Dreiaxiale verformungen an Solnhofener Kalkstein im Temperaturbereich von 20–650° C. Röntgenographische Gefügeuntersuchungen mit dem Texturgoniometer

Axial-symmetric and real triaxial deformation tests on Solnhofen limestones were made in the range of 20 to 650° C. Stress, strain and time observations as functions of temperature and the ratios of the external stresses are plotted as stress-strain and strain-time curves. Mechanical twinning on e (01¯12) and syntectonic recrystallization (at temperatures above 500° C) is assumed to be the dominant flow mechanism. On samples of high permanent strain the textural changes and development of preferred orientations were investigated by means of the X-ray diffractometer. In all tests the symmetry of the polefigures is exactly identical with the symmetry of the external stress-field.In tests with ₁>₂=₃ the poles of the planes investigated (10¯11; 10¯12; 11¯20) occupy girdles about the unique principle compressive axis. When all principle stresses are different (₁>₂>₃) the poles of the planes investigated tend to maxima (in the case of plane strain) ore to girdle-occupations about the principle axis of maximum extension. The deduced c-diagrams show a fairly similar tendency of the spacial orientations.The pole figures (as well as the calculated orientation of the c-axis) must be explained by the superposition of reflected intensities on planes in twinned and untwinned grains. In every diagram partial occupations—possibly representing the orientations of twinned grains-are in fairly good agreement with the orientation predicted by the theory of Brace-MacDonald for the stable orientation of anisotropic minerals in a non-hydrostatic stress-field.

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Herrn Prof. Dr. F. Karl danke ich sehr herzlich für zahlreiche Diskussionen sowie für die kritische Durchsicht des Manuskripts. Mein Dank gilt auch der Deutschen Forschungsgemeinschaft, welche die Untersuchung durch eine Sachbeihilfe unterstützte.     

A study on the combination of satellite, airborne, and terrestrial gravity data

Satellite gravity missions, such as CHAMP, GRACE and GOCE, and airborne gravity campaigns in areas without ground gravity will enhance the present knowledge of the Earths gravity field. Combining the new gravity information with the existing marine and ground gravity anomalies is a major task for which the mathematical tools have to be developed. In one way or another they will be based on the spectral information available for gravity data and noise. The integration of the additional gravity information from satellite and airborne campaigns with existing data has not been studied in sufficient detail and a number of open questions remain. A strategy for the combination of satellite, airborne and ground measurements is presented. It is based on ideas independently introduced by Sjöberg and Wenzel in the early 1980s and has been modified by using a quasi-deterministic approach for the determination of the weighting functions. In addition, the original approach of Sjöberg and Wenzel is extended to more than two measurement types, combining the Meissl scheme with the least-squares spectral combination. Satellite (or geopotential) harmonics, ground gravity anomalies and airborne gravity disturbances are used as measurement types, but other combinations are possible. Different error characteristics and measurement-type combinations and their impact on the final solution are studied. Using simulated data, the results show a geoid accuracy in the centimeter range for a local test area.     

The effect of high temperature and high confining pressure on compressional wave velocities in quartz-bearing and quartz-free igneous and metamorphic rocks

Compressional wave velocities have been measured in granite, granulite, amphibolite and peridotite specimens under conditions of high temperature up to 700°C and confining pressures up to 6 kbar. In general, velocity increases with pressure and decreases with temperature.Quartz-bearing rocks show an anomalous behavior of their compressional wave velocities. The velocity—temperature relations exhibit a velocity-“deep” due to the high—low inversion of the constituent quartz crystals. The intrinsic effect of temperature on velocities is hard to determine due to thermal expansion and consequent loosening of the structure. The opening of new cracks and the widening of old cracks causes a large decrease in compressional wave velocities. The minimum pressure to prevent damage at a given temperature should, therefore, be about 1 kbar/100°C.The values obtained at these conditions are considered to be most nearly correct as intrinsic properties of the compact aggregates. Velocity anisotropies at high confining pressures and high temperatures correlate with preferred lattice orientation of the constituent minerals. The effect of dimensional orientation and microcracks on seismic anisotropy seems to be of minor importance in dry rocks. It is the more eliminated the higher the confining pressure. The data do not support the concept of a velocity maximum in depth of 10–20 km.     

An assessment of the near real‐time rainfall network on Canada's eastern Prairies

Abstract

Bogusing errors associated with estimating rainfalls for ungauged points on Canada's eastern Prairies based on the near real‐time network have been determined for growing season totals, summer monthly amounts and summer daily values. The bogusing errors as a percentage of the concurrent area‐average amount or the coefficients of variation decreased as the measurement period increased. Growing season precipitation totals can be approximated to within 20%. The error associated with bogused summer monthly amounts was more than twice as large. The field of summer daily rainfall amounts cannot be estimated accurately. It can be concluded, therefore, that the precipitation network on the eastern Prairies is not sufficient for applications requiring the input of summer daily or monthly precipitation amounts from points other than the gauged locations. The network does, nevertheless, provide relatively accurate estimates of the growing season's precipitation field to assist in defining the climate.

Reductions in the magnitude of the bogusing errors associated with estimated precipitation amounts can be achieved by adding new stations to the network. While additional sites provide data at the newly gauged points, they do little to improve the network's representation of the rainfall field unless the new stations are added in fairly large numbers.     

