Hydrogeochemical exploration for Mississippi valley-type deposits, Arkansas, U.S.A.

Three areas located in northern Arkansas, U.S.A., representing differing host rock and mineralization, were selected to investigate the usefulness of hydrogeochemical exploration for Mississippi Valley-type Pb-Zn mineralization. Despite the geologic differences among the areas, there were no great differences in groundwater chemistry and threshold values. Anomalous Pb concentrations, and also anomalous Zn concentrations to a lesser extent, are useful in detecting the Pb-Zn mineralized areas; however, specific deposits could not be located. Because of the low threshold values (about 20 μg/1) for Pb and Zn, spring water must be utilized in order to avoid plumbing contamination.     

The nursery role of seagrass meadows in the upper and lower reaches of the Chesapeake Bay

A two-year trawling and gill-netting study of vegetated and unvegetated bottoms near Parson’s Island, Maryland and near the mouth of the York River, Virginia was carried out to assess the nursery function of submerged vegetation for populations of fishes and decapod crustaceans in the Chesapeake Bay. Results revealed that vegetated bottoms supported substantially larger numbers of decapods, but not fishes, than unvegetated substrates. The lower Bay grassbed was an important nursery area for juvenile blue crabs, although neither of the grassbeds functioned as a nursery for commercially or recreationally valuable fishes. Our results suggest that: (1) further decreases in lower Bay Seagrass biomass would result in reduced numbers of adult blue crabs, but should not substantially affect populations of valuable fish species; (2) additional decreases in Upper Bay submerged vegetation should not produce dramatic change in the population sizes of either adult blue crabs or fishes.     

The distribution and production of the hard clam,Mercenaria mercenaria,in Wassaw Sound,Georgia

Estuaries and Coasts - Hard clams,Mercenaria mercenaria, occurred in four intertidal habitats in the outer, high salinity (18‰) region of Wassaw Sound, Georgia: small feeder creeks $$(\bar x...     

Forecasting in the social and natural sciences: An overview and analysis of isomorphisms

This article identifies and analyzes several points of similarity in the structure and context of forecasting in the social and natural sciences. These include: the limits of identities or universal laws as a basis for forecasts; the corresponding need for simplifying parametric representations of one or more of the variables that enter into identities; various sources of uncertainty about parameterizations; intrinsic limitations on predictability or forecasting accuracy in large-scale systems; the need for sensitivity analyses of model responses to changes in exogenous variables and/or parametric structures; problems of model linkage; and the social (organizational and political) context of forecasts. Suggestions for future lines of inquiry are made in each case. Several of these are such that they can benefit from a sharing of experience and expertise across disciplinary lines.The research reported herein was supported in part by the IC² Institute, The University of Texas at Austin, and in part by National Science Foundation Grant Number SES-8411702. However, the opinions expressed in the paper are those of the authors and do not necessarily reflect those of the sponsoring organizations. We appreciate the advice and comments of Jesse H. Ausubel, Robert S. Chen, Judith Jacobsen, and Richard C. Rockwell on earlier versions of this paper.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Explosive magma-water interactions: Thermodynamics,explosion mechanisms,and field studies

