Mid-depth Lagrangian pathways in the North Atlantic and their impact on the salinity of the eastern subpolar gyre

The role of Mediterranean Overflow Water (MOW) in creating subsurface salinity anomalies within the Rockall Trough, a gateway to high latitude areas of deep convection, has been examined closely in recent years. Eulerian investigations of high latitude property fields have suggested that these subsurface anomalies are likely the result of variability in the zonal extent of the eastern limb of the subpolar gyre: when expanded into the eastern North Atlantic, the gyre is presumed to limit the extent to which MOW is able to penetrate northward to subpolar latitudes. However, though the depth of the subsurface salinity anomalies in the Rockall Trough supports the hypothesis that the intermittent presence of MOW is involved in creating the anomalies, MOW pathways to the Rockall Trough have not yet been established. Here, Lagrangian trajectories from floats released in the eastern North Atlantic between 1996 and 1997 and synthetic trajectories launched within an eddy-resolving ocean general circulation model are used to demonstrate that two main density neutral transport pathways lead to the Rockall Trough. One pathway involves the transport of relatively fresh waters as part of the North Atlantic Current and the other involves the transport of relatively salty waters from the eastern reaches of the subtropical North Atlantic. The results from this study indicate that changes in these pathways over time can explain the subsurface salinity variability in the Rockall Trough.     

U-Th systematics and Th ages of carbonate chimneys at the Lost City Hydrothermal Field

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the ²³⁰Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The ²³⁰Th/²³²Th atomic ratios of the vent fluids range from 1 (±10) × 10⁻⁶ to 11 (±5) × 10⁻⁶, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic ²³⁰Th to the LCHF carbonate chimney deposits. Chimney ²³⁸U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ²³⁴U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate ²³²Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and ²³⁰Th/²³²Th atomic ratios vary from near seawater values of 43 (±8) × 10⁻⁶ up to 530 (±25) × 10⁻³. Chimney ages, corrected for initial ²³⁰Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.     

Identifying biological effects of organic contaminants in surface- and groundwater

Thousands of chemicals are in daily use; many of these reach the aquatic environment, which serves as a medium of transport and deposition into sediment and organisms. It is often unknown which effects these contaminants, alone or in combination with other stressors, may have on organisms, populations and communities in the aquatic environment. Ecotoxicology strives to identify and mechanistically understand contaminant–biota interactions with the ultimate goal to predict potential adverse effects. There are two general routes to addressing this goal. The first is to understand how organisms and populations respond according to anticipated exposure routes, organisms’ genome and physiology, and structure- physico-chemical properties of chemicals. This knowledge should lead to improved criteria for chemical design and approval. The second general route is to identify the cause–effect relationships of effects detected in the environment without prior knowledge on the chemical’s identity. This approach serves to pinpoint critical chemicals in complex environmental samples to enable decisions or technologies for their reduction or removal. An example will be presented in which biological effect assessment contributed to a better understanding of groundwater contamination.     

A Typology of Catalyst Events for Collaborative Watershed Management in the United States

While much has been written about the benefits of collaborative watershed management to address nonpoint source pollution and other water quality concerns in the United States, few scholars have addressed the catalytic nature of events that generate these collective action responses. Further, because equivalent catalyst events in different communities do not always lead to collective action, it is critical to understand the interaction between a community's baseline conditions and the catalyst events that lead to collective action. This article presents a conceptual framework that illustrates the relationship between baseline conditions and events that lead to collective action. In this article a theoretical typology of catalyst events is presented that includes both intentional and nonintentional types of events. Understanding these types of catalyst events can help water quality advocates create and/or seize opportunities to nurture a collective action. This article concludes with a call for future research into catalyst events.     

Temporal and spatial variation of infiltration in urban green infrastructure

Infiltration is the primary mechanism in green stormwater infrastructure (GSI) systems to reduce the runoff volume from urbanized areas. Soil hydraulic conductivity is most important in influencing GSI infiltration rates. Saturated hydraulic conductivity (Ksat) is a critical parameter for GSI design and post-construction performance. However, Ksat measurement in the field is problematic due to temporal and spatial variability and measurement errors. This review paper focuses on a comparison of methods for in-situ Ksat measurement and the causes of temporal and spatial variations of Ksat within GSI systems. Automated infiltration testing methods, such as the Modified Philip–Dunne (MPD) and SATURO infiltrometers, show promise for efficient Ksat measurements. Soil Ksat values can change over time and substantially vary throughout a GSI, which can be attributed to multiple factors, including but not limited to temperature changes, soil composition and properties, soil compaction level, plant root morphology and distribution, biological and macrofauna activities in the soil, inflow sediment characteristics, quality of infiltrating water, and measurement errors. There is evidence that infiltration rates in vegetated urban GSI systems are sustained given an appropriate GSI design, reasonable concentration of suspended sediments in the inflow runoff, and routine maintenance procedures. These observations indicate that clogging can be counteracted by processes that tend to increase the soil hydraulic conductivity (e.g., plant root and biological activities). This self-sustainability underlines that infiltration-based GSI systems are a reliable long-term stormwater management solution. Recommendations on how to incorporate the temporal changes of Ksat in GSI design and on obtaining a spatially-representative Ksat for the GSI design are presented.     