Long-term summer temperature reconstruction inferred from tree-ring records from the Eastern Carpathians

The first 1,000 year long Carpathian tree-ring width chronology was established based on living and subfossil stone pine (Pinus cembra L.) samples from an upper timberline forest located in Calimani Mts. (Romania). Tree-ring data were standardized using the regional curve standardization method in order to preserve the low and medium frequency climate signals. The de-trended index strongly correlates with summer mean temperature both at annual and decadal scales. The Calimani summer mean temperature anomalies were reconstructed for the period ad 1163-2005 applying the rescaling method. This new climate proxy from the Carpathians shows similar fluctuations to other North Hemispheric temperature reconstructions, but with periods of distinct differences. The fingerprint of Little Ice Age in the Calimani area is visible between ad 1370 and 1630 followed by lagged cold decades in ad 1820 and 1840. The recent warming is evident only after the 1980s in our reconstruction.     

Stratigraphic evolution of the nearshore to fluvial plain of the Upper Cuyo Group,Neuquén,Argentina

The upper portion of the Cuyo Group in the Zapala region, south‐eastern Neuquén Basin (Western Argentina), encompasses marine and transitional deposits (Lajas Formation) overlain by alluvial rocks (Challacó Formation). The Challacó Formation is covered by the Mendoza Group above a second‐order sequence boundary. The present study presents the stratigraphic framework and palaeophysiographic evolution of this Bajocian to Eo‐Calovian interval. The studied succession comprises the following genetic facies associations: (i) offshore and lower shoreface–offshore transition; (ii) lower shoreface; (iii) upper shoreface; iv) intertidal–subtidal; (v) supratidal–intertidal; (vi) braided fluvial to delta plain; (vii) meandering river; and (viii) braided river. The stratigraphic framework embraces four third‐order depositional sequences (C1 to C4) whose boundaries are characterized by the abrupt superposition of proximal over distal facies associations. Sequences C1 to C3 comprise mostly littoral deposits and display well‐defined, small‐scale transgressive–regressive cycles associated with fourth‐order depositional sequences. Such high‐frequency cycles are usually bounded by ravinement surfaces associated with transgressive lags. At last, the depositional sequence C4 delineates an important tectonic reorganization probably associated with an uplift of the Huincul Ridge. This is suggested by an inversion of the transport trend, north‐westward during the deposition of C1 to C3 depositional sequences (Lajas Formation) to a south‐west trend during the deposition of the braided fluvial strata related to the C4 depositional sequence (Challacó Formation).     

Insights into agricultural influences and weathering processes from major ion patterns

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.     

水饱和裂纹对地壳岩样中地震波速及各向异性的影响

选择４种地壳岩石样品,经干燥或水饱和处理后在不同围压条件下测量了在其中传播的纵、横波的速度及其各向异性．在大气压条件下低孔隙度(＜１％岩样中,水饱和样品中的纵波速度明显地比干燥样品中的高,但横波速度的差别不大．因为在低孔隙度岩样中纵波速度对孔隙流体的反应比横波速度敏感,可以用泊松比的变化来反映随着围压的增加晶粒间流体对弹性波传播特性的影响．根据实验数据,按Ｏ’Ｃｏｎｎｅｌｌ模型分别计算了干燥和水饱和岩样中的裂纹密度,与通过实测体应变曲线得到的裂纹孔隙度十分吻合．利用横波的速度和偏振特性可以推断岩样中定向排列微裂纹的空间取向情况．研究表明,同时测量在岩样中传播的纵、横波的速度,通过Ｖｐ／Ｖｓ比值可以给出有关颗粒边界流体的证据,也可以估计岩样中的裂纹密度．     

Untersuchungen zum Abbau von Pharmaka in kommunalen Kläranlagen mit HPLC-Electrospray-Massenspektrometrie

Examination of the Degradation of Drugs in Municipal Sewage Plants Using Liquid Chromatography-Electrospray Mass Spectrometry Numerous drugs can be identified in the secondary effluent of municipal sewage plants. In order to obtain information about the degree of elimination (adsorption, aerobic degradation) of these compounds, a batch reactor containing different drugs in environmentally relevant concentrations and a suspension of activated sludge was coupled to a HPLC-MS-MS system. During a testing period of three days concentration-time-curves were recorded. For most of the examined drugs (acetamidoantipyrine, crotamiton, diclofenac, primidone, propyphenazone) solely a strong decrease of the initial concentration within the first 15 minutes was observed, which was interpreted primarily as adsorption to the activated sludge. For acetaminophenol and pentoxifyllin an additional slower decrease in concentration within several hours was observed. This slower elimination was interpreted to be caused mainly by primary degradation. It could be shown that dihydrocodeine is oxidized to hydrocodone in the batch reactor. The conjugate acetaminophen glucuronide was cleaved.     

Quartz preferred orientation in naturally deformed mylonitic rocks (Montalto shear zone–Italy): a comparison of results by different techniques,their advantages and limitations

International Journal of Earth Sciences - In the geologic record, the quartz c-axis patterns are widely adopted in the investigation of crystallographic preferred orientations (CPO) of naturally...