Proton flux and radiation dose from galactic cosmic rays in the lunar regolith and implications for organic synthesis at the poles of the Moon and Mercury

Galactic cosmic rays are a potential energy source to stimulate organic synthesis from simple ices. The recent detection of organic molecules at the polar regions of the Moon by LCROSS (Colaprete, A. et al. [2010]. Science 330, 463–468, http://dx.doi.org/10.1126/science.1186986), and possibly at the poles of Mercury (Paige, D.A. et al. [2013]. Science 339, 300–303, http://dx.doi.org/10.1126/science.1231106), introduces the question of whether the organics were delivered by impact or formed in situ. Laboratory experiments show that high energy particles can cause organic production from simple ices. We use a Monte Carlo particle scattering code (MCNPX) to model and report the flux of GCR protons at the surface of the Moon and report radiation dose rates and absorbed doses at the Moon’s surface and with depth as a result of GCR protons and secondary particles, and apply scaling factors to account for contributions to dose from heavier ions. We compare our results with dose rate measurements by the Cosmic Ray Telescope for the Effects of Radiation (CRaTER) experiment on Lunar Reconnaissance Orbiter (Schwadron, N.A. et al. [2012]. J. Geophys. Res. 117, E00H13, http://dx.doi.org/10.1029/2011JE003978) and find them in good agreement, indicating that MCNPX can be confidently applied to studies of radiation dose at and within the surface of the Moon. We use our dose rate calculations to conclude that organic synthesis is plausible well within the age of the lunar polar cold traps, and that organics detected at the poles of the Moon may have been produced in situ. Our dose rate calculations also indicate that galactic cosmic rays can induce organic synthesis within the estimated age of the dark deposits at the pole of Mercury that may contain organics.     

Oxygen and hydrogen isotope fractionation in serpentine-water and talc-water systems from 250 to 450 °C, 50 MPa

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than ¹⁸O-¹⁶O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of ¹⁸O-¹⁶O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 10⁶/T² − 25.49 × 10³/T + 12.48 and 1000 ln  = 3.49 × 10⁶/T² − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 10⁶/T² − 41.52 × 10³/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 10⁶/T² − 34.736 × 10³/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and ¹⁸O-¹⁶O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.     

Fire Severity,Water Repellency Characteristics and Hydrogeomorphological Changes Following the Christmas 2001 Sydney Forest Fires

Soil water repellency can enhance overland flow and erosion and may be altered by fire. The Christmas 2001 bushfires near Sydney allowed investigation of the relationship between fire severity, water repellency and hydrogeomorphological changes. For two sub-catchments with differences in fire severities in Nattai National Park, south-west of Sydney, this paper considers: (1) the links between fire severity based on SPOT image analysis and ground observation of fire severity and repellency; (2) the textural and organic/minerogenic characteristics of eroded sediment; and (3) erodibility, erosion and deposition of soils in both catchments. Ground surveys show that image analysis reflects well the degree of vegetation consumption by fire, but cannot adequately predict the degree of ground litter consumption, associated soil heating and repellency effects. Fire had varying effects on repellency, leaving it unchanged, destroying it or enhancing it, depending on the soil temperature reached. The main post-fire hydrogeomorphological changes have been widespread erosion and colluvial and alluvial deposition of topsoil in foot-slope locations and river systems, but only localised redistribution of the highly erodible, repellent sandy subsurface layer. The fire did not trigger major geomorphological change in the study area, but fires probably cause important topsoil and nutrient depletion and may also affect water quality.     

THE STUDY OF THE GENESIS OF SURFACE WATERS BY OBSERVING THEIR ELECTRICAL RESISTIVITIES*

Specific electrical resistivity of natural waters contains information on their genesis. The authors propose to conduct mass and regime observations of this parameter in river and stream beds. The electrical resistivities in streams flowing from under a glacier reveal details formed at the same time as the glacier. Observations in the beds of big rivers show a gradual increase in water salinity overlain by reductions by inflowing glacial waters. The diurnal and annual trend of changes in the electrical conductivity of water associated with the change in the balance of glacial and ground waters has been established near to glaciers. Resistivity observations help to locate discharge sites of sub-permafrost waters, for water.     

Tropical Deforestation and Climate Change: What Does the Record Reveal?

Tropical deforestation is widely believed to directly influence the climate at a number of scales. Yet while much has been written about the tropical forest-climate relationship, there is little empirical evidence showing if and how local and regional climates are modified by deforestation. This study presents the results of an analysis of deforestation and climate change in a rain forest in southern Mexico. Records from 18 climate stations in the Selva Lacandona of Chiapas, Mexico were examined and related to an analysis of deforestation based on Landsat images. The area surrounding some stations has been deforested since the stations were established, while the area surroundings others has remained forested. Strong climatic trends were generally evident at the deforested stations, including decreases in the average daily maximum temperature and temperature range. No precipitation changes were observed. A comparison of the results with microclimatic experiments and modeling studies suggests that the climatic impacts of deforestation are overgeneralized at the local scale. Landscape heterogeneity appears to influence the biophysical mechanisms linking tropical forests and climate, and should be explicitly represented in modeling studies.     

Flow and form in rehabilitation of large-river ecosystems: An example from the Lower Missouri River

On large, intensively engineered rivers like the Lower Missouri, the template of the physical habitat is determined by the nearly independent interaction of channel form and flow regime. We evaluated the interaction between flow and form by modeling four combinations of modern and historical channel form and modern and historical flow regimes. The analysis used shallow, slow water (shallow-water habitat, SWH, defined as depths between 0 and 1.5 m, and current velocities between 0 and 0.75 m/s) as an indicator of habitat that has been lost on many intensively engineered rivers and one that is thought to be especially important in rearing of young fishes. Two-dimensional hydrodynamic models for modern and historical channels of the Lower Missouri River at Hermann, Missouri, indicate substantial differences between the two channels in total availability and spatial characteristics of SWH. In the modern channel, SWH is maximized at extremely low flows and in overbank flows, whereas the historical channel had substantially more SWH at all discharges and SWH increased with increasing discharge. The historical channel form produced 3–7 times the SWH area of the modern channel regardless of flow regime. The effect of flow regime is evident in increased within-year SWH variability with the natural flow regime, including significant seasonal peaks of SWH associated with spring flooding. Comparison with other reaches along the Lower Missouri River indicates that a) channel form is the dominant control of the availability of habitat even in reaches where the hydrograph is more intensively altered, and b) rehabilitation projects that move toward the historical condition can be successful in increasing topographic diversity and thereby decreasing sensitivity of the availability of habitat to flow regime. The relative efficacy of managing flow and form in creating SWH is useful information toward achieving socially acceptable rehabilitation of the ecosystem in large river systems.