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921.
James L. Gooding Klaus Keil Takaaki Fukuoka Roman A. Schmitt 《Earth and Planetary Science Letters》1980,50(1):171-180
Bulk abundances of Na, Mg, Al, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, La, Sm, Eu, Yb, Lu, Ir, and Au were determined by neutron activation analysis of chondrules separated from unequilibrated H-, L-, and LL-chondrites (Tieschitz, Hallingeberg, Chainpur, Semarkona) and correlated with chondrule petrographic properties. Despite wellknown compositional differences among the whole-rock chondrites, the geometric mean compositions of their respective chondrule suites are nearly indistinguishable from each other for many elements. Relative to the condensible bulk solar system (approximated by the Cl chondrite Orgueil), chondrules are enriched in lithophile and depleted in siderophile elements in a pattern consistent with chondrule formation by melting of pre-existing materials, preceded or attended by silicate/metal fractionation. Relative to nonporphyritic chondrules, porphyritic chondrules are enriched in refractory and siderophile elements, suggesting that these two chondrule groups may have formed from different precursor materials. 相似文献
922.
George E. Harlow C.E. Nehru Martin Prinz G. Jeffrey Taylor Klaus Keil 《Earth and Planetary Science Letters》1979,43(2):173-181
Single-crystal X-ray, optical, and microprobe study of pyroxenes in the Serra de Magéfeldspar cumulate eucrite indicate complex exsolution features from a slow cooling history. Two pyroxenes now exist: “low” orthohypersthene ( P21ca) as host ( ~82 vol.%) and augite ( C2/c) in four distinct habits. This pyroxene pair yields an apparent “equilibration” temperature of ~900°. These relations are typical for orthopyroxene of both the Stillwater and Kintoki-San types, indicating an original pigeonite pyroxene with a bulk composition En51Fs39Wo10. Variations in augite-hypersthene textural relationships suggest variable initial compositions from about Wo8 to Wo11. The bulk composition is intermediate to those of initial pigeonites in Moama and Moore County but the augite-hypersthene tie line is longer suggesting a slower cooling history. Our examinations of all three meteorites show that Serra de Magéaugite lamellae are as thick or thicker than those in the other meteorites, contrary to the measurement of Miyamoto and Takeda. The compositional data, textural relations, and existence of P21ca hypersthene suggest at least a comparable if not slower cooling history for Serra de Magé. 相似文献
923.
Reference Values Following ISO Guidelines for Frequently Requested Rock Reference Materials 总被引:2,自引:0,他引:2 下载免费PDF全文
Klaus Peter Jochum Ulrike Weis Beate Schwager Brigitte Stoll Stephen A. Wilson Gerald H. Haug Meinrat O. Andreae Jacinta Enzweiler 《Geostandards and Geoanalytical Research》2016,40(3):333-350
We present new reference values for nineteen USGS, GSJ and GIT‐IWG rock reference materials that belong to the most accessed samples of the GeoReM database. The determination of the reference values and their uncertainties at the 95% confidence level follows as closely as possible ISO guidelines and the Certification Protocol of the International Association of Geoanalysts. We used analytical data obtained by the state‐of‐the‐art techniques published mainly in the last 20 years and available in GeoReM. The data are grouped into four categories of different levels of metrological confidence, starting with isotope dilution mass spectrometry as a primary method. Data quality was checked by careful investigation of analytical procedures and by the application of the Horwitz function. As a result, we assign a new and more reliable set of reference values and respective uncertainties for major, minor and a large group of trace elements of the nineteen investigated rock reference materials. 相似文献
924.
