中国海相油气田勘探实例之五塔中奥陶系大型凝析气田的勘探和发现

塔中奥陶系碳酸