Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.     

Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering,provenance, and tectonic setting

The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si₂O versus K₂O/Na₂O tectonic setting diagram.     

Optimal design of rain gauge network in the Middle Yarra River catchment,Australia

Rainfall data are a fundamental input for effective planning, designing and operating of water resources projects. A well‐designed rain gauge network is capable of providing accurate estimates of necessary areal average and/or point rainfall estimates at any desired ungauged location in a catchment. Increasing network density with additional rain gauge stations has been the main underlying criterion in the past to reduce error and uncertainty in rainfall estimates. However, installing and operation of additional stations in a network involves large cost and manpower. Hence, the objective of this study is to design an optimal rain gauge network in the Middle Yarra River catchment in Victoria, Australia. The optimal positioning of additional stations as well as optimally relocating of existing redundant stations using the kriging‐based geostatistical approach was undertaken in this study. Reduction of kriging error was considered as an indicator for optimal spatial positioning of the stations. Daily rainfall records of 1997 (an El Niño year) and 2010 (a La Niña year) were used for the analysis. Ordinary kriging was applied for rainfall data interpolation to estimate the kriging error for the network. The results indicate that significant reduction in the kriging error can be achieved by the optimal spatial positioning of the additional as well as redundant stations. Thus, the obtained optimal rain gauge network is expected to be appropriate for providing high quality rainfall estimates over the catchment. The concept proposed in this study for optimal rain gauge network design through combined use of additional and redundant stations together is equally applicable to any other catchment. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Using spatial statistics to identify the uranium hotspot in groundwater in the mid-eastern Gangetic plain,India

The occurrence of uranium in groundwater is of particular interest due to its toxicological and radiological properties. It has been considered as a relevant contaminant for drinking water even at a low concentration. Uranium is a ubiquitously occurring radionuclide in the environment. Four hundred and fifty-six (456) groundwater samples from different locations of five districts of South Bihar (SB) were collected and concentrations of uranium (U) were analyzed using a light-emitting diode (LED) fluorimetric technique. Uranium concentrations in groundwater samples varied from 0.1 µg l^?1 to 238.2 µg l^?1 with an average value of 12.3 µg l^?1 in five districts of Bihar in the mid-eastern Gangetic plain. This study used hot spot spatial statistics to identify the distribution of elevated uranium concentration in groundwater. The hypothesis whether spatial distribution of high value and low value of U is more likely spatially clustered due to random process near a uranium hotspot in groundwater was tested based on z score and Getis-Ord Gi* statistics. The method implemented in this study, can be utilized in the field of risk assessment and decision making to locate potential areas of contamination.     

Experimental study on loss factor for corrugated plates by bandwidth method

The material loss factor for technically orthotropic plates was measured by half-power bandwidth method. Rectangular and trapezoidal corrugated plates of steel were considered. A simple isotropic steel plate was also considered for comparison of the results. The concept of single degree of freedom system was adopted. The tests were undertaken at very low frequency range (0–100) Hz. The plate models were suspended freely with two wires to minimize or prevent excessive extraneous energy dissipation. Out of plane point force, random in nature was applied to the top middle of the plates and the responses were measured from the middle point of the plates by FFT analyzer using miniature small mass accelerometer as sensor. The aim of these tests is to investigate the effects of bending rigidity and mode orders over material loss factor. The values of estimated modal damping loss factors are compared and tabulated for the plates models considered. Natural frequencies of some of the initial modes of the plates are also presented.It is observed that the higher the value of bending rigidity of the plates, the larger the values of loss factor of it. There was a significant increase in value of loss factor in corrugated plates to that of the isotropic plate.     

Use of SARAL/AltiKa Observations for Modeling River Flow

In the absence of many gauging stations in the major and mighty river systems, there is a need for satellite-based observations to estimate temporal variations in the river water storage and associated water management. In this study, SARAL/AltiKa application for setting up hydraulic model (HEC-RAS) and river flow simulations over Tapi River India has been discussed. Waveform data of 40 Hz from Ka band altimeter has been used for water levels retrieval in the Tapi river. SARAL/AltiKa retrieved water levels were converted to discharge in the upstream location (track-926) using the rating curve available for the nearby gauging site and using linear spatial interpolation technique. Steady state simulations were done for various flow conditions in the upstream. Validation of river flow model was done in the downstream location (track-367) by comparing simulated and altimeter retrieved water levels (RMSE 0.67 m). Validated model was used to develop rating curve between water levels and simulated discharge for the downstream location which enables to monitor discharge variations from satellite platform in the absence of in situ observations. It has been demonstrated that SARAL/AltiKa data has potential for river flow monitoring and modeling which will feed for flood disaster forecasting, management and planning.     

