Organization of amphiphiles, Part VIII: Role of polyoxyethylated alkylphenols in optimizing the beneficiation of hydrophilic mineral

The floatability of silica has been determined by adsorbing various concentrations of a series of polyoxyethylated nonyl and octyl alkyl phenols of varying oxyethylene units (10–40 units) to investigate the role of adsorbed layer. It is seen that the floatability of silica increases with increase in concentration till a maximum of  90% in premicellar region and then decrease to minimum of 40–45% in all cases in spite of the significant differences in adsorption densities. Zeta potential measurement reveals that a thin oxyethylene layer is formed at silica–water interface masking silica surface (Pramila K. Misra, P. Somasundaran, J. Surf. Deterg., Vol. 7, 2004, 373). This layer with oxyethylene units lying on silica surface and alkyl chain dangling to the bulk solution provides the same extent of hydrophobicity. The decrease in flotation recovery has been attributed to increase in the solvent hydrophobicity due to formation of premicellar aggregates and micelles.     

Analysis of pile subjected to torsion in multi‐layered soil

A new method of analysis of piles in multi‐layered elastic soil subjected to a torque at the head is developed. The differential equation governing the angle of twist in the pile is derived using the variational principles of mechanics. The method of initial parameters is used to obtain closed‐form solutions of the angle of twist and torque in the pile as a function of depth. The inputs required for the analysis are shear moduli of pile and soil, pile geometry and thickness of soil layers. Copyright © 2013 John Wiley & Sons, Ltd.     

Evaluation of dynamically downscaled reanalysis precipitation data for hydrological application

Skilful and reliable precipitation data are essential for seasonal hydrologic forecasting and generation of hydrological data. Although output from dynamic downscaling methods is used for hydrological application, the existence of systematic errors in dynamically downscaled data adversely affects the skill of hydrologic forecasting. This study evaluates the precipitation data derived by dynamically downscaling the global atmospheric reanalysis data by propagating them through three hydrological models. Hydrological models are calibrated for 28 watersheds located across the southeastern United States that is minimally affected by human intervention. Calibrated hydrological models are forced with five different types of datasets: global atmospheric reanalysis (National Centers for Environmental Prediction/Department of Energy Global Reanalysis and European Centre for Medium‐Range Weather Forecasts 40‐year Reanalysis) at their native resolution; dynamically downscaled global atmospheric reanalysis at 10‐km grid resolution; stochastically generated data from weather generator; bias‐corrected dynamically downscaled; and bias‐corrected global reanalysis. The reanalysis products are considered as surrogates for large‐scale observations. Our study indicates that over the 28 watersheds in the southeastern United States, the simulated hydrological response to the bias‐corrected dynamically downscaled data is superior to the other four meteorological datasets. In comparison with synthetically generated meteorological forcing (from weather generator), the dynamically downscaled data from global atmospheric reanalysis result in more realistic hydrological simulations. Therefore, we conclude that dynamical downscaling of global reanalysis, which offers data for sufficient number of years (in this case 22 years), although resource intensive, is relatively more useful than other sources of meteorological data with comparable period in simulating realistic hydrological response at watershed scales. Copyright © 2013 John Wiley & Sons, Ltd.     

Escalation of salinity levels in the quaternary aquifers of the Ganga alluvial plain,India

A detailed water quality analysis was carried out in the quaternary aquifer system of the marginal alluvial plain (Ganga Plain) in Bah Tahsil, Agra district, India. The electrical conductivity of 50 samples each from dug wells, hand pumps and tube wells was analysed for the study of salinity levels in shallow, intermediate and deep aquifers. Out of 50, 20 samples of each were also analysed for other chemical constituents such as Na⁺, K⁺, Cl⁻, F⁻ and TDS. The analyses show drastic changes in the salinity levels of shallow, intermediate and deep aquifers. The deep aquifers are more saline compared to the shallow and intermediate aquifers. On the contrary, the concentration of chemical constituents such as Na⁺, K⁺, Cl⁻ and F⁻ was more in the shallow aquifers compared to the deep aquifers. Moreover, there is an indication that the salinity and concentration of the above chemical constituents also escalate with time in each aquifer. The chemical constituents such as Na⁺, K⁺, Cl⁻, F⁻ and TDS range from 51 to 165 mg/l, 1 to 14 mg/l, 224 to 1,459 mg/l, 0 to 1.5 mg/l and 750 to 2,650 mg/l, respectively. Over a 3-year period, the salinity levels have sharply increased and the average F level has increased by 0.1–0.3 mg/l. An attempt has been made here to discuss the factors causing the variation and escalation of chemical constituents and salinity in the water of the three aquifers.     

Age of granitic activity associated with copper–molybdenum mineralization at Malanjkhand, Central India

The Malanjkhand copper–molybdenum deposit in the Bhandara Craton, Central India, is hosted by a granite complex which consists of regionally dominant grey granitoid and pink granitoid confined to the mineralized zone. New SHRIMP RG data on zircons from both granite types are inferred to have crystallized during the same magmatic pulse at ca 2.48 Ga. The discrepancy between zircon age and earlier obtained Rb–Sr whole-rock age is attributed to modification of the Rb–Sr system by hydrothermal overprint. Similarity in petrographic features and chemical affinity in combination with identical age strongly indicate that the pink granite is the hydrothermally altered variety (microclinization and silicification) of the grey granite. The spatially associated, main Cu–Mo mineralization event at Malankhand appears to be broadly contemporaneous with and genetically related to the emplacement of the host granitoids at about 2.48 Ga.     

