析、沉积相分析,认为张剪性区域构造背景控制福拉凹陷的构造与沉积发育,下白垩统Abu Gabra组发育有一定规模有效生烃凹陷,可形成Abu Gabra组烃源岩层,Abu Gabra组自储自盖,Bentiu组储、Aradeiba组盖及Aradeiba组自储自盖等3套生储盖组合,其中第二套储盖组合为该凹陷不同于六区其他凹陷的良好储盖组合。紧邻生烃凹陷、继承性发育的构造带,如中部滚动背斜—断鼻、南部次凹西缘断鼻、南部断阶带断鼻、北部次凹东缘断鼻等构造带是有利的成藏带。继承性发育的Fula1号滚动背斜、Fula2号断鼻构造具有多套储盖组合,勘探风险低,为有利的勘探目标。这些认识为福拉凹陷油气勘探提供了科学依据,且其研究方法及思路也为新区油气勘探提供良好的借鉴。