A study on the preparation of fine and low soda alumina

A simple process to produce fine and low soda α-alumina (α-Al₂O₃) from a commercial grade aluminium trihydroxide (gibbsite, Al(OH)₃) produced by KC Corporation Ltd was developed. There are two options for this process with the first one producing low soda α-alumina (< 0.05% Na₂O) having a mean particle size of 50 μm. The second option yields a fine product with a mean size of less than 10 μm. In the first option, a plant aluminium trihydroxide containing 0.20% Na₂O was first fluidized with nitrogen at 400–600 °C to yield an amorphous activated alumina. This intermediate product was then treated with acetic or oxalic acid, washed with water and heated to 1200 °C to form calcined α-alumina, having a Na₂O content of less than 0.05%. A 20 min leaching using 0.2 M acetic or oxalic acid could yield an alumina product containing 0.04% Na₂O. In the second option, a new technique for the preparation of fine and low soda α-alumina was evaluated using an attrition mill working also as a leaching vessel at 80 °C. Fine (< 10 μm in mean particle size) and low soda (< 0.04% Na₂O) alumina was produced by a 20 min leaching step with 0.2 M acetic acid and concurrent attrition milling.     

Eastern Asian hydrometeorology simulation using the Regional Climate System Model

We present the hydrometeorology of eastern Asia during April 1995 simulated by the Regional Climate System Model. The amount and location of simulated monthly precipitation agrees well with observations. Soil water content variation was closely correlated with precipitation. Land-surface evaporation and the surface energy budget were strongly controlled by soil moisture content. A sensitivity test with reduced initial soil moisture content suggested that near-surface soil moisture spins up quickly after heavy precipitation events. However, variations in the initial soil moisture field may alter details of the simulated precipitation which can introduce further complexity in climate simulations.     

Geostatistical integration of MT and borehole data for RMR evaluation

The geostatistical approach was applied to integrate MT (Magneto-telluric) resistivity data and borehole information for the spatial RMR (Rock Mass Rating) evaluation. Generally, resistivity of the subsurface is believed to be positively related to the RMR, thus the resistivity and borehole RMR information was combined in a geostatistical approach. To relate the two different sets of data, the MT resistivity data were used as secondary information and the RMR mean values were estimated at unsampled points by identification of the resistivity to the borehole data. Two types of approach are performed for the estimation of RMR mean values. Then the residuals of the RMR values around the borehole sites are geostatistically modeled to infer the spatial structure of difference between real RMR values and estimated mean values. Finally, this geostatistical estimation is added to the previous means. The result applied to a real situation shows prominent improvements to reflect the subsurface structure and spatial resolution of RMR information.     

Effect of boundary element details on the seismic deformation capacity of structural walls

The objective of this study is to investigate the effect of boundary element details of structural walls on their deformation capacities. Structural walls considered in this study have different sectional shapes and/or transverse reinforcement content at the boundaries of the walls (called boundary element details hereafter). Four full‐scale wall specimens (3000mm (h_w)×1500mm (l_w)×200mm (T)) were fabricated and tested. Three specimens are rectangular in section and the other specimen has a barbell‐shaped cross‐section (a wall with boundary columns). The rectangular wall specimens are reinforced according to the common practice used for reinforced concrete residence buildings in Korea and Chile. In this study, the primary variable for these rectangular specimens is the content of transverse reinforcement to confine the boundary elements of a wall. The barbell‐shaped specimen was designed in compliance with ACI 318‐95. The response of the barbell‐shaped specimen is compared with those of other rectangular specimens. The effective aspect ratio of the specimens is set to two in this study. Based on the experimental results, it is found that the deformation capacities of walls, which are represented by displacement ductility, drift ratio and energy dissipation capacities, are affected by the boundary element details. Copyright © 2002 John Wiley & Sons, Ltd.     