Physical analysis of explosive, magma-water interaction is complicated by several important controls: (1) the initial geometry and location of the contact between magma and water; (2) the process by which thermal energy is transferred from the magma to the water; (3) the degree to and manner by which the magma and water become intermingled prior to eruption; (4) the thermodynamic equation of state for mixtures of magma fragments and water; (5) the dynamic metastability of superheated water; and (6) the propagation of shock waves through the system. All of these controls can be analyzed while addressing aspects of tephra emplacement from the eruptive column by fallout, surge, and flow processes. An ideal thermodynamic treatment, in which the magma and external water are allowed to come to thermal equilibrium before explosive expansion, shows that the maximum system pressure and entropy are determined by the mass ratio of water and magma interacting. Explosive (thermodynamic) efficiency, measured by the ratio of maximum work potential to thermal energy of the magma, depends upon heat transfer from the pyroclasts to the vapor during the expansion stage. The adiabatic case, in which steam immediately separates from the tephra during ejection, produces lower efficiencies than does the isothermal case, in which heat is continually transferred from tephra to steam as it expands. Mechanisms by which thermal equilibrium between water and magma can be obtained require intimate mixing of the two. Interface instabilities of the Landau and Taylor type have been documented by experiments to cause fine-scale mixing prior to vapor explosion. In these cases, water is heated rapidly to a metastable state of superheat where vapor explosion occurs by spontaneous nucleation when a temperature limit is exceeded. Mixing may also be promoted by shock wave propagation. If the shock is of sufficient strength to break the magma into small pieces, thermal equilibrium and vapor production in its wake may drive the shock as a thermal detonation. Because these mechanisms of magma fragmentation allow calculation of grain size, vapor temperature and pressure, and pressure rise times, detailed emplacement models can be developed by critical field and laboratory analysis of the resulting tephra deposits. Deposits left by dense flows of tephra and wet steam as opposed to those left by dilute flows of dry steam and tephra show contrasts in median grain size, dispersal area, grain shape, grain surface chemistry, and bed form.     

Seasonality of materials transport through a coastal freshwater marsh: Riverine versus tidal forcing

Transports of nitrate and suspended solids were measured six times from January 1984 until January 1985 in a small freshwater tidal bayou in south-central Louisiana. The bayou and adjacent marshes are influenced by Atchafalaya River discharges, tides, and coastal weather patterns. Large net ebb-directed water transports occurred in winter, spring, and summer, coincident with high river discharges, indicating riverine dominance. A very small net flood-directed water transport occurred in fall, indicating tidally dominated hydrology. Nitrate and suspended solids transports were net ebb-directed in all seasons, but were two orders of magnitude higher during high river flow. Exports changed as hydrology switched from river dominated to tidally dominated, and as concentrations of materials changed. Comparison of suspended solids and nitrate concentrations in the river and bayou shows that these materials were usually lower in the bayou, indicating retention by the marsh/aquatic system.     

Environmental oxidation rate of manganese(II): bacterial catalysis

A simple mass balance for dissolved manganese(II) in waters containing low levels of oxygen in Saanich Inlet indicates that the residence time for Mn(II) removal to the solid phase is on the order of a few days. The average oxidation state of Mn in particulate material sampled from the region of Mn removal was 2.3–2.7, and electron micrographs revealed structures characteristic of bacterially formed Mn precipitates. Radiotracer experiments utilizing ⁵⁴Mn(II) indicated that removal of Mn from solution in the region of active uptake was substantially blocked by a poison mixture, demonstrating that Mn(II) binding to particulates is catalyzed by bacteria in this environment.     

Sulphur uptake by salt grasses,mangroves, and seagrasses in anaerobic sediments

Stable sulfur isotope analyses show that rooted estuarine plants growing in anoxic sediments incorporate substantial amounts of ³⁴S-depleted sulfides, or oxidation products thereof. In roots, this incorporation predominates over sulfate uptake from interstitial porewater. Either the plants incorporate normally toxic sulfides, or they are creating and using a specialized nutrient pool of oxidized sulfides at the root-sediment interface.     

Solubility of rhodochrosite (MnCO3) in water and seawater

The solubility product of rhodochrosite (MnCO₃) was measured in seawater, deionized water and dilute NaCl solutions. The solubility product extrapolated to infinite dilution at 25.0 C was (2.60 ± 0.07)× 10^?11. The stoichiometric solubility product measured in seawater of 34.27%. salinity was (3.24 ± 0.23) × 10^?9 at 25.0 C and (2.28 ± 0.24) × 10^?9 at 3.3 C. The stoichiometric solubility product is in good agreement with the value calculated from an ion association model. The enthalpy of the reaction is in fair agreement with the estimated value.