The hydrologic effect of replacing pasture or other short crops with trees is reasonably well understood on a mean annual basis. The impact on flow regime, as described by the annual flow duration curve (FDC) is less certain. A method to assess the impact of plantation establishment on FDCs was developed. The starting point for the analyses was the assumption that rainfall and vegetation age are the principal drivers of evapotranspiration. A key objective was to remove the variability in the rainfall signal, leaving changes in streamflow solely attributable to the evapotranspiration of the plantation. A method was developed to (1) fit a model to the observed annual time series of FDC percentiles; i.e. 10th percentile for each year of record with annual rainfall and plantation age as parameters, (2) replace the annual rainfall variation with the long term mean to obtain climate adjusted FDCs, and (3) quantify changes in FDC percentiles as plantations age. Data from 10 catchments from Australia, South Africa and New Zealand were used. The model was able to represent flow variation for the majority of percentiles at eight of the 10 catchments, particularly for the 10–50th percentiles. The adjusted FDCs revealed variable patterns in flow reductions with two types of responses (groups) being identified. Group 1 catchments show a substantial increase in the number of zero flow days, with low flows being more affected than high flows. Group 2 catchments show a more uniform reduction in flows across all percentiles. The differences may be partly explained by storage characteristics. The modelled flow reductions were in accord with published results of paired catchment experiments. An additional analysis was performed to characterise the impact of afforestation on the number of zero flow days (Nzero) for the catchments in group 1. This model performed particularly well, and when adjusted for climate, indicated a significant increase in Nzero. The zero flow day method could be used to determine change in the occurrence of any given flow in response to afforestation. The methods used in this study proved satisfactory in removing the rainfall variability, and have added useful insight into the hydrologic impacts of plantation establishment. This approach provides a methodology for understanding catchment response to afforestation, where paired catchment data is not available. 相似文献
925.
In September 1993 (M26) and June/July 1996 (M36), a total of 239 surface samples (7 m depth) were collected on two transects across the open Atlantic Ocean (224 samples) and northwest European shelf edge area. We present an overview of the horizontal variability of dissolved Cd, Co, Zn, and Pb in between the northwest and northeast Atlantic Ocean in relation to salinity and the nutrients. Our data show a preferential incorporation of Cd relative to P in the particulate material of the surface ocean when related to previously published parallel measurements on suspended particulate matter from the same cruise. There is a good agreement with results recently estimated from a model by Elderfield and Rickaby (Nature 405 (2000) 305), who predict for the North Atlantic Ocean a best fit for αCd/P=[Cd/P]POM/[Cd/P]SW of 2.5, whereas the approach of our transect shows a αCd/P value of 2.6. The Co concentrations of our transects varied from <5 to 131 pmol kg−1, with the lowest values in the subtropical gyre. There were pronounced elevations in the low-salinity ranges of the northwest Atlantic and towards the European shelf. The Co data are decoupled from the Mn distribution and support the hypothesis of marginal inputs as the dominant source. Zinc varied from a minimum of <0.07 nmol kg−1 to a maximum of 1.2 and 4.8 nmol kg−1 in regions influenced by Labrador shelf or European coastal waters, respectively. In subtropical and northeast Atlantic waters, the average Zn concentration was 0.16 nmol kg−1. Zinc concentrations at nearly three quarters of the stations between 40°N and 60°N were <0.1 nmol kg−1. This suggests that biological factors control Zn concentrations in large areas of the North Atlantic surface waters. The Pb data indicated that significant differences in concentration between the northwest and northeast Atlantic surface waters presently (1996) do not exist for this metal. The transects in 1993 and 1996 exhibited Pb concentrations in the northeast Atlantic surface waters of 30 to 40 pmol kg−1, about a fifth to a quarter of the concentrations observed in 1981. This decline is supported by our particle flux measurements in deep waters of the same region. 相似文献
926.
