Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.     

Space–time distribution of ancient and active alluvial karst subsidence: examples from the central Ebro Basin,Spain

Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines), aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times. According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast, rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not have an equivalent in observed paleodolines.     

Problems of soil and groundwater pollution in the disposal of “marble” slurries in NW Sicily

This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction, simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis. Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that, even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled as secondary raw material for a suitable process.     

Bedrock, soils, and hillslope hydrology in the Central Texas Hill Country, USA: implications on environmental management in a carbonate-rock terrain

The Hill Country of Central Texas, USA, is undergoing rapid socioeconomic development, but environmental management of this region is hampered by misconceptions about local bedrock, soils, terrain, and hydrologic processes. The Hill Country is underlain mostly by Glen Rose Limestone (Lower Cretaceous) and exhibits a stepped terrain, which has been incorrectly attributed to alternating hard and soft bedrock strata. Other characteristics mistakenly attributed to this landscape include thin soils with scant water-retention capabilities, and rapid runoff as the dominant hydrologic process. This report presents new findings: unweathered bedrock is well indurated, but interbeds exhibit variable weathering rates. Recessive slopes (“risers”) on this stepped terrain result from rapid deterioration of strata having generally heterogeneous depositional fabrics (bioturbation and irregular clay partings) in contrast to ledge-forming strata having homogeneous fabrics. A stony regolith is thus formed beneath risers, providing porous and permeable ground that retards runoff and promotes the formation of moderately deep to deep (two-tiered) regolith/soil zones. These surficial materials on local steep slopes compose important natural environmental buffers; they support diverse biota and enhanced geochemical cycling of nutrients; they also exhibit significant water retention and enhanced erosion abatement. Proper land management demands recognition of these attributes in the siting, design, and construction of facilities.     

Numerical modeling assessment of three-gate structures for capturing contaminated groundwater

This modeling study evaluated the capability of alternative funnel-and-gate structures with three gates for capturing contaminated groundwater in a hypothetical unconfined aquifer. Simulated interceptor structures were linear and 45 m wide, consisting of three gates and two funnels (walls). One gate occupied the center and two gates occupied the ends of the interceptor structures. The structures, positioned perpendicular to regional groundwater flow, traversed the entire thickness of the aquifer. A total of four structures were evaluated (numbers designate widths of end, center, and end gates, respectively, in meters): 3-3-3, 2-5-2, 1-7-1, and 4-1-4. Particle tracking and zonal water budgets identified shapes of capture zones and discharge patterns for each interceptor structure. A mass transport model, accounting for advection and hydrodynamic dispersion, tested the capability of each structure for capturing a contaminant plume. Results suggest that: time-dependent capture zones underestimate the amount of time to capture a contaminant plume, wide center gates facilitate plume capture, and wide end gates facilitate lateral containment of contaminants. Of the structures simulated, the 2-5-2 configuration was relatively efficient at processing and containing the simulated contaminant plume.     

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.     

Spatial data for landslide susceptibility, hazard, and vulnerability assessment: An overview

The aim of this paper is to discuss a number of issues related to the use of spatial information for landslide susceptibility, hazard, and vulnerability assessment. The paper centers around the types of spatial data needed for each of these components, and the methods for obtaining them. A number of concepts are illustrated using an extensive spatial data set for the city of Tegucigalpa in Honduras. The paper intends to supplement the information given in the “Guidelines for Landslide Susceptibility, Hazard and Risk Zoning for Land Use Planning” by the Joint ISSMGE, ISRM and IAEG Technical Committee on Landslides and Engineered Slopes (JTC-1). The last few decades have shown a very fast development in the application of digital tools such as Geographic Information Systems, Digital Image Processing, Digital Photogrammetry and Global Positioning Systems. Landslide inventory databases are becoming available to more countries and several are now also available through the internet. A comprehensive landslide inventory is a must in order to be able to quantify both landslide hazard and risk. With respect to the environmental factors used in landslide hazard assessment, there is a tendency to utilize those data layers that are easily obtainable from Digital Elevation Models and satellite imagery, whereas less emphasis is on those data layers that require detailed field investigations. A review is given of the trends in collecting spatial information on environmental factors with a focus on Digital Elevation Models, geology and soils, geomorphology, land use and elements at risk.     

A new method of estimating the ratio between in situ rock stresses and tectonics based on empirical and probabilistic analyses

This paper describes a new procedure for assessing the ratio between in situ stresses in rock masses by means of K (K = σ_H / σ_v, being σ_H and σ_v principal stress) and tectonics for purposes of engineering geology and rock mechanics. The method combines the use of the logic decision tree and the empirical relationship between the Tectonic Stress Index, TSI, and a series of K in situ values obtained from an extensive database. The decision tree considers geological and geophysical factors affecting stress magnitudes both on the regional and local scale. The TSI index is defined by geological and geomechanical parameters. The method proposed provides an assessment of the magnitude of horizontal stresses of tectonic origin. Results for several regions of Europe are presented and the possible applications of the procedure are discussed.     

Design of shallow foundations under tensile loading for transmission line towers: An overview

Tensioned foundations are common in civil engineering applications such as transmission towers, harbors, offshore structures, basement slabs under pressure, industrial equipment, etc. Procedures for the design of tensioned foundations are discussed in this paper, including specific recommendations for more common transmission tower foundations. Starting from a distinction between shallow and deep modes of failure, the paper presents the most common failure mechanisms for shallow failure in tension, including procedures for calculation of foundation tensile capacity under vertical and inclined loading. Emphasis is given to the influence of the strength of the compacted backfill compared to the strength of the natural soil, including presentation of results of full-scale loading tests.