Axial convergence in a well-mixed estuary

Transverse secondary circulations involving surface convergence, observed in a well-mixed estuary in North Wales, are made visible by the collection of surface material along an axial line which extends continuously for many kilometres through the estuary. The circulation and axial convergence, however, are seen only during the flood phase of the tide and no similar behaviour has been observed during the ebb phase.Convergent circulations in the estuary are associated with small but steady transverse density gradients in the cross-section, produced by non-uniform advection of the longitudinal gradient through the channel. A diagnostic model, using measured mean distributions of cross-sectional density, indicates surface transverse velocities (～0.1 ms^?1) similar to those observed in the estuary. The model further predicts appreciable transverse divergent currents at a fractional depth of 0.75: a prediction which has been tested in the estuary using a vertical array of accurately resolving current direction indicators.     

The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.     

Reef exploration in the East Sengkang Basin,Sulawesi, Indonesia

Reconnaissance seismic shot in 1971/72 showed a number of well defined seismic anomalies within the East Sengkang Basin which were interpreted as buried reefs. Subsequent fieldwork revealed that Upper Miocene reefs outcropped along the southern margin of the basin. A drilling programme in 1975 and 1976 proved the presence of shallow, gas-bearing, Upper Miocene reefs in the northern part of the basin. Seismic acquisition and drilling during 1981 confirmed the economic significance of these discoveries, with four separate accumulations containing about 750 × 10⁹ cubic feet of dry gas in place at an average depth of 700 m. Kampung Baru is the largest field and contains over half the total, both reservoir quality and gas deliverability are excellent. Deposition in the East Sengkang Basin probably started during the Early Miocene. A sequence of Lower Miocene mudstones and limestones unconformably overlies acoustic basement which consists of Eocene volcanics. During the tectonically active Middle Miocene, deposition was interrupted by two periods of deformation and erosion. Carbonate deposition became established in the Late Miocene with widespread development of platform limestones throughout the East Sengkang Basin. Thick pinnacle reef complexes developed in the areas where reef growth could keep pace with the relative rise in sea level. Most reef growth ceased at the end of the Miocene and subsequent renewed clastic sedimentation covered the irregular limestone surface. Late Pliocene regression culminated in the Holocene with erosion. The Walanae fault zone, part of a major regional sinistral strike-slip system, separates the East and West Sengkang Basins. Both normal and reverse faulting are inferred from seismic data and post Late Pliocene reverse faulting is seen in outcrop.     

Microstructures of co-axially folded vein segments and crenulation cleavage： Evidence for dissolution phenomena in the Chamba Thrust Sheet, western Himalayas

The metasediments in the Chamba region experienced three phases of deformation: DF1, DF2 and DF3.Folded quartz veins are co-folded with the F2 crenulation folds. Their geometric and tectonic significance is studied by microstructures and shortening adjacent to the discrete crenulation cleavage, S2. Microstructures of folded vein segments, their geometric changes and truncation to cleavage (S2) are mainly due to pressure-solution phenomena and the estimated volume loss from reconstructed vein segments range from 16 to 25.5%,which is closely related to volume decrease (26%) calculated from the polydeformed slates of North Wales areas.     

Ultraviolet reflectance properties of asteroids

An analysis of the UV spectra of 28 asteroids obtained with the Internal Ultraviolet Explorer (IUE) satellite is presented. The spectra lie within the range 2100–3200 Å. Our results are examined in terms of both asteroid classification and of current ideas concerning the surface mineralogy of asteroids. For all the asteroids examined, UV reflectivity declines approximately linearly toward shorter wavelengths. In general, the same taxonomic groups are seen in the UV as in the visible and IR, although there is some evidence for asteroids with anomalous UV properties and for UV subclasses within the S class. No mineral absorption features are reported of strength similar to the strongest features in the visible and IR regions, but a number of shallow absorptions do occur and may provide valuable information on the surface composition of many asteroids.     

Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.