Arsenic release from biotite into a Holocene groundwater aquifer in Bangladesh

Continuous core sediments (to a depth of 90.1 m) taken at a transitional area of Holocene and Pleistocene deposits in Sonargaon, Bangladesh were characterized for their mineralogy and chemistry. Among the sediments of the lower part of the Holocene aquifer (depth: 18–29 m), where most domestic wells are installed, As is mostly fixed in biotite and organic phases. A positive correlation of As concentration with those of Al and Fe but not that of total organic C clearly suggests that biotite is a primary source of As. Although microbial reduction–dissolution of As-containing Fe oxyhydroxides is thought to cause As-enriched groundwater in the Ganges–Brahmaputra–Meghna delta plain, the authors conclude that chemical weathering of biotite is the primary formation mechanism and prevailing reducing conditions contribute to the expansion of As-enriched groundwater in the study area.     

Hard X-ray emission from the solar corona

This review surveys hard X-ray emissions of non-thermal electrons in the solar corona. These electrons originate in flares and flare-related processes. Hard X-ray emission is the most direct diagnostic of electron presence in the corona, and such observations provide quantitative determinations of the total energy in the non-thermal electrons. The most intense flare emissions are generally observed from the chromosphere at footpoints of magnetic loops. Over the years, however, many observations of hard X-ray and even γ-ray emission directly from the corona have also been reported. These coronal sources are of particular interest as they occur closest to where the electron acceleration is thought to occur. Prior to the actual direct imaging observations, disk occultation was usually required to study coronal sources, resulting in limited physical information. Now RHESSI has given us a systematic view of coronal sources that combines high spatial and spectral resolution with broad energy coverage and high sensitivity. Despite the low density and hence low bremsstrahlung efficiency of the corona, we now detect coronal hard X-ray emissions from sources in all phases of solar flares. Because the physical conditions in such sources may differ substantially from those of the usual “footpoint” emission regions, we take the opportunity to revisit the physics of hard X-radiation and relevant theories of particle acceleration.     

Transition of solar cycle length in association with the occurrence of grand solar minima indicated by radiocarbon content in tree-rings

In this paper, we review the variation of the 11-year solar cycle since the 15th century revealed by the measurement of radiocarbon content in single-year tree-rings of Japanese cedar trees. Measurements of radiocarbon content in absolutely dated tree-rings provide a calibration curve for accurate dating of archaeological matters, but at the same time, enable us to examine the variations of solar magnetic activity in the pre-historical period. The Sun holds several long-term quasi-cyclic variations in addition to the fundamental 11-year sunspot activity cycle and the 22-year polarity reversal cycle, and it is speculated that the property of the 11-year and the 22-year solar cycle varies in association with such long-term quasi-cycles. It is essential to reveal the details of solar variations around the transition time of solar dynamo for illuminating the mechanisms of the long-term solar variations. We therefore have investigated the property of the 11-year and 22-year cycles around the two grand solar minima; the Maunder Minimum (1645–1715 AD) and the Spoerer Minimum (1415–1534 AD), the periods of prolonged sunspot minima. As a result, slight stretching of the “11-year” and the “22-year” solar cycles was found during these two grand solar activity minima; continuously during the Maunder Minimum and only intermittently during the Spoerer Minimum. On the contrary, normal or slightly shortened 11-year cycles were detected during the interval period of these two minima. It suggests the inverse correlation between the solar cycle length and solar magnetic activity level, and also the change of meridional flow during the grand solar activity minima. Further measurements for the beginning of the grand solar minima will provide a clue to the occurrence of such prolonged sunspot disappearance. We also discuss the effect of solar variations to radiocarbon dating.     

A new approach to evaluation of the effect of the two half-Lambert surfaces composed of different albedoes on the emergent radiation at the top of the atmosphere

A new way is adopted for the evaluation of the upwelling radiation from atmosphere bounded by two half-Lambert surfaces. The atmosphere is assumed to be homogeneous, and is composed of aerosol, molecules, and absorbent gases, where the model aerosol is of the oceanic and water soluble types.In the computational procedure, an iterative doubling-adding equation is expanded into a series of the radiative interaction modes between atmosphere and surface. Next, a probability of radiation interacting with respective half surfaces is calculated based on the assumption of single-scattering in the atmosphere. On the basis of this probability, the emergent radiation at the top of the atmosphere is approximately calculated by considering the radiative intractions to be twice as large. The effect of the multiple-scattering is fully taken into account. A numerical simulation exhibits the extraordinary effect near the two half-surface boundary of different albedoes. The effect of the other half-surface on the radiance decreases monotonically with the distance from the boundary. The present new version enable us to quantitatively discuss radiative transfer near the boundary of two half-surfaces even if the optical thickness is large and (or) surface albedo is great.     

Rhenium and osmium systematics on iron and stony iron meteorites

Abstract— Re and Os abundances and ¹⁸⁷Os/¹⁸⁶Os isotopic ratios in 12 iron meteorites of various groups and five stony iron meteorites have been determined by an inductively coupled plasma mass spectrometry (ICP-MS). The series of iron meteorites studied have Re and Os concentrations ranging from 0.004 to 3.3 ppm and 0.03 to 41 ppm, respectively. The ¹⁸⁷Re/¹⁸⁶Os ratios in these meteorites fall between 3.0 and 6.1 and the ¹⁸⁷Os/¹⁸⁶Os between 1.0 and 1.2, giving an initial ¹⁸⁷Os/¹⁸⁶Os isotopic ratio of 0.790 and a Re-Os age of iron meteorites of 4.30 ± 0.28 Ga when employing the decay constant of 1.64 × 10^?11 yr^?1. The observed Re-Os age for iron meteorites appears somewhat younger than that for chondrites. The resultant younger age might be due either to a very slow cooling of the parental planetesimals or due to a secondary “shock” event. However, for definite conclusions about the Re-Os age, higher precisions of the Re and Os isotopic measurements and of the decay constant of ¹⁸⁷Re are required. Furthermore, the clear elucidation of the mechanisms for the fractionation of the Re/Os abundance ratios are related to the understanding of the meaning of the Re-Os age. The Re and Os abundances in pallasite stony iron meteorites are extremely low compared with those for most iron meteorites. On the other hand, the Re and Os abundances in mesosiderite stony iron meteorites show values comparable with those observed in most iron meteorites. The difference in Re and Os abundances in pallasite and mesosiderite stony iron meteorites strongly suggests that these stony iron meteorites are different in origin or history of chemical evolution. Re and Os abundances in the series of iron and stony iron meteorites were found to have a wide variation covering nearly four orders of magnitude, with a very high correlation coefficient (0.996), and a slope very slightly less than unity. The regression line observed here covers various groups of iron meteorites, stony iron meteorites and also chondrites. Masuda and Hirata (1991) suggested the possible direct mixing process of particles of most refractory metallic elements with gaseous clouds of less refractory matrix elements, since the Re and Os were predicted theoretically to be the first elements to condense as a solid phase from the high temperature solar nebula. The aims of this paper are to present a reliable technique for the Re-Os chronology and to study the cosmochemical sequences of the meteoritic metals.     

Short-wave radiation flux divergence in arctic cirrus: a case study

Radiation and particle measurements have been performed with an aircraft in deep cirrus cloud fields near the island of Svalbard. The data of 12 March 1993, when measurements at 10 different levels could be obtained, are used in a comparative study with radiative transfer calculations. In a first analysis, the cirrus cloud field was assumed to be horizontally homogeneous and invariable during the time of measurements (frozen properties). Calculations of the up and downward radiative flux densities showed root mean square differences of 9 Wm⁻² from the measurements. To estimate the possible effect of changes of the optical properties of cirrus with time, the flux densities in the upper part (6000–8500 m) and the lower part (3000–5500 m) of the cirrus cloud were analyzed separately. In these simulations, the optical thickness in the lower (upper) part was increased (decreased) by 50%. By this treatment, most of all calculated flux densities were within one standard deviation of the natural variability in each leg. Finally, the effect of inhomogeneities in the cloud field on the solar flux density has been simulated using a Monte Carlo method, since the upper part of the cirrus field has indeed been very inhomogeneous. This paper is a result of a collaborative effort between the MRI in Tsukuba, Japan, and the GKSS in Geesthacht, Germany.     

达拉布特蛇绿岩带镁铁质岩的地球化学

达拉布特蛇绿岩带的镁铁质岩属亚碱性和碱性系列,可能是弧后盆地火册活动的产物。根据镁铁质岩的层位关系、岩浆来源和微量元素特征,可将该盆地的地质演化概括为扩张阶段和封闭阶段。盆地扩张阶段早、中期喷发的镁铁质岩具有低的稀土和不相容元素丰度,而在盆地封闭阶段晚期喷发的碱性玄武岩,其特点是稀土和大多数不相容元素丰度极大增高,其稀土元素分布模式为轻稀土元素强烈富集型。     

Lagrangian observation of phytoplankton dynamics at an artificially enriched subsurface water in Sagami Bay,Japan

Phytoplankton dynamics in the lower euphotic zone were observed by tracking a subsurface water released at 20-m depth from Takumi, an artificial upwelling device. Takumi continually discharged seawater pumped up from a depth of 205 m: this water was mixed with 5-m depth water to adjust the density to that of 20-m depth water of Sagami Bay, Japan. The discharged water was pulse-labeled at Takumi with uranine and tracked for 63.9 h with a drifting buoy equipped with a drogue at 20-m depth. We present a simple model to estimate in situ phytoplankton net growth rates from temporal changes in phytoplankton abundance in the discharged water with correction for the influence of water exchange between the discharged water and neighboring layers. Lagrangian observation showed active growth of pico- and nanophytoplankton, especially cryptophytes and Synechococcus (Cyanobacteria), in the subsurface layer. In contrast, diatoms grew little in spite of micromolar concentrations of nutrients. The active growth of pico- and nanophytoplankton was in good agreement with shipboard serial dilution culture experiments. The low growth activity of diatoms was suggested to be related to low light availability in the subsurface layer.     

Basalts and serpentinite from the Puerto Rico Trench, 2. Rare-earth geochemistry

Seven tholeiitic basalts from the Puerto Rico Trench walls (three from the south wall and four from the north wall) were investigated for rare-earth abundances. All these rocks, with the exception of a pigeonite-bearing rock (RC8-RD1–12), were found to possess similar rare-earth features. Their rare-earth patterns resembled those of usual abyssal basalts, and showed no Eu anomalies. There is no difference between the rare-earth abundances of fine-grained and coarse-grained rocks. It is clear that the pigeonite-bearing rock (RC8-RD1 type 2) differs in origin from the abyssal basalts. The rocks with rare-earth patterns similar to that of RC8-RD1–12 are found among the Japanes “geosynclinal” basalts (Tanaka and Sugisaki, 1973).A serpentinite from the same trench was also analyzed for the same elements. The resultant rare-earth pattern suggests that the relevant original rock was separated from a magma having the same relative rare-earth abundances as a chondritic meteorite. The markedly high Eu positive anomaly of this serpentinite is also discussed.