Quartz types in the Upper Pennsylvanian organic-rich Cline Shale (Wolfcamp D), Midland Basin,Texas: Implications for silica diagenesis,porosity evolution and rock mechanical properties

The origin and form of quartz in mudrocks has significant implications for interpretation of depositional environments, diagenetic pathways, mechanisms of porosity reduction and rock mechanical-property evolution. Quartz types in the Upper Pennsylvanian Cline Shale, Midland Basin, Texas, were examined using a combination of field-emission scanning electron microscopy-based energy-dispersive spectroscopy elemental mapping (to determine mineralogy) and scanning electron microscopy-based cathodoluminescence imaging (to determine quartz types) with the goal of elucidating a high-resolution imaging protocol at the micrometre scale for shale petrology. Also, the unconfined compressive rock strength of shale samples with contrasting proportions of different quartz types was measured using Equotip Bambino analyses. The results suggest that extrabasinal detrital quartz, which accounts for an average of 26 vol.% of the rock in all analyzed samples, is the dominant form of quartz in the Cline Shale. The intergranular clay-size microquartz, which accounts for an average of 10 vol.% of the rock in all analyzed samples, is the dominant form of authigenic quartz. Dissolved radiolarians and sponge spicules are likely sources of silica for clay-size microquartz and other authigenic quartz showing pale-mauve to dark greyish cathodoluminescence colour. Some authigenic quartz in the form of intragranular pore filling and mollusc skeletal replacement displays bright-reddish cathodoluminescence colour, which may be associated with silica released at a different time in the rock's diagenetic history, such as during smectite illitization. Porosity reduction in the Cline Shale predominantly resulted from compaction because of extremely low intergranular volume and the general lack of early cementation. Quartz form significantly impacts rock mechanical properties in the Cline Shale: widely distributed intergranular clay-size microquartz cement is a major factor controlling rock strength. This correlation also applies to other mudrock successions of various geological ages, tectonic histories and lithologies.     

Spectral analysis of climate data

The complexity of climate variability on all time scales requires the use of several refined tools to unravel its primary dynamics from observations. Indeed, ideas from the theory of dynamical systems have provided new ways of interpreting the information contained in climatic time series.We review the properties of several modern time series analysis methods. Those methods belong to four main classes: Fourier techniques (Blackman-Tukey and Multi-Taper), Maximum Entropy technique, Singular-spectrum techniques and wavelet analysis. Their respective advantages and limitations are illustrated by numerical experiments on synthetic time series. As climate data can be irregularly spaced in time, we also compare three interpolating methods on those time series. Those tests are aimed at showing the pitfalls of the blind use of mathematical or statistical techniques on climate data.We apply those methods to real climatic data from temperature variations over the last century, and the Vostok ice core deuterium record over the last glacial cycle. Then we show how interpretations on the dynamics of climate can be derived on those time scales.     

Place,identity and stigma: blocks and the ‘blockies’ of Tara,Queensland, Australia

This article explores the role of geographical context in generating a stigmatised identity among residents of Tara rural subdivisions in the coal seam gas fields in Queensland’s Western Downs. The research was based on qualitative interviews with Tara ‘Blockies’, as these residents are commonly referred to, that revealed how their existence in the middle of an agrarian region resulted in the assignation of a stigma that has marked them as different, and subsequently devalued their status. We explain that this distinction and category division of the normals, referring to Tara’s Agrarian residents, from the ‘stigmatised’ led to an antagonistic relationship that prevented successful socio-cultural assimilation. We demonstrate how an immoral place becomes disadvantaged, resulting in poor well-being, and how imposed labels threaten the self-esteem of its occupants.     

Variations in seasonal rainfall in Southern Europe during the present century: relationships with the North Atlantic Oscillation and the El Niño-Southern Oscillation

 Analysis of data from seventeen rainfall stations in the Iberian Peninsula, Balearic Islands and Northern Africa has revealed significant El Ni?o-Southern Oscillation (ENSO) signals in Europe. Both North Atlantic Oscillation (NAO) and Southern Oscillation (SO) exert an influence on Iberian climate, but at different temporal and spatial scales. Though most of the peninsula is under NAO influence in winter, some stations in the eastern region show no connection with this phenomenon. The same is found for ENSO, with a positively correlated region appearing in the eastern part of Spain, while the rest of the peninsula remains insensitive. The correlation between ENSO and Iberian rainfall has increased towards the end of the present century, with strong positive signals spanning over half of the area studied. The percentage of springtime variability due to ENSO has similarly increased, reaching up to 50% in certain areas. We also show how there are outstanding climatic sensors of these phenomena such as Lake Gallocanta, which manifests a positive response to ENSO while appears insensitive to NAO. Common long-term patterns are observed between SOI and an inferred lake level series, suggesting a constant influence of the low-frequency component of ENSO throughout the period considered. Lake drying phases every 14 years reflect the impact of this signal, approximately every four ENSO events. Received: 6 June 1996/Accepted: 30 October 1996