Suitability of Mn‐ and Fe‐Rich Reference Materials for Microanalytical Research

Manganese‐ and iron‐rich materials are of major geoscientific and economic interest, many of which contain microscopic features that provide valuable information. To obtain accurate results, a homogeneous microanalytical reference material for calibration is needed. Several researchers have used the Mn‐ and Fe‐rich RMs, JMn‐1, NOD‐A‐1, NOD‐P‐1 and FeMn‐1, for this purpose; therefore, they were tested in this study to determine their suitability for microanalysis. Their homogeneity was investigated by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) with two different types of lasers (nano‐ and femtosecond), with spot and line scan analyses and with different operating parameters, such as spot size, pulse repetition rate and fluence. As the established manganese nodule RMs revealed inhomogeneities for picogram to microgram test portions, we also investigated the new synthetic Fe‐ and Mn‐rich RM, FeMnOx‐1. FeMnOx‐1 was found to be homogeneous for large (ø 40 μm: 2% RSD repeatability) and small (ø 8–10 μm: 10% RSD repeatability) spot sizes. This homogeneity is in the range of the homogeneous NIST SRM 610 and GSE‐1G reference glasses. Furthermore, FeMnOx‐1 revealed a large‐scale homogeneity within uncertainties of a few per cent, using test portions in the ng range, when measuring four individual mounts of this material.     

广东河源断裂带地热成因及与构造关系初探

广东省河源断裂带位于中国东南沿海地热异常区,地热资源十分丰富,但其形成机制和利用前景尚不确定。为此文章开展了多学科综合分析,获得以下初步认识:温泉是断裂带内深循环地下水被地温加热而成,断裂剪切热和花岗岩浆残余热的贡献基本可以排除;沿断裂展布的厚层硅化带是古水热活动的产物;硅化带形成时期的挤压应力方向为北东-南西,与河源断裂及河源盆地晚白垩世以来的伸展活动对应,现代构造应力场为北西西-南东东方向挤压,与古应力场相比发生了明显变化;现今构造应力场使得北东向河源断裂呈右旋挤压运动,而北西向断裂则发生左旋张剪,导致地下水循环格局也发生相应改变;目前温泉沿河源断裂呈带分布,沿北西向断裂呈线性溢出,断裂交汇部位是热泉上升的主要通道。总体而言,河源地区拥有令人鼓舞的地热资源及应用前景,有可能达到建设地热发电厂的目标。建议继续深入开展地质学、地球物理、水文地质学和地热成因机理等多学科综合研究,从而更好地定量评价地热潜能与开发前景。     

Nano‐Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg^?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.     

Small satellites for global coverage: Potential and limits

There is an increasing need for Earth Observation (EO) missions to meet the information requirements in connection with Global Change Studies. Small and cost-effective missions are powerful tools to flexibly react to information requirements with space-borne solutions. Small satellite missions can be conducted relatively quickly and inexpensively by using commercial off-the-shelf-technologies, or they can be enhanced by using advanced technologies. A new class of advanced small satellites, including autonomously operating “intelligent” satellites may be created, opening new fields of application. The increasing number of small satellites and their applications drive developments in the fields of small launchers, small ground station networks, cost-effective data distribution methods, and cost-effective management and quality assurance procedures. There are many advantages of small satellite missions, like more frequent mission opportunities, a faster return of data, larger variety of missions, more rapid expansion of the technical and/or scientific knowledge base, greater involvement of small industry, feasibility by universities and others.This paper deals with general trends in the field of small satellite missions for Earth observation. Special attention is given to the potential of spatial, spectral, and temporal resolution of small satellite based systems. Examples show small satellites offer also the unique possibility to install affordable constellations to provide good daily coverage of the globe and/or allow us to observe dynamic phenomena.The facts and examples given in this paper lead to the conclusion: Small satellites are already powerful tools for monitoring global, regional and local phenomena. In the future, their application spectrum will even broaden based on the ongoing development in many areas of technology and observation techniques.     

Laboratory measurements of seismic attenuation and Young's modulus dispersion in a partially and fully water‐saturated porous sample made of sintered borosilicate glass

We measured the extensional‐mode attenuation and Young's modulus in a porous sample made of sintered borosilicate glass at microseismic to seismic frequencies (0.05–50 Hz) using the forced oscillation method. Partial saturation was achieved by water imbibition, varying the water saturation from an initial dry state up to ～99%, and by gas exsolution from an initially fully water‐saturated state down to ～99%. During forced oscillations of the sample effective stresses up to 10 MPa were applied. We observe frequency‐dependent attenuation, with a peak at 1–5 Hz, for ～99% water saturation achieved both by imbibition and by gas exsolution. The magnitude of this attenuation peak is consistently reduced with increasing fluid pressure and is largely insensitive to changes in effective stress. Similar observations have recently been attributed to wave‐induced gas exsolution–dissolution. At full water saturation, the left‐hand side of an attenuation curve, with a peak beyond the highest measured frequency, is observed at 3 MPa effective stress, while at 10 MPa effective stress the measured attenuation is negligible. This observation is consistent with wave‐induced fluid flow associated with mesoscopic compressibility contrasts in the sample's frame. These variations in compressibility could be due to fractures and/or compaction bands that formed between separate sets of forced‐oscillation experiments in response to the applied stresses. The agreement of the measured frequency‐dependent attenuation and Young's modulus with the Kramers–Kronig relations and additional data analyses indicate the good quality of the measurements. Our observations point to the complex interplay between structural and fluid heterogeneities on the measured seismic attenuation and they illustrate how these heterogeneities can facilitate the dominance of one attenuation mechanism over another.     

Wavelet transform-based seismic facies classification and modelling: application to a geothermal target horizon in the NE German Basin

At the geothermal test site near Groß Schönebeck (NE German Basin), a new 3D seismic reflection survey was conducted to study geothermal target layers at around 4 km depth and 150°C. We present a workflow for seismic facies classification and modelling which is applied to a prospective sandstone horizon within the Rotliegend formation. Signal attributes are calculated along the horizon using the continuous Morlet wavelet transform. We use a short mother wavelet to allow for the temporal resolution of the relatively short reflection signals to be analysed. Time-frequency domain data patterns form the input of a neural network clustering using self-organizing maps. Neural model patterns are adopted during iterative learning to simulate the information inherent in the input data. After training we determine a gradient function across the self-organizing maps and apply an image processing technique called watershed segmentation. The result is a pattern clustering based on similarities in wavelet transform characteristics. Three different types of wavelet transform patterns were found for the sandstone horizon. We apply seismic waveform modelling to improve the understanding of the classification results. The modelling tests indicate that thickness variations have a much stronger influence on the wavelet transform response of the sandstone horizon compared with reasonable variations of seismic attenuation. In our interpretation, the assumed thickness variations could be a result of variable paleo-topography during deposition of predominantly fluvial sediments. A distinct seismic facies distribution is interpreted as a system of thicker paleo-channels deposited within a deepened landscape. The results provide constraints for the ongoing development of the geothermal test site.