Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

The age of the Lower Carboniferous conglomerate at Lligwy Bay,Anglesey

The Lower Carboniferous conglomerate at Lligwy Bay, Anglesey, is shown to be underlain as well as overlain by limestones of D₁ age so that the conglomerate is of intra-D₁ age. It is considered to have been deposited very close to a coastline.     

Zur Dynamotheorie stellarer und planetarer Magnetfelder I. Berechnung sonnenähnlicher Wechselfeldgeneratoren

Non-reflectionsymmetric turbulent motions in an electrically conducting fluid provide for an average electromotoric force α parallel to the average magnetic field . This effect – furthermore called α-effect – can lead to a self-excited built-up of magnetic fields by dynamo action. Since by actions of Coriolis forces turbulent motions in rotating systems generally are non-reflectionsymmetric, the explanation of stellar and planetary magnetic fields becomes possible. – In this first part spherical alternating field dynamos are calculated on conditions similar to those at the sun; α-effect and differential rotation provide for dynamo action. – The basic equations, which form a system of partial differential equations, are treated by a separation method; in this way our problem is transformed into a two-parametric eigenvalue problem for an infinite system of ordinary differential equations. The two eigenvalues determine the frequency and the amount of the induction actions necessary for the field maintenance. The solution of this problem was made by an electronic computer. – The results give evidence for the possibility of magnetohydrodynamic alternating field dynamos. Furthermore the magnitude of the calculated eigenvalues and the similarities between the calculated field and the observed solar magnetic field are showing that the sun realizes a dynamo of this kind.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

金塔绿洲风场与温湿场特征的数值模拟

使用美国NCAR新版MM5V3.6非静力平衡模式,采用三重嵌套的降尺度方法,模拟研究了甘肃河西走廊金塔绿洲风场与温湿场特征。结果表明:由于绿洲的存在,绿洲沙漠系统产生的次级环流对局地环流有一定影响;平流作用将沙漠中的干热空气送向绿洲,绿洲近地层会出现逆温,感热向地表输送;沙漠上由于临近绿洲的水汽平流作用,上层大气湿度比低层更大,这就是逆湿现象。     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Desert vegetation and timing of solar radiation

Timing and amount of solar radiation were examined as factors influencing the distribution of seven perennial plants on a small mountain located in the Chihuahuan Desert. Average direct beam solar radiation fluxes at differing times throughout the day and year were estimated with computer calculations. Principal components analysis was used to reduce the number of solar radiation parameters and include the maximum available information with a manageable number of variables. The remaining solar radiation parameters were compared to plant distributions using redundancy analysis and generalized additive models. Unimodal, bimodal, and monotonic responses were all found depending upon the species and solar radiation parameter. Niche separation at this location depends upon the timing as well as the amount of solar radiation.     

Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.