Estrogenic Activity and Volume Fraction of Waste Water Origin in Monitoring Wells Along the Santa Cruz River, Arizona

The fate of estrogenic activity in waste water effluent was examined during surface transport and incidental recharge along the Santa Cruz River in Pima County, Arizona. Based on measurement of boron isotopes, the fractional contribution of reclaimed water in surface waters and ground water wells proximate to the river was determined for a contemporary sample set. Estrogenic activity decreased by −60% over the 25 mi length of the river below effluent discharge points in Tucson. In ground water samples obtained from monitoring wells that are proximate to the Santa Cruz River, both dissolved organic carbon ( p = 0.0003) and estrogenic activity ( p = 3 × 10⁻⁶) were highly correlated to fractional waste water content. Results indicate that proximate ground water quality is sensitive to incidental recharge of reclaimed water in the Santa Cruz River bed. In a few locations, little attenuation of estrogenic activity was apparent during percolation of effluent in the river channel to well withdrawal points.     

Assessment of river habitat in Brandenburg, Germany

A habitat assessment of 1,707 km of rivers in the Federal State of Brandenburg, Germany, was undertaken using the desk-based ‘overview method’. This method includes the analysis of different sources such as topographic and thematic maps, reports, remote sensing data, and interviews with authorities. It compares actual habitat conditions with natural conditions, and assesses the human disturbances using a seven-step scale. Results show, that in Brandenburg more than 50% of surveyed river units are heavily (class 5) to totally disturbed (class 7) and only slightly more than 20% are undisturbed (class 1) to little disturbed (class 2). Main human disturbances are canalization, bank stabilizations, flood control, migration barriers, and agricultural and urban development in the floodplain. All survey data and maps are embedded in a geographical information system (GIS) that not only allows future analysis and use in river restoration management by experts, but also serves as information for the public. The river habitat map of Brandenburg is part of the river habitat map of the entire Germany.     

Sub-surface precipitation of salts in supercritical seawater

Extremely low solubility of typical seawater salts within certain supercritical sections of their pressure–temperature composition space is a proven experimental fact. Its consequences are often referred to as either 'shock crystallization' or 'out-salting'. Our alternative model for the formation of salt deposits hypothesizes that high temperatures and pressures characteristic for the high heat-flow zones of tectonically active basins may bring submarine brines into the out-salting regions and result in the accumulation of geological-scale salt depositions.
To confirm the laboratory observations, molecular-scale simulations (molecular dynamics) have been employed to study structural changes in a model seawater system where temperature increased from ambient to near-critical and supercritical. Fluid properties and phase transition regions extracted from the simulations were then used as input parameters for a reservoir simulator program to model out-salting in a simple hydrothermal geological system. Both numerical simulations and laboratory experiments confirm that supercritical out-salting is a viable process of geological significance for the formation and accumulation of evaporites. We suggest two regions where hydrothermally associated salts may be depositing today: Atlantis II Deep, in the Red Sea, and Lake Asale, Ethiopia.     

Recharge estimation from discrete water-table datasets in a coastal shallow aquifer in a humid subtropical climate

A time-series approach to the estimation of recharge rate in unconfined aquifers of highly variable water level is proposed. The approach, which is based on the water-table fluctuation method (WTF), utilizes discrete water-level measurements. Other similar techniques require continuous measurements, which makes them impossible to apply in cases where no data from automatic loggers are available. The procedure is deployed at the Ressacada Farm site, southern Brazil, on a coastal shallow aquifer located in a humid subtropical climate where diurnal water-level variations of up to 1 m can follow a precipitation event. The effect of tidal fluctuations on the groundwater levels is analyzed using a harmonic component builder, while a time-variable drainage term is evaluated through an independent analysis and included in the assessment. The estimated recharge values are compared with those obtained from the continuous measurements showing a good agreement with the approaches for discrete dataset intervals of up to 15 days. Subsequently, the estimated recharge rates are incorporated into a transient groundwater-flow model and the water levels are compared showing a good match. Henceforth, the approach extends the applicability of WTF to noncontinuous water-level datasets in groundwater recharge studies.     

40Ar/39Ar ages and zircon petrochronology for the rear arc of the Izu-Bonin-Marianas intra-oceanic subduction zone