Laboratory investigations on rotary diamond drilling

Extensive laboratory drilling investigations were conducted on a wide variety of rocks to study the inter-dependence of machine as well as rock parameters on the performance of the drilling operation. Detailed physical and mechanical properties of all the rock types were determined to study the influence of the rock properties on the drilling performance. The effect of PEO (poly-ethylene-oxide) added to the drilling water was also studied. Slake durability tests were conducted in plain water as well as a PEO mixed water medium to observe the effects of PEO on the surface properties of the rock. An attempt is also made to understand the different modes of wear of impregnated diamond bits in the rotary drilling operation.     

http://www.sciencedirect.com/science/article/pii/S1674987113000546

In the eastern part of the Indian shield,late PaleozoiceMesozoic sedimentary rocks of the Talchir Basin lie precisely along a contact of Neoproterozoic age between granulites of the Eastern Ghats Mobile Belt(EGMB)and amphibolite facies rocks of the Rengali Province.At present,the northern part of the basin experiences periodic seismicity by reactivation of faults located both within the basin,and in the Rengali Province to the north.Detailed gravity data collected across the basin show that Bouguer anomalies decrease from the EGMB(wt15 mGal),through the basin(w 10 mGal),into the Rengali Province(w 15 mGal).The data are consistent with the reportedly uncompensated nature of the EGMB,and indicate that the crust below the Rengali Province has a cratonic gravity signature.The contact between the two domains with distinct sub-surface structure,inferred from gravity data,coincides with the North Orissa Boundary Fault(NOBF)that defnes the northern boundary of the Talchir Basin.Post-Gondwana faults are also localized along the northern margin of the basin,and present-day seismic tremors also have epicenters close to the NOBF.This indicates that the NOBF was formed by reactivation of a Neoproterozoic terrane boundary,and continues to be susceptible to seismic activity even at the present-day.     

The seasonal predictability of the Asian summer monsoon in a two-tiered forecast system

An extensive set of boreal summer seasonal hindcasts from a two tier system is compared with corresponding seasonal hindcasts from two other coupled ocean–atmosphere models for their seasonal prediction skill (for precipitation and surface temperature) of the Asian summer monsoon. The unique aspect of the two-tier system is that it is at relatively high resolution and the SST forcing is uniquely bias corrected from the multi-model averaged forecasted SST from the two coupled ocean–atmosphere models. Our analysis reveals: (a) The two-tier forecast system has seasonal prediction skill for precipitation that is comparable (over the Southeast Asian monsoon) or even higher (over the South Asian monsoon) than the coupled ocean–atmosphere. For seasonal anomalies of the surface temperature the results are more comparable across models, with all of them showing higher skill than that for precipitation. (b) Despite the improvement from the uncoupled AGCM all models in this study display a deterministic skill for seasonal precipitation anomalies over the Asian summer monsoon region to be weak. But there is useful probabilistic skill for tercile anomalies of precipitation and surface temperature that could be harvested from both the coupled and the uncoupled climate models. (c) Seasonal predictability of the South Asian summer monsoon (rainfall and temperature) does seem to stem from the remote ENSO forcing especially over the Indian monsoon region and the relatively weaker seasonal predictability in the Southeast Asian summer monsoon could be related to the comparatively weaker teleconnection with ENSO. The uncoupled AGCM with the bias corrected SST is able to leverage this teleconnection for improved seasonal prediction skill of the South Asian monsoon relative to the coupled models which display large systematic errors of the tropical SST’s.     

K-Ar age of Ukra glauconites from the Kutch Basin, India

The present paper reports the K-Ar ages determined on glauconitic samples collected from the Ukra Member of the Mesozoic Bhuj Formation in two different sections, one located on the Ghuneri-Ghaduli road near Katesar Mahadeo temple and the other at the base of the Ukra hill in the northwestern part of the Kutch Mainland area. Three glauconite samples viz., Ukra_KT-1, Ukra_KT-4 and Ukra_UH-3 have yielded K-Ar ages of 107.9 ± 3.4 Ma, 105.5 ± 3.3 Ma and 103.5 ± 3.4 Ma, respectively. The sample Ukra_KT-l treated with 0.5N HC1 and analysed in duplicate has yielded a mean age of 104 ± 2.3 Ma while the sample Ukra_KT-4 treated with 0.1N HCl has given an age of 106.5 ± 3.3 Ma. The ages of the treated and untreated glauconites are indistinguishable within 2σ uncertainty with a mean of 105.2 ± 1.3 Ma, which has been interpreted as the depositional age of the Ukra Member of the Mesozoic Bhuj Formation. The study has further indicated that mild acid treatment (up to 0.5N HCl) does not lead to any loss of radiogenic argon in the glauconites and can be helpful in purification of the samples.