Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.     

Traces of ancient geysers preserved in the travertine of Siwaqa,Jordan: conditions of their formation

A Pleistocene travertine quarrying on a hill in Siwaqa area, central Jordan, excavated solid, well-stratified travertine beds of about 12 m in thickness. The fabric and composition of the travertine indicate original deposition from hot spring water. At present, the area and its surrounding are devoid of any perennial water, except for periodic flood flows that collect at Siwaqa dam 4–5 km to the west of the quarry area, joining the catchment of the River Mujib. The travertine overlies combusted oil shale. The exposed hot spring travertine consists predominantly of well-bedded limestone, interrupted by horizons of chaotic angular debris, indicating ejection from below such as those produced by geysers. The article discusses the origins of the mottled and angular rock fragments, their transportation due to explosive geyser, the conditions and possible causes that produced the pressures leading to steam outbreaks and are responsible for the observed redistribution of travertine layers.     

Empirical assessment of rockfall and debris flow risk along the Karakoram Highway,Pakistan

Natural Hazards - The Karakoram Highway links north Pakistan with southwest China. It passes through unique geomorphological, geological and tectonic setting. This study focused 200-km-long section...     

Blind Source Separation for Compositional Time Series

Many geological phenomena are regularly measured over time to follow developments and changes. For many of these phenomena, the absolute values are not of interest, but rather the relative information, which means that the data are compositional time series. Thus, the serial nature and the compositional geometry should be considered when analyzing the data. Multivariate time series are already challenging, especially if they are higher dimensional, and latent variable models are a popular way to deal with this kind of data. Blind source separation techniques are well-established latent factor models for time series, with many variants covering quite different time series models. Here, several such methods and their assumptions are reviewed, and it is shown how they can be applied to high-dimensional compositional time series. Also, a novel blind source separation method is suggested which is quite flexible regarding the assumptions of the latent time series. The methodology is illustrated using simulations and in an application to light absorbance data from water samples taken from a small stream in Lower Austria.

     

Polarized single-crystal FTIR-spectra of natural staurolite

Polarized infrared absorption spectra of thin single-crystal slabs parallel to (010) and (001) of a staurolite from Pizzo Forno, Ticino, with analyzed composition (Fe_2.9Mg_0.9Zn_0.1Mn_0.1)Al_17.5Ti_0.1(Si_7.7Al_0.3)O₄₈H₃ have been measured in the range of 3000–4000 cm^?1. From the pleochroitic behaviour of the OH-vibrations three groups of bands can be distinguished: the bands of group I, a strong band at 3445 cm^?1 plus a weak shoulder at 3358 cm^?1, and the bands of group II, a weak band centered at 3677 cm^?1 plus a shoulder at 3635 cm^?1, are assigned to the H1 and H2 protons, respectively. The bands of group III, a weak band at 3577 cm^?1 plus a shoulder, cannot be interpreted on the basis of the proton positions known so far. We assign them to an additional proton H3, which is bonded to O1 and shows a bifurcated hydrogen bridge to two O5 in a vacant T2 site.     

Consequences of explosive eruptions on small Solar System bodies: the case of the missing basalts on the aubrite parent body

Aubrite meteorites are composed of constituents which are almost certainly of igneous origin. If they were generated by the melting and fractionation of enstatite chondrite-like parental material, as seems very likely, then plagioclase-rich, basaltic complements to the aubrites should have formed. However, such materials are not known as individual meteorites, and the compositions of two plagioclase-silica clasts and one albite-silica-(diopside-anorthite) clast (probably an impact melt) in the Norton County aubrite breccia suggest that they are not the putative enstatite-plagioclase basalts. We propose a new mechanism that explains the absence of these materials, showing that the expansion of even very small amounts of volatiles present in a melt approaching the surface of a small, low-gravity body will be enough to disrupt the melt into a spray of droplets moving faster than the local escape velocity. This explosive volcanic process of melt removal requires larger melt volatile contents on larger bodies, and data on the solubility of volatiles in basaltic melts suggest that the process was limited to bodies smaller than about 100 km in radius.     

Extremely low temperatures in the stratosphore and very low total ozone amount above northern and central Europe during winter 1989

On 1 February 1989, -83.5°C was recorded in 27.8 hPa over Hohenpeißenberg, the lowest temperature in the 22-year series. This was measured together with a very low total ozone amount of 266 DU. This may be compared with nearly twice this amount on 27 February 1989. The situation was very unusual: following an extremely cold winter in the Arctic stratosphere, the stratospheric cold pole was located over southern Scandinavia on 1 February in a very southerly position. The analyzed temperatures of -92 °C in 30 hPa were also unusual. Even though the low ozone amounts over Hohenpeißenberg were probably dynamically caused, an additional very small ozone decrease due to heterogeneous reactions in altitudes from 23–28 km, where the temperatures lie below -80 °C, cannot be ruled out. Extinction measurements by the orbitting SAGE II instrument indeed show polar stratospheric clouds over Europe near 50° N during the period 31 January–2 February. Also, polar stratospheric clouds were previously observed over Kiruna at similarly low temperatures and signs of a corresponding small ozone decrease were noted there.