Long-lived intra-oceanic arcs of Izu-Bonin-Marianas (IBM)-type are built on thick, granodioritic crust formed in the absence of pre-existing continental crust. International Ocean Discovery Program Expedition 350, Site U1437, explored the IBM rear arc to better understand continental crust formation in arcs. Detailed petrochronological (U–Pb geochronology combined with trace elements, oxygen and hafnium isotopes) characterizations of zircon from Site U1437 were carried out, taking care to exclude potential contaminants by (1) comparison of zircon ages with ship-board palaeomagnetic and biostratigraphic ages and ⁴⁰Ar/³⁹Ar geochronology, (2) analysing zircon from drill muds for comparison, (3) selectively carrying out in situ analysis in petrographic thin sections, and (4) minimizing potential laboratory contamination through using pristine equipment during mineral separation. The youngest zircon ages in Site U1437 are consistent with ⁴⁰Ar/³⁹Ar and shipboard ages to a depth of ~1390 m below sea floor (mbsf) where Igneous Unit Ig 1 yielded an ⁴⁰Ar/³⁹Ar age of 12.9 ± 0.3 Ma (all errors 2σ). One single zircon (age 15.4 ± 1.0 Ma) was recovered from the deepest lithostratigraphic unit drilled, Unit VII (1459.80–1806.5 mbsf). Site U1437 zircon trace element compositions are distinct from those of oceanic and continental arc environments and differ from those generated in thick oceanic crust (Iceland-type) where low-δ¹⁸O evolved melts are produced via re-melting of hydrothermally altered mafic rocks. Ti-in-zircon model temperatures are lower than for mid-ocean ridge rocks, in agreement with low zircon saturation temperatures, suggestive of low-temperature, hydrous melt sources. Zircon oxygen (δ¹⁸O = 3.3–6.0‰) and hafnium (εHf = + 10–+16) isotopic compositions indicate asthenospheric mantle sources. Trace element and isotopic differences between zircon from Site U1437 rear-arc rocks and the Hadean detrital zircon population suggest that preserved Hadean zircon crystals were probably generated in an environment different from modern oceanic convergent margins underlain by depleted mantle.     

Pollen-based reconstructions of late Holocene climate from the central and western Canadian Arctic

Two lake-sediment cores from the western and central Canadian Arctic were used to investigate late Holocene climate variability in the region. Both cores were analyzed for pollen, organic matter, biogenic silica, and magnetic susceptibility, and were dated using a combination of ²¹⁰Pb and ¹⁴C techniques. Core MB01, from southwestern Victoria Island, provides a 2600-year-long record. Fossil pollen percentages, along with other parameters, suggest the occurrence of a cold period around 2400 cal year BP (450 BC), followed by slightly warmer conditions by 1800 cal year BP (150 AD), and a return to cooler conditions throughout much of the last millennium. Core SL06, from southern Boothia Peninsula, shows more subtle changes in pollen percentages over its 2500-year duration, but an increase in Cyperaceae and decrease in Oxyria pollen around 1400 cal year BP (550 AD) are indicative of warmer conditions at that time. Quantitative climate reconstructions from these pollen sequences were compared to two other pollen-based climate records from the region and indicate the presence of a widespread wet period ~1500 cal year BP (450 AD), and a cool and dry Little Ice Age. In the reconstructions based on pollen percentage data, the twentieth century summer temperature and annual precipitation in the central and western Canadian Arctic were comparable to that which occurred over the last 2500 years. However, pollen-influx values increase in the most recent sediments, suggesting high plant productivity during the late twentieth century.

Century-scale records of land-based activities recorded in Mesoamerican coral cores

The Mesoamerican Reef, the second-largest barrier reef in the world, is located in the western Caribbean Sea off the coasts of Mexico, Belize, Guatemala, and Honduras. Particularly in the south, the surrounding watersheds are steep and the climate is extremely wet. With development and agricultural expansion, the potential for negative impacts to the reef from land-based runoff becomes high. We constructed annually resolved century-scale records of metal/calcium ratios in coral skeletons collected from four sites experiencing a gradient of land-based runoff. Our proxy data indicate that runoff onto the reef has increased relatively steadily over time at all sites, consistent with land use trends from historical records. Sediment supply to the reef is greater in the south, and these more exposed reefs will probably benefit most immediately from management that targets runoff reduction. However, because runoff at all sites is steadily increasing, even distal sites will benefit from watershed management.     

Seismic demands on nonstructural components anchored to concrete accounting for structure-fastener-nonstructural interaction (SFNI)

This paper investigates the influence of the hysteretic shear behavior of postinstalled anchors in concrete on the seismic response of nonstructural components (NSCs) using numerical methods. The purpose of the investigation is to evaluate current design requirements for NSC and their anchorage. Current design guidelines and simplified methods, such as floor response spectra (FRS), typically approach the dynamics of the structure-fastener-NSC (SFN) system using simplified empirical formulae. These formulations decouple the structure from the NSC and neglect the behavior of the anchor connection, with the assumption of full rigidity. There is a lack of knowledge on the complex interaction between a host structure, the fastening system, and the NSC, herein referred to as structure-fastener-nonstructural interaction (SFNI). More specifically, it is important to investigate whether and how the actual hysteresis shear behavior that takes place in the anchorage could alter the seismic response of the SFN system and its components. Herein, the results of extensive nonlinear dynamic analyses (NLDA) with different models for the anchorage force-displacement relationship are presented and compared with those obtained with FRS procedures and current code provisions. The anchor models include (a) linear-elastic, (b) bilinear, and (c) a recently developed hysteresis rule. The results of the NLDA showed that the first two approaches are not able to reflect the behavior of an anchor loaded in dynamic shear. Moreover, when using the more refined hysteresis model, it appears that current code provisions might underestimate the component and anchor shear amplification factors for rigid NSC fixed to the host structure through anchors.