Global land mapping of satellite-observed CO2 total columns using spatio-temporal geostatistics

ABSTRACT

This study presents an approach for generating a global land mapping dataset of the satellite measurements of CO₂ total column (XCO₂) using spatio-temporal geostatistics, which makes full use of the joint spatial and temporal dependencies between observations. The mapping approach considers the latitude-zonal seasonal cycles and spatio-temporal correlation structure of XCO₂, and obtains global land maps of XCO₂, with a spatial grid resolution of 1° latitude by 1° longitude and temporal resolution of 3 days. We evaluate the accuracy and uncertainty of the mapping dataset in the following three ways: (1) in cross-validation, the mapping approach results in a high correlation coefficient of 0.94 between the predictions and observations, (2) in comparison with ground truth provided by the Total Carbon Column Observing Network (TCCON), the predicted XCO₂ time series and those from TCCON sites are in good agreement, with an overall bias of 0.01?ppm and a standard deviation of the difference of 1.22?ppm and (3) in comparison with model simulations, the spatio-temporal variability of XCO₂ between the mapping dataset and simulations from the CT2013 and GEOS-Chem are generally consistent. The generated mapping XCO₂ data in this study provides a new global geospatial dataset in global understanding of greenhouse gases dynamics and global warming.     

Production patterns in Massachusetts Bay with outfall relocation

On September 6, 2000, the sewage outfall at the mouth of Boston Harbor was relocated 15 km offshore to alleviate pollution in Boston Harbor. The expected responses for nutrients and water column productivity parameters were for values to decrease at Boston Harbor, to increase at the outfall location, and to remain unchanged at the boundary of the near field region within 5 km of the outfall. Average values ofr water column measurements from 1992 to 2004 indicated these general responses with some exceptions. At the Harbor, nutrients decreased and chlorophyll increased but¹⁴C primary productivity remained statistically unchanged. At the new outfall location and at the boundary of the near field, nutrients increased and chlorophyll increased but primary productivity remained unchanged. Physical factors affecting primary production, such as pring water temperature, stratification, and wind, had more affects on productivity patters than nutrients from outfall relocation in the near field. A decrease in summer zooplankton after outfall relocation appeared to be due to a region-wide rather than outfall effluents.     

Gendered access to customary land in East Timor

Land tenure rights reflect the deeper structures of society, particularly gender distinctions in relation to land. Considering the structural differences between patrilineal and matrilineal customary tenure systems in East Timor are understudied, this paper explores men and women’s experiences in accessing land under such arrangements. The comparative analysis of two patrilineal with one matrilineal land tenure systems in Ainaro and Manufahi districts suggests a significant degree of flexibility within both systems with respect to the norms of gendered inheritance. Therefore, the binary constructs of ‘patrilineal’ and ‘matrilineal’ societies are limiting. Both men and women in these communities may acquire land rights under different circumstances, mainly through negotiations with their parents or hamlet chief. Daughters in the patrilineal communities could inherit family land upon their parents’ death and sons in the matrilineal community could gain land by cultivating and maintaining unclaimed customary land. Empirical evidence show that inheritance principally determines usufruct rights to land, but marriage exchange practices complicates a deeper understanding of traditional East Timorese land rights.

Microbial sources of intact polar diacylglycerolipids in the Western North Atlantic Ocean

Intact polar membrane lipids are essential components of microbial membranes and recent work has uncovered a diversity of them occurring in the ocean. While it has long been understood that lipid composition varies across microbial groups, the microbial origins of the intact polar lipids in the surface ocean remain to be fully explained. This study focused on identifying the microbial sources of intact polar diacylglycerolipids (IP-DAGs) in the surface waters of the western North Atlantic Ocean. We used three approaches to define these microbial sources: (i) ¹³C tracing to identify photoautotrophic and heterotrophic production of the major classes of IP-DAGs, (ii) cell sorting flow cytometry of Prochlorococcus, Synechococcus and heterotrophic bacteria to determine IP-DAG composition and (iii) regrowth incubations targeting IP-DAG production by heterotrophic bacteria. Stable isotope tracing indicated that sulfoquinovosyldiacylglycerol (SQDG) and diacylglyceryl-trimethyl-homoserine (DGTS) were produced predominantly by photoautotrophs, while phosphatidylglycerol (PG) production was dominated by heterotrophic bacteria. Of the cells sorted with flow cytometry, Prochlorococcus and Synechococcus were found to have abundant glycolipids, while heterotrophic bacteria were dominated by phospholipids. The regrowth incubations showed that the growth of heterotrophic bacteria correlated with an increase in the concentration of PG, phosphatidylethanolamine (PE) and monoglycosyldiacylglycerol (MGDG). The finding of MGDG in heterotrophic bacteria differs from previous work, which had asserted that the membranes of heterotrophic bacteria in this environment were composed entirely of phospholipids. Overall, our findings indicate that phytoplankton are the primary source of SQDG and DGTS, while heterotrophic bacteria are the dominant source of PG, making these three compounds promising biomarkers for the study of microbes in the surface ocean.     