Sebastian?Staude Wolfgang?Werner Teresa?Mordhorst Klaus?Wemmer Dorrit?E.?Jacob Gregor?MarklEmail author 《Mineralium Deposita》2012,47(3):251-276
The Wittichen Co–Ag–Bi–U mining area (Schwarzwald ore district, SW Germany) hosts several unconformity-related vein-type mineralizations
within Variscan leucogranite and Permian to Triassic redbeds. The multistage mineralization formed at the intersection of
two fault systems in the last 250 Ma. A Permo-Triassic ore stage I with minor U–Bi–quartz–fluorite mineralization is followed
by a Jurassic to Cretaceous ore stage II with the main Ag and Co mineralization consisting of several generations of gangue
minerals that host the sub-stages of U–Bi, Bi–Ag, Ni–As–Bi and Co–As–Bi. Important ore minerals are native elements, Co and
Ni arsenides, and pitchblende; sulphides are absent. The Miocene ore stage III comprises barite with the Cu–Bi sulfosalts
emplectite, wittichenite and aikinite, and the sulphides anilite and djurleite besides native Bi, chalcopyrite, sphalerite,
galena and tennantite. The mineral-forming fluid system changed from low salinity (<5 wt.% NaCl) at high temperature (around
300°C) in Permian to highly saline (around 25 wt.% NaCl + CaCl2) at lower temperatures (50–150°C) in Triassic to Cretaceous times. Thermodynamic calculations and comparison with similar
mineralizations worldwide show that the Mesozoic ore-forming fluid was alkaline with redox conditions above the hematite–magnetite
buffer. We suggest that the precipitation mechanism for native elements, pitchblende and arsenides is a decrease in pH during
fluid mixing processes. REE patterns in fluorite and the occurrence of Bi in all stages suggest a granitic source of some
ore-forming elements, whereas, e.g. Ag, Co and Ni probably have been leached from the redbeds. The greater importance of Cu
and isotope data indicates that the Miocene ore stage III is more influenced by fluids from the overlying redbeds and limestones
than the earlier mineralization stages. 相似文献
927.
928.
Origin and extent of fresh groundwater, salty paleowaters and recent saltwater intrusions in Red River flood plain aquifers, Vietnam 总被引:1,自引:0,他引:1
Luu T. Tran Flemming Larsen Nhan Q. Pham Anders V. Christiansen Nghi Tran Hung V. Vu Long V. Tran Hoan V. Hoang Klaus Hinsby 《Hydrogeology Journal》2012,20(7):1295-1313
A model has been established on the origin and extent of fresh groundwater, salty paleowaters and saltwater from recent seawater intrusions in the Red River flood plain in Vietnam. This was done with geological observations, geophysical borehole logging and transient electromagnetic methods. Salt paleowater is present up to 50–75?km from the coastline, with occurrence controlled by the Holocene transgression. A density-driven leaching of salty porewater has occurred from high-permeability Holocene sediments into underlying Pleistocene deposits, whereas diffusion has dominated in low-permeability layers. In the Pleistocene aquifer, the highest content of dissolved solids is found below two intrinsic valleys with Holocene marine sediments and along the coastline. Recent intrusion of saltwater from the South China Sea is observed in shallow groundwater 35?km inland, probably a result of transport of salty water inland in rivers or leaching of paleowaters from very young near-coast marine sediments. The observed inverted salinity profile, with high saline water overlying fresher groundwater, has been formed due to the global eustatic sea-level changes during the last 8,000–9,000?years. The proposed model may therefore be applicable to other coastal aquifers, with a proper incorporation of the local geological environments. 相似文献
929.
High resolution climate simulations over the Arctic 总被引:1,自引:0,他引:1
Annette Rinke Klaus Dethloff Arne Spekat Wolfgang Enke Jens Hesselbjerg Christensen 《Polar research》1999,18(2):143-150
The regional atmospheric climate model HIRHAM has been applied to the Arctic. Simulations for the whole year 1990 and for an ensemble of winter months (January of 1985-1995) have been performed. The comparison of the simulations with observational data analyses shows that the general spatial patterns are in good agreement with the data, in both the vertical structure and the annual cycle. For an additional validation of the model results, a multivariate classification of large-scale circulation patterns has been applied to the January ensemble model simulations. 相似文献
930.
In this paper, a model is developed for the dynamics of a system of two bodies whose material points are under the influence of a central gravitational force. One of the bodies is assumed to be rigid and spherically symmetric, while the other is assumed to be deformable. To develop a tractable model for the system, the deformable body is modeled using Cohen and Muncaster's theory of a pseudo-rigid body. The resulting model of the system has several of the features, such as angular momentum conservation, exhibited by more restrictive models. We also show how the self-gravitation of the deformable body can be accommodated using appropriate constitutive equations for a force tensor. This enables our model to subsume many existing models of ellipsoidal figures of equilibrium. After the model and its conservations have been discussed, attention is restricted to steady motions of the system. Several results, which generalize recent works on rigid satellites, are established for these motions. For a specific choice of constitutive equations for the pseudo-rigid body, we determine the steady motions with the aid of a numerical continuation method. These results can also be considered as generalizations of earlier works on Roche's ellipsoids of equilibrium. 相似文献