Summer monsoon rainfall patterns over South Korea and associated circulation features

Summary Seasonal summer monsoon (June through August) rainfall patterns over South Korea are classified by an objective method using data for a 40-year period (1961–2000). The rainfall patterns are represented by the percentage departures from the normal rainfall of 12 stations spread uniformly over South Korea. The statistical technique employed is the k-means (KM) clustering method. The Euclidean distance has been used as a measure of similarity between the patterns. Four dominant types are obtained by this method. Intercorrelations among the types suggest that the dominant patterns are distinct. The summer monsoon rainfall shows an increasing trend. Investigation of the physical processes associated with these patterns using NCEP/NCAR Reanalysis data clearly reveals contrasting circulation features associated with the dominant types during the summer monsoon period. In particular, contrasting circulation features are related to the position, shape and strength of the North Pacific Subtropical High. Received October 30, 2000 Revised November 12, 2001     

Effects of surfactants and electrolyte solutions on the properties of soil

Biosurfactants are frequently used in petroleum hydrocarbon and dense non-aqueous phase liquids (DNAPLs) remediation. The applicability of biosurfactant use in clayey soils requires an understanding and characterization of their interaction. Comprehensive effects of surfactants and electrolyte solutions on kaolinite clay soil were investigated for index properties, compaction, strength characteristics, hydraulic conductivities, and adsorption characteristics. Sodium dodecyl sulfate (SDS) and NaPO₃ decreased the liquid limit and plasticity index of the test soil. Maximum dry unit weights were increased and optimum moisture contents were decreased as SDS and biosurfactant were added for the compaction tests for mixtures of 30% kaolinite and 70% sand. The addition of non-ionic surfactant, biosurfactant, and CaCl₂ increased the initial elastic modulus and undrained shear strength of the kaolinite–sand mixture soils. Hydraulic conductivities were measured by fixed-wall double-ring permeameters. Results showed that the hydraulic conductivity was not significantly affected, but slightly decreased from 1×10⁻⁷ cm/s (water) to 0.3×10⁻⁷ cm/s for Triton X-100 and SDS. The adsorption characteristics of the chemicals onto kaolinite were also investigated by developing isotherm curves. SDS adsorbed onto soil particles with the strongest bonding strength of the fluids tested. Correlations among parameters were developed for surfactants, electrolyte solutions, and clayey soils.     

Large seasonal changes in the recharge of seawater in a subterranean estuary revealed by a radon tracer

Activities of radon (²²²Rn) in groundwater were continuously monitored in a saline aquifer from September 2010 to July 2011. The activities of ²²²Rn ranged from 200 to 4300 Bq m^?3, with a large seasonal variation. Because the activity of ²²²Rn in seawater is low, ²²²Rn in saline groundwater must be produced in the aquifer from radium (²²⁶Ra) in rocks and sediments. The ²²²Rn activities were higher in the warm‐dry seasons (September–November 2010 and April–May 2011) when the saline aquifer was stable. In contrast, the lowest ²²²Rn activities were observed in the cold‐dry season (December 2010 and January–March 2011), because of the effective exchange between groundwater and seawater. In addition, sudden decreases of ²²²Rn activities coincided with episodic drops in groundwater temperatures. These results reveal that lower seawater temperature in winter may result in density‐driven seawater intrusion. During the wet season (June–July 2011), ²²²Rn activities were more clearly affected by semi‐monthly and diurnal tidal pumping, showing higher ²²²Rn activities during low and spring tides. Such a tidal effect was not clearly observed during the warm‐dry and cold‐dry seasons. This result implies that the residence time of SGD in coastal zones is significantly affected by seasonal changes in driving forces such as tidal pumping and seawater intrusion. Copyright © 2016 John Wiley & Sons, Ltd.     

An analysis on movement patterns between zones using smart card data in subway networks

Identifying zones and movement patterns of people is crucial to understanding adjacent regions and the relationship in urban areas. Most previous studies addressed zones or movement patterns separately without analysing simultaneously the two issues. In this article, we propose an integrated approach to discover directly both zones and movement patterns among the zones, referred to as movement patterns between zones (MZPs), from historical boarding behaviours of passengers in subway networks by using an agglomerative clustering method. In addition, evaluation measures of MZPs are suggested in terms of coverage and accuracy. The effectiveness of the proposed approach is finally demonstrated through a real-world data set obtained from smart cards on a subway network in Seoul, Korea.