Controls on carbonate platform architecture and reef recovery across the Palaeozoic to Mesozoic transition: A high-resolution analysis of the Great Bank of Guizhou

Carbonate platforms spanning intervals of global change provide an opportunity to identify causal links between the evolution of marine environment and depositional architecture. This study investigates the controls on platform geometry across the Palaeozoic to Mesozoic transition and yields new stratigraphic and palaeoenvironmental constraints on the Great Bank of Guizhou, a latest Permian to earliest Late Triassic isolated carbonate platform in the Nanpanjiang Basin of south China. Reconstruction of platform architecture was achieved by integrating field mapping, petrography, biostratigraphy, satellite imagery analysis and δ¹³C chemostratigraphy. In contrast to previous interpretations, this study indicates that: (i) the Great Bank of Guizhou transitioned during Early Triassic time from a low-relief bank to a platform with high relief above the basin floor (up to 600 m) and steep slope angles (preserved up to 50°); and (ii) the oldest-known platform-margin reef of the Mesozoic Era grew along steep, prograding clinoforms in an outer-margin to lower-slope environment. Increasing platform relief during Early Triassic time was caused by limited sediment delivery to the basin margin and a high rate of accommodation creation driven by Indosinian convergence. The steep upper Olenekian (upper Lower Triassic) slope is dominated by well-cemented grainstone, suggesting that high carbonate saturation states led to syndepositional or rapid post-depositional sediment stabilization. Latest Spathian reef initiation coincided with global cooling following Early Triassic global warmth. The first Triassic framework-building metazoans on the Great Bank of Guizhou were small calcareous sponges restricted to deeper water settings, but early Mesozoic reef builders were volumetrically dominated by Tubiphytes, a fossil genus of uncertain taxonomic affinity. In aggregate, the stratigraphic architecture of the Great Bank of Guizhou records sedimentary response to long-term environmental and biological recovery from the end-Permian mass extinction, highlighting the close connections among marine chemistry, marine ecosystems and carbonate depositional systems.     

Alkalinity production as an indicator of failure in steel slag leach beds treating acid mine drainage

Acid mine drainage is a serious environmental problem throughout mining regions of the US and around the world. In Appalachia, reuse of steel slag from steel production as a source of alkalinity for treatment of acid mine drainage has become a common practice. In these systems, dubbed steel slag leach beds, relatively clean surface water is percolated through a bed of steel slag to add large amounts of alkalinity to the water before mixing it with acidic, metalliferous mine water. These beds do not operate consistently and their failure mechanisms are poorly understood. Using the experience of Raccoon Creek watershed in southern Ohio, the alkalinity distribution of the discharge of six steel slag leach beds is compared. Two of these beds are still functional, one has been abandoned and three are operating poorly. The difference in alkalinity distribution between these beds suggests that a carbonate-dominated alkalinity system is an indicator of a poorly performing steel slag leach bed, while a more even distribution between hydroxide, carbonate and bicarbonate may point to more ideal operating conditions. In eight laboratory column experiments, this evidence was then expanded upon by testing different mixed media substrates (differing mixes of steel slag, wood chips and river gravel) to see which provided the most ideal alkalinity distributions. The columns that had steel slag mixed either with wood chips or wood chips and river gravel outperformed the column with slag only in terms of alkalinity distribution, perhaps due to microbial processes or increased hydraulic conductivity without significant added calcium or carbon that could drive calcium carbonate precipitation within the beds and causing them to fail.     