Interannual variability of Kelvin wave propagation in the wave guides of the equatorial Indian Ocean,the coastal Bay of Bengal and the southeastern Arabian Sea during 1993–2006

The observed variability of the Kelvin waves and their propagation in the equatorial wave guide of the Indian Ocean and in the coastal wave guides of the Bay of Bengal (BoB) and the southeastern Arabian Sea (AS) on seasonal to interannual time scales during years 1993–2006 is examined utilizing all the available satellite and in-situ measurements. The Kelvin wave regime inferred from the satellite-derived sea surface height anomalies (SSHA) shows a distinct annual cycle composed of two pairs of alternate upwelling (first one occurring during January–March and the second one occurring during August–September) and downwelling (first one occurring during April–June and the second one occurring during October–December) Kelvin waves that propagate eastward along the equator and hit the Sumatra coast and bifurcate. The northern branches propagate counterclockwise over varied distances along the coastal wave guide of the BoB. The potential mechanisms that contribute to the mid-way termination of the first upwelling and the first downwelling Kelvin waves in the wave guide of the BoB are hypothesized. The second downwelling Kelvin wave alone reaches the southeastern AS, and it shows large interannual variability caused primarily by similar variability in the equatorial westerly winds during boreal fall. The westward propagating downwelling Rossby waves triggered by the second downwelling Kelvin wave off the eastern rim of the BoB also shows large interannual variability in the near surface thermal structure derived from SODA analysis. The strength of the equatorial westerlies driven by the east–west gradient of the heat sources in the troposphere appears to be a critical factor in determining the observed interannual variability of the second downwelling Kelvin wave in the wave guides of the equatorial Indian Ocean, the coastal BoB, and the southeastern AS.     

Enhancing the mechanical properties of marine clay using cement solidification

Abstract

The use of soft clay and dredged marine clays as the construction material is challenging. This is because the high water content, high compressibility and low permeability of the clay causing the instability of ground and structure. This detrimental effect of soft clay can be improved by the cement solidification process, which is relatively cheap and efficient. This paper mainly focuses on the study of improvement on the mechanical behavior of cement mixed marine clay. The soil is reconstituted by using ordinary Portland cement of 5%, 10%, 15% and 20% by its mass. The study reveals that cementation of clay significantly improves the peak and residual strength of soil. Similarly, the primary yield stress of the soil is also improved from 16 to 275?kPa as cement content increases from 5% to 20%, respectively. By using statistical tools, the relationships between various parameters are established, which are very important to define the mechanical behavior of the clay. This study reveals that the yield surface of the solidified marine clay is not a smooth elliptical surface. Rather it is composed of two linear surfaces followed by a log-linear surface which can be modeled by using simple parameters obtained from triaxial tests.     

Rhenium in rivers and estuaries of India: Sources,transport and behaviour

The concentration of dissolved and particulate Re have been measured in the Narmada, Tapi and the Mandovi estuaries in the Arabian Sea and the Hooghly estuary in the Bay of Bengal. Re concentration in water and particulate matter of these estuaries is highly variable. Re in river waters analysed varies from 1 to 41 pmol/kg, the lowest in the Mandovi and the highest in the Mahi river. Re concentrations in the rivers analysed except in the Mandovi river are higher than the average global riverine Re concentration of 2.1 pmol/kg. Based on this study and the available data, the contemporary global annual flux of dissolved riverine Re is estimated to be ~ 350 × 10³ mol with an average concentration of ~ 9.2 pmol/kg, much higher than the earlier estimates. Residence time of Re in the oceans based on this estimate is 175,000 years, ~ 4 times lower compared to earlier estimates. Re behaves conservatively in all the estuaries studied. Re concentrations of seawater in the Bay of Bengal and in the Arabian Sea, estimated from the data of the Hooghly and the Mandovi estuaries respectively are ~ 40 pmol/kg, similar to the open ocean Re values of the Arabian Sea measured in this study and the values reported for in other oceanic regions. However, the dissolved Re in the Gulf of Cambay is 2 to 5 times higher, consistent with the high Re measured in the Mahi estuary and in the coastal waters of the Gulf of Cambay. The source of high Re in the Gulf of Cambay seems to be anthropogenic, measurements of Re in rivers and industrial waste waters draining into the Gulf supply amount to ~ 2300 mol of Re annually. This anthropogenic supply coupled with high residence time of water in the Gulf contribute to its high Re. Re concentration in suspended sediments of the Narmada estuary varies from 1 to 2 pmol/g, and does not show any discernible trend with salinity.The contemporary global riverine Re supply to the oceans estimated in this study is ~ 2–4 times higher compared to its removal in the reducing (anoxic/suboxic) sediments, indicating non-steady state of Re in the ocean. High dissolved riverine Re flux coupled with high Re content in the Gulf of Cambay highlights the need of a detailed study of Re in the various global rivers and in oceans including coastal regions and semi enclosed basins of the world to understand its behaviour in various reservoirs and to constrain the residence time of Re in the ocean.