Influence of salinity on permeability characteristics of marine sediments

Abstract

Laboratory tests were conducted on compacted marine sediments to study the effect of salt concentration of permeating fluid on its permeability characteristics. Deep sea sediment samples were collected from water depths varying from 3700 to 4500 m off Mauritius coast. Liquid limit and plasticity index varied widely from 45 to 75 and 10 to 35, respectively. Permeability was found at different void ratios with distilled water and 0.2, 0.4, and 0.8 N NaCl solutions as permeating fluid. It was found that permeability increases with an increase in salt concentration for a given void ratio. This is explained by diffused double layer theory. Also, the rate of increase in permeability decreases with increase in salt concentration. The effect of salt concentration seemed to be less at higher void ratios.     

On the formation of cluster radio relics

In several merging clusters of galaxies so-called cluster radio relics have been observed. These are extended radio sources which do not seem to be associated with any radio galaxies. Two competing physical mechanisms to accelerate the radio-emitting electrons have been proposed: (i) diffusive shock acceleration and (ii) adiabatic compression of fossil radio plasma by merger shock waves. Here the second scenario is investigated. We present detailed three-dimensional magneto-hydrodynamical simulations of the passage of a radio plasma cocoon filled with turbulent magnetic fields through a shock wave. Taking into account synchrotron, inverse Compton and adiabatic energy losses and gains, we evolved the relativistic electron population to produce synthetic polarization radio maps. On contact with the shock wave the radio cocoons are first compressed and finally torn into filamentary structures, as is observed in several cluster radio relics. In the synthetic radio maps the electric polarization vectors are mostly perpendicular to the filamentary radio structures. If the magnetic field inside the cocoon is not too strong, the initially spherical radio cocoon is transformed into a torus after the passage of the shock wave. Very recent, high-resolution radio maps of cluster radio relics seem to exhibit such toroidal geometries in some cases. This supports the hypothesis that cluster radio relics are fossil radio cocoons that have been revived by a shock wave. For a late-stage relic the ratio of its global diameter to the filament diameter should correlate with the shock strength. Finally, we argue that the total radio polarization of a radio relic should be well correlated with the three-dimensional orientation of the shock wave that produced the relic.     

Bizarre geochemistry of komatiites from the Crixás greenstone belt,Brazil

Komatiite lava flows in the Crixás greenstone belt, Goiás, Brazil, have textures and volcanic structures typical of Archean komatiites, but are geochemically most unusual. The flows are porphyritic and massive, or layered with spinifex upper parts and olivine cumulate lower parts. MgO contents range from 18 to 40%. In such lavas, only olivine (and minor chromite) can have crystallized, but neither major nor trace elements fall on olivine control lines. In MgO variation diagrams, CaO and Sr fall on lines with slopes steeper than olivine control lines; SiO₂, FeO, Na₂O, K₂O and Y show little systematic variation; Zr shows a large variation that does not correlate with MgO; and Al₂O₃ decreases markedly with decreasing MgO. The aberrant behaviour is highlighted by the REE (rare earth elements) in spinifex and olivine cumulate layers from three flows: in the spinifex layers, chondrite-normalized REE patterns are hump-shaped with maxima at Nd or Sm ((La/Sm)_N=0.6, (Gd/Yb)_N=1.6–2.3), whereas cumulate zones in the same flows have steadily sloping patterns, with LREE enriched relative to HREE ((La/Sm)_N=1.3, (Gd/Yb)_N=1.4). Neither normal magmatic processes acting during emplacement of the komatiites, nor thermal erosion and wall-rock assimilation can explain these effects, and we speculate that elements commonly thought of as “immobile” (e.g. Al, Zr, REE) migrated during hydrothermal alteration or metamorphism. A Pb-Pb whole rock isochron gave an age of 2,728±140 Ma and selected Sm-Nd analyses an apparent isochron age of 2,825±98 Ma (ɛ_Nd≈0). The Pb-Pb age is believed to be the approximate time of emplacement. Interpretation of the Sm-Nd data is complicated by the evidence of mobility of REE.     

Site effect on vulnerability of high-rise shear wall buildings under near and far field earthquakes

Worldwide experience repeatedly shows that damages in structures caused by earthquakes are highly dependent on site condition and epicentral distance. In this paper, a 21-storey shear wall-structure built in the 1960s in Hong Kong is selected as an example to investigate these two effects. Under various design earthquake intensities and for various site conditions, the fragility curves or damage probability matrix of such building is quantified in terms of the ductility factor, which is estimated from the ratio of storey yield shear to the inter-storey seismic shear. For high-rise buildings, a higher probability of damage is obtained for a softer site condition, and damage is more severe for far field earthquakes than for near field earthquakes. For earthquake intensity of VIII, the probability of complete collapse (P) increases from 1 to 24% for near field earthquakes and from 1 to 41% for far field earthquakes if the building is moved form a rock site to a site consisting a 80 m thick soft clay. For intensity IX, P increases from 6 to 69% for near field earthquake and from 14 to 79% for far field earthquake if the building is again moved form rock site to soft soil site. Therefore, site effect is very important and not to be neglected. Similar site and epicentral effects should also be expected for other types of high-rise structures.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

THE BEGINNING OF THE USING OF ZINC IN CHINA.

In my work, Lapidarium Sinicum, the chapter on brass is speciallydevoted to this inquiry. Recently Dr. Read of the U. S. Bureau of Mineswrote to Dr. Ting, suggesting the question whether "The knowledge ofzinc-smelting in India is previous to that developed in China." Therefore     

Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

A pockmark field in the Patras Gulf (Greece) and its activation during the 14/7/93 seismic event

During a recent oceanographical-geophysical survey carried out in the southeastern part of the Gulf of Patras in Western Greece for the construction of an outfall, an active pockmark field was found. The pockmark field was formed in soft layered Holocene silts. The pockmarks are associated with acoustic anomalies attributed to gas-charged sediments. The pockmarks vary in size and shape from 25 to 250 m in diameter and from 0.5 to 15 m in depth and are among the largest and deepest observed in the world.

On July 14th, 1993, during the survey, a major earthquake of magnitude 5.4 on the Richter scale occurred in the area. During the 24 hour period prior to the earthquake the bottom water temperature anomalously increased on three occasions, whilst for a few days after the earthquake it was noted that the majority of the pockmarks were venting gas bublles.

It is considered that the three abrupt sea-water temperature increases were probably the result of upward migrating high-temperature gas bubbles in the water column. It is further suggested that the earthquake was the triggering mechanism and that the gas expulsion was caused by the reduction in the pore volume in the sediments resulting from changes in the stress regime prior to the earthquake. Therefore, it can be suggested that in seismic areas adjacent to pockmark fields, earthquake prediction may be achieved by monitoring the water temperature and/or the rate of gas venting in the pockmark field.

Our analysis indicates that the pockmark field in the Patras Gulf has formed slowly during the Holocene by continuous gas venting, which is periodically being interrupted by short-duration events of enhanced gas seepage triggered by earthquakes.