Scouring the surface: Ejecta dynamics and the LCROSS impact event

The Lunar CRater Observation and Sensing Satellite mission (LCROSS) impacted the moon in a permanently shadowed region of Cabeus crater on October 9th 2009, excavating material rich in water ice and volatiles. The thermal and spatial evolution of LCROSS ejecta is essential to interpretation of regolith properties and sources of released volatiles. The unique conditions of the impact, however, made analysis of the data based on canonical ejecta models impossible. Here we present the results of a series of impact experiments performed at the NASA Ames Vertical Gun Range designed to explore the LCROSS event using both high-speed cameras and LCROSS flight backup instruments. The LCROSS impact created a two-component ejecta plume: the usual inverted lampshade “low-angle” curtain, and a high speed, high-angle component. These separate components excavated to different depths in the regolith. Extrapolations from experiments match the visible data and the light curves in the spectrometers. The hollow geometry of the Centaur led to the formation of the high-angle plume, as was evident in the LCROSS visible and infrared measurements of the ejecta. Subsequent ballistic return of the sunlight-warmed ejecta curtain could scour the surface out to many crater radii, possibly liberating loosely bonded surface volatiles (e.g., H₂). Thermal imaging reveals a complex, heterogeneous distribution of heated material after crater formation that is present but unresolved in LCROSS data. This material could potentially serve as an additional source of energy for volatile release.     

Seasonal Prevalence of Hematodinium sp. Infections of Blue Crabs in Three South Carolina (USA) Rivers

Blue crab, Callinectes sapidus, commercial landings in the USA have been declining at an alarming rate. In South Carolina, these declines are significantly correlated with years of decreased rainfall and elevated salt marsh salinity. Previous studies suggest that higher salinity increases the risk of infection by Hematodinium sp., a dinoflagellate parasite of blue crabs, C. sapidus. A 4-year survey (June 2008 to March 2012) of blue crabs in the ACE Basin National Estuarine Research Reserve documented (1) the temporal and spatial patterns of Hematodinium sp. infection in relation to salinity, (2) some environmental correlates of disease prevalence, and (3) the characteristics of infected blue crabs. Sampling was conducted four times a year in March, June, September, and December in the South Edisto, Ashepoo, and Combahee rivers beginning in June 2008. Crab hemolymph samples were collected and preserved and DNA was successfully amplified for 2,303 individuals. Hematodinium sp. infection was evaluated by PCR amplification of its 18S rRNA gene and adjacent regions. Prevalence was highest in December 2008 in the Combahee River at sites closest to St. Helena Sound. The spatial and temporal pattern of Hematodinium sp. infection was correlated with several environmental parameters. Infected crabs exhibited differences in carapace shape and body condition compared to uninfected crabs. Overall, these results suggest that blue crabs in regions of higher salinity are at greater risk of infection by Hematodinium sp. and infected individuals exhibit sub-lethal effects of the disease.     

Fluoride in Nebraska's Ground Water

Fluoride concentrations in ground water are generally low but play an important role in dental health. This study evaluates the vertical and spatial distribution of fluoride in Nebraska's ground water and examines the geological and geochemical processes that control its concentration. Data from 1794 domestic wells sampled by the Nebraska Department of Health and Human Services. Regulation, and Licensure (NDOH) had a range of fluoride concentrations from <0.1 to 2.6 mg/L. and a median concentration of 0.3 mg/L. The median fluoride concentrations for Nebraska's 13 ground water regions varied from 0.2 to 0.7 mg/L. In each of these regions, individual wells may have either insufficient or overabundant F concentrations; we recommend that individual private water systems be tested for fluoride. Based on these data, system-specific recommendations can be made regarding the necessity for fluoridation.
Geochemical data indicated that the majority of fluoride occurs as F. Dissolution of F-bearing minerals controls fluoride occurrence. Apatite plus minor amounts of fluorite along with significant ground water residence times are the primary factors controlling F in the water from the Dakota Formation in Knox County, as well as in other parts of northeastern Nebraska. In western and southwestern Nebraska, dissolution of volcanic glass is the most probable source of F Long residence times plus fluorite also may contribute to the F concentrations in the Chadron Formation.