Variability of Sea Surface Heights in the Baltic Sea: An Intercomparison of Observations and Model Simulations

Sea level changes in the Baltic Sea are dominated by internal, short-term variations that are mostly caused by the ephemeral nature of atmospheric conditions over the Baltic area. Tides are small and their influence decreases from western parts of the Baltic Sea to the Baltic Proper. Superimposed to the large short-term sea level changes (up to few decimeters from day to day) are seasonal and interannual variations (centimeters to decimeters). This study focuses on the comparison of sea surface heights obtained from observations and from a high resolution oceanographic model of the Baltic Sea. From this comparison, the accuracy of the modeled sea surface variations is evaluated, which is a necessary precondition for the further use of the oceanographic model in geodetic applications. The model reproduces all observed Baltic sea level variations very reliably with an accuracy of 5 to 9 cm (rms) for short-term variations (up to 2 months) and 8 cm (rms) for long-term variations (>2 months). An additional improvement of the model can be attained by including long-period sea level variations of the North Sea. The model performs well also in the case of extreme sea level events, as is shown for a major storm surge that occurred at the southern coast of the Baltic Sea in November 1995.     

Hybrid event beds dominated by transitional‐flow facies: character,distribution and significance in the Maastrichtian Springar Formation,north‐west Vøring Basin,Norwegian Sea

Hybrid event beds comprising clay‐poor and clay‐rich sandstone are abundant in Maastrichtian‐aged sandstones of the Springar Formation in the north‐west Vøring Basin, Norwegian Sea. This study focuses on an interval, informally referred to as the Lower Sandstone, which has been penetrated in five wells that are distributed along a 140 km downstream transect. Systematic variations in bed style within this stratigraphic interval are used to infer variation in flow behaviour in relatively proximal and distal settings, although individual beds were not correlated. The Lower Sandstone shows an overall reduction in total thickness, bed amalgamation, sand to mud ratio and grain size in distal wells. Turbidites dominated by clay‐poor sandstone are at their most common in relatively proximal wells, whereas hybrid event beds are at their most common in distal wells. Hybrid event beds typically comprise a basal clay‐poor sandstone (non‐stratified or stratified) overlain by banded sandstone, with clay‐rich non‐stratified sandstone at the bed top. The dominant type of clay‐poor sandstone at the base of these beds varies spatially; non‐stratified sandstone is thickest and most common proximally, whereas stratified sandstone becomes dominant in distal wells. Stratified and banded sandstone record progressive deposition of the hybrid event bed. Thus, the facies succession within hybrid event beds records the longitudinal heterogeneity of flow behaviour within the depositional boundary layer; this layer changed from non‐cohesive at the front, through a region of transitional behaviour (fluctuating non‐cohesive and cohesive flow), to cohesive behaviour at the rear. Spatial variation in the dominant type of clay‐poor sandstone at the bed base suggests that the front of the flow remained non‐cohesive, and evolved from high‐concentration and turbulence‐suppressed to increasingly turbulent flow; this is thought to occur in response to deposition and declining sediment fallout. This research may be applicable to other hybrid event bed prone systems, and emphasizes the dynamic nature of hybrid flows.     

Effects of rock fragment size and cover on overland flow hydraulics,local turbulence and sediment yield on an erodible soil surface

The interactions between overland flow hydraulics and sediment yield were studied in flume experiments on erodible soil surfaces covered by rock fragments. The high erodibility of a non-cohesive fine sediment (D₅₀ + 0·09mm) permitted the effects of local turbulence and scour on sediment yield to be examined. Overland flow hydraulics and sediment yield were compared for experiments with pebble (D₅₀ + 1·5cm) and cobble (D₅₀ + 8·6cm) rock fragment covers. Cover percentages range from 0 to 99 per cent. Rock fragment size strongly affects the relations between flow hydraulics and rock fragment cover. For pebbles spatially-averaged hydraulic parameters (flow velocity, flow depth, effective flow width, unit discharge, total shear stress, Darcy-Weisbach friction factor, percentage grain friction and grain shear stress) vary most rapidly within cover percentages at low covers (power functions). In contrast, for cobbles these parameters vary most rapidly within cover percentages at high covers (exponential functions). As the type of the function that describes the relation between flow hydraulics and cover percentage can be deduced from the ratio of rock fragment height to flow depth, the continuity equation can be employed to determine the actual coefficients of the functions, provided the regression of one hydraulic parameter (e.g. flow velocity) with cover percentage is known and a good estimate exists for two values of another hydraulic variable for a low and a high cover percentage. The variation of sediment yield with cover percentage is also strongly dependent on rock fragment size, but neither the convex-upward relation for pebbles, nor the positive relation for cobbles can be solely attributed to the spatially averaged hydraulics of sheet-flow. Rock fragments induce local turbulence that leads to scour hole development on the stoss side of the rock fragments while deposition commonly occurs in the wake. This local scour and deposition substantially affects sediment yield. However, scour dimensions cannot be predicted by spatially averaged flow hydraulics. An adjustment of existing scour formulas that predict scour around bridge piers is suggested. Sediment yield from non-cohesive soils might then be estimated by a combination of sediment transport and scour formulas.