Rare earth element geochemistry of Late Cenozoic alkaline lavas of the McMurdo Volcanic Group, Antarctica

Rare earth element (REE) concentrations were determined in 16 Ross Island and northern Victoria Land alkaline lava samples which were representative of four lava lineages of the McMurdo Volcanic Group, Antarctica. A kaersutite and two feldspar mineral separates were also analysed.

Two of the lava lineages, a basanite to nepheline benmoreite and a basanite to phonolite, have similar chondrite-normalized REE fractionation patterns, with a continuous enrichment of light and heavy REE and depletion of middle REE. The patterns result from the fractionation of olivine, clinopyroxene, spinels, feldspar, kaersutite and apatite. Kaersutite is an important fractionated phase responsible for the middle REE depletion.

Another of the lava lineages is mildly potassic with trachyandesite to peralkaline K-trachyte lavas which have partly overlapping REE fractionation patterns. There is a depletion in REE from tristanite to K-trachyte. Fractionation of olivine, clinopyroxene, feldspar and apatite probably control the REE chemistry of the lineage, greater degrees of apatite fractionation deplete the K-trachyte in REE relative to the tristanite. Feldspar fractionation in the genesis of the peralkaline K-trachyte is shown by a large negative Eu anomaly (Eu/Eu* = 0.10).

A nepheline hawaiite to anorthoclase phonolite lava lineage from the Erebus Centre shows enrichment of REE, although minor overlapping in the middle REE does occur. Anorthoclase phonolite has a positive Eu anomaly (Eu/Eu* = 1.31), indicating possible accumulation of anorthoclase. The lineage resulted from fractionation of olivine, clinopyroxene, magnetite and apatite.     

印尼Ertsberg地区斑岩型、矽卡岩型、交代型矿床中的贵金属矿物学

印度尼西亚伊里安查亚中西部的 Ertsberg地区位于新几内亚岛中央山脉中,距阿拉弗拉海120km.本区的矿床为新几内亚地区主要的Au±Cu矿床,包括多组矿体,与这些矿体相伴的是侵入于中-新生代沉积序列的年龄为4~2.5 Ma的过渡成分侵入体     

An Augmented Norm Activation Model: The Case of Residential Outdoor Water Use

Understanding the factors that influence voluntary conservation is critical for developing effective residential water conservation policy. Previous work drawing on Schwartz’s Norm Activation Model (NAM) has been useful to understand some of these factors. However, one’s relationship with the broader community impacted by consumptive decisions has often been overlooked. Similarly, scholars have emphasized the importance of contextual factors not captured in the NAM. In this study we hypothesize and test an augmented NAM that incorporates community attachment, along with contextual variables (sociodemographic and household infrastructure), to understand the factors that lead to the development of moral obligations to conserve water and their relationship with residential outdoor water use. Results indicate personal norms, defined as a moral obligation to conserve water, are negatively related to outdoor water use, and that community attachment is a predictor of personal norms. Contextual factors are found to have an influence on outdoor water use.     

Prospectivity Modeling for Cambrian–Ordovician Hydraulic Fracturing Sand Resources Around The Llano Uplift,Central Texas

Cambrian–Ordovician strata in Central Texas are a major source of specialty sand for hydraulic fracturing and have potential to play a bigger role in proppant supply to markets in and around Texas. Sandstone in the Hickory Member of the Riley Formation is suitable in compressive strength, as well as grain size and shape to be used as proppant. The Hickory sandstone forms the basal sequence that non-conformably overlies the Precambrian basement and is a complex succession of terrestrial and transgressive marine arkosic to quartz arenitic sands and silts. The quantity and location of sand resources in the Central Texas Frac Sand district is illustrated through geospatial volumetric techniques and estimated at 5 billion tonnes of proppant material. The prospectivity modeling of favorable characteristics of existing resource locations is applied to determine new sites for resource development and locate and quantify the abundance of prospective natural sand resources in the Central Texas Frac Sand district.     

Sediment storage and severity of contamination in a shallow reservoir affected by historical lead and zinc mining

A combination of sediment-thickness measurement and bottom-sediment coring was used to investigate sediment storage and severity of contamination in Empire Lake (Kansas), a shallow reservoir affected by historical Pb and Zn mining. Cd, Pb, and Zn concentrations in the contaminated bottom sediment typically exceeded baseline concentrations by at least an order of magnitude. Moreover, the concentrations of Cd, Pb, and Zn typically far exceeded probable-effects guidelines, which represent the concentrations above which toxic biological effects usually or frequently occur. Despite a pre-1954 decrease in sediment concentrations likely related to the end of major mining activity upstream by about 1920, concentrations have remained relatively stable and persistently greater than the probable-effects guidelines for at least the last 50 years. Cesium-137 evidence from sediment cores indicated that most of the bottom sediment in the reservoir was deposited prior to 1954. Thus, the ability of the reservoir to store the contaminated sediment has declined over time. Because of the limited storage capacity, Empire Lake likely is a net source of contaminated sediment during high-inflow periods. The contaminated sediment that passes through, or originates from, Empire Lake will be deposited in downstream environments likely as far as Grand Lake O’ the Cherokees (Oklahoma).     

Peripheral communities of the Eastern Lau Spreading Center and Valu Fa Ridge: community composition,temporal change and comparison to near‐vent communities

Western Pacific hydrothermal vents will soon be subjected to deep‐sea mining and peripheral sites are considered the most practical targets. The limited information on community dynamics and temporal change in these communities makes it difficult to anticipate the impact of mining activities and recovery trajectories. We studied community composition of peripheral communities along a cline in hydrothermal chemistry on the Eastern Lau Spreading Center and Valu Fa Ridge (ELSC‐VFR) and also studied patterns of temporal change. Peripheral communities located in the northern vent fields of the ELSC‐VFR are significantly different from those in the southern vent fields. Higher abundances of zoanthids and anemones were found in northern peripheral sites and the symbiont‐containing mussel Bathymodiolus brevior, brisingid seastars and polynoids were only present in the northern peripheral sites. By contrast, certain faunal groups were seen only in the southern peripheral sites, such as lollipop sponges, pycnogonids and ophiuroids. Taxonomic richness of the peripheral communities was similar to that of active vent communities, due to the presence of non‐vent endemic species that balanced the absence of species found in areas of active venting. The communities present at waning active sites resemble those of peripheral sites, indicating that peripheral species can colonize previously active vent sites in addition to settling in the periphery of areas of venting. Growth and mortality were observed in a number of the normally slow‐growing cladorhizid stick sponges, indicating that these animals may exhibit life history strategies in the vicinity of vents that differ from those previously recorded. A novel facultative association between polynoids and anemones is proposed based on their correlated distributions.