Gaschromatographische Bestimmung von polychlorierten Biphenylen in Wasser nach Headspace-Festphasenmikroextraktion

Gas-chromatographic Determination of Polychlorinated Biphenyls in Water after Headspace Solid-phase Microextraction Headspace-analytical techniques are usually applied to the determination of easily volatile substances in water, whereas semivolatiles are generally isolated by liquid-liquid or solid-phase extraction. In the present paper, a method is presented for isolating high boiling polychlorinated biphenyls (PCB) using headspace solid-phase microextraction at elevated temperature. In spite of their low vapor pressure, the analytes are adsorbed very efficiently on a poly-dimethylsiloxane-coated fiber. Thus, in combination with GC/ECD, a very simple and sensitive solventless determination of PCB is accomplished. Using the simplest possible standard conditions, limits of determination in the lowest nanogram-per-liter range are achieved. Further increased sensitivity down to the ppq (parts per quadrillion) range is possible by stirring and increasing the sample volume and adsorption time. Moderate matrix effects have been observed in some surface and groundwaters.     

Ambiguous Moment Tensors and Radiation Patterns in Anisotropic Media with Applications to the Modeling of Earthquake Mechanisms in W-Bohemia

Anisotropic material properties are usually neglected during inversions for source parameters of earthquakes. In general anisotropic media, however, moment tensors for pure-shear sources can exhibit significant non-double-couple components. Such effects may be erroneously interpreted as an indication for volumetric changes at the source. Here we investigate effects of anisotropy on seismic moment tensors and radiation patterns for pure-shear and tensile-type sources. Anisotropy can significantly influence the interpretation of the source mechanisms. For example, the orientation of the slip within the fault plane may affect the total seismic moment. Also, moment tensors due to pure-shear and tensile faulting can have similar characteristics depending on the orientation of the elastic tensor. Furthermore, the tensile nature of an earthquake can be obscured by near-source anisotropic properties. As an application, we consider effects of inhomogeneous anisotropic properties on the seismic moment tensor and the radiation patterns of a selected type of micro-earthquakes observed in W-Bohemia. The combined effects of near-source and along-path anisotropy cause characteristic amplitude distortions of the P, S1 and S2 waves. However, the modeling suggests that neither homogeneous nor inhomogeneous anisotropic properties alone can explain the observed large non-double-couple components.The results also indicate that a correct analysis of the source mechanism, in principle, is achievable by application of anisotropic moment tensor inversion.     

Maximum Storm Surge Curve Due to Global Warming for the European North Sea Region During the 20th–21st Century

Computations of storm surges during the 20th century needs to incorporate globalwarming of about 0.6 °C ± 0.2 °C (IPCC, 2001). In order totake this global warming into consideration, the development of all storm surgesoccurred during the 20th century have been analysed. The study comprises determiningto what degree the storm surge curve and storm surge level depend on each other. Thisfact can be used to calculate a maximum storm surge curve and each single storm surgeevent can be summarised. The tendency of the surge and wind parameters do not showthat this maximum storm surge levels in the 20th century will occur earlier than predicted, however, the global warming of 0.6 °C will extend the duration of the mean storm surge curve.     

On the variability of the flow along the Meso-American Barrier Reef system: a numerical model study of the influence of the Caribbean current and eddies

A high resolution (3–8 km grid), 3D numerical ocean model of the West Caribbean Sea (WCS) is used to investigate the variability and the forcing of flows near the Meso-American Barrier Reef System (MBRS) which runs along the coasts of Mexico, Belize, Guatemala and Honduras. Mesoscale variations in velocity and temperature along the reef were found in seasonal model simulations and in observations; these variations are associated with meandering of the Caribbean current (CC) and the propagation of Caribbean eddies. Diagnostic calculations and a simple assimilation technique are combined to infer the dynamically adjusted flow associated with particular eddies. The results demonstrate that when a cyclonic eddy (negative sea surface height anomaly (SSHA)) is found near the MBRS the CC shifts offshore, the cyclonic circulation in the Gulf of Honduras (GOH) intensifies, and a strong southward flow results along the reef. However, when an anticyclonic eddy (positive SSHA) is found near the reef, the CC moves onshore and the flow is predominantly westward across the reef. The model results help to explain how drifters are able to propagate in a direction opposite to the mean circulation when eddies cause a reversal of the coastal circulation. The effect of including the Meso-American Lagoon west of the Belize Reef in the model topography was also investigated, to show the importance of having accurate coastal topography in determining the variations of transports across the MBRS. The variations found in transports across the MBRS (on seasonal and mesoscale time scales) may have important consequences for biological activities along the reef such as spawning aggregations; better understanding the nature of these variations will help ongoing efforts in coral reef conservation and maintaining the health of the ecosystem in the region.     

On the influence of adequate Weddell Sea characteristics in a large-scale global ocean circulation model

Global ocean circulation models usually lack an adequate consideration of high-latitude processes due to a limited model domain or insufficient resolution. Without the processes in key areas of the global thermohaline circulation, the characteristics and flow of deep and bottom waters cannot be modeled realistically. In this study, a high-resolution (~20 km) ocean model focused on the Weddell Sea sector of the Southern Ocean is combined with a low-resolution (2^° × 2^°) global ocean model applying the state estimation technique. Temperature, salinity, and velocity data on two Weddell Sea sections from the regional model are used as constraints for the large-scale model in addition to satellite altimetry and sea-surface temperatures. The differences between the model with additional constraints and without document that the Weddell Sea circulation exerts significant influence on the course of the Antarctic Circumpolar Current with consequences for Southern Ocean water mass characteristics and the spreading of deep and bottom waters in the South Atlantic. Furthermore, a warming trend in the period 1993–2001 was found in the Weddell Sea and adjacent basins in agreement with float measurements in the upper Southern Ocean. Teleconnections to the North Atlantic are suggested but need further studies to demonstrate their statistical significance.     

The lower marine to lower freshwater Molasse transition in the northern Alpine foreland basin (Oligocene; central Switzerland–south Germany): age and geodynamic implications

The Wilhelmine Alpe section near Immenstadt (Allgäu, south Germany), which represents one of the best continuously exposed outcrops within the northern Alpine foreland basin, has been analyzed for magnetostratigraphic and palynostratigraphic signals. The section comprises the marine-to-terrestrial transition from Lower Marine (UMM) to Lower Freshwater Molasse (USM) sediments. Based on the correlation of the local magnetic pattern with the geomagnetic polarity timescale (GPTS) and palynostratigraphic data, an age of about 31 Ma is suggested for the UMM–USM transition in the Wilhelmine Alpe section. A comparison with coeval magnetostratigraphic sections from central and eastern Switzerland indicates that the regression of the UMM sea along the southern margin of the Molasse basin occurred strongly heterochronously between 31.5 and 30 Ma. The heterochroneity is attributed to the deposition of fan-delta and alluvial fan sediments which document that the overall marine conditions during the UMM were accompanied by strong clastic input derived from the rising Alps. This clastic contribution had a much stronger influence on the depositional pattern than previously thought.     

GPS monitoring of vertical ground motion in northern Ardenne–Eifel: five campaigns (1999–2003) of the HARD project

We present the HARD project of GPS monitoring of vertical ground motion in NE Ardenne and Eifel (western Europe). Its main purposes are to get a better insight into the present-day rates of vertical ground motion in intraplate settings and to identify the various causes of these motions. Since 1999, we have carried out yearly campaigns of simultaneous GPS measurements at 12 sites situated so as to sample the different tectonic subunits of the study area and especially to record potential displacements across the seismogenic Hockai fault zone. Five campaigns (1999–2003) have been processed currently. Key issues of the data processing with the Gamit software are discussed and first results are presented. Though temporally consistent in many cases, the obtained vertical motion rates are spatially highly variable. They are also much too high (several mm/year) to support a tectonic interpretation, and a long-term influence of groundwater level variations is proposed to account for the observed motions. This influence should be distinguished from seasonal variations and from inter-survey variations linked to the varying degree of soil and subsoil drying off during the successive spring surveys.     

P–T evolution of Precambrian eclogite in the Sveconorwegian orogen,SW Sweden

Conditions of the prograde, peak‐pressure and part of the decompressional P–T path of two Precambrian eclogites in the eastern Sveconorwegian orogen have been determined using the pseudosection approach. Cores of garnet from a Fe–Ti‐rich eclogite record a first prograde and syn‐deformational stage along a Barrovian gradient from ~670 °C and 7 kbar to 710 °C and 8.5 kbar. Garnet rims grew during further burial to 16.5–19 kbar at ~850–900 °C, along a steep dP/dT gradient. The pseudosection model of a kyanite‐bearing eclogite sample of more magnesian bulk composition confirms the peak conditions. Matrix reequilibration associated with subsequent near‐isothermal decompression and partial exhumation produced plagioclase‐bearing symplectites replacing kyanite and clinopyroxene at an estimated 850–870 °C and 10–11 kbar. The validity of the pseudosections is discussed in detail. It is shown that in pseudosection modelling the fractionation of FeO in accessory sulphides may cause a significant shift of field boundaries (here displaced by up to 1.5 kbar and 70 °C) and must not be neglected. Fast burial, exhumation and subsequent cooling are supported by the steepness of both the prograde and the decompressional P–T paths as well as the preservation of garnet growth zoning and the symplectitic reaction textures. These features are compatible with deep tectonic burial of the eclogite‐bearing continental crust as part of the underthrusting plate (Eastern Segment, continent Baltica) in a collisional setting that led to an effectively doubled crustal thickness and subsequent exhumation of the eclogites through tectonic extrusion. Our results are in accordance with regional structural and petrological relationships, which demonstrate foreland‐vergent partial exhumation of the eclogite‐bearing nappe along a basal thrust zone and support a major collisional stage at c. 1 Ga. We argue that the similarities between Sveconorwegian and Himalayan eclogite occurrences emphasize the modern style of Grenvillian‐aged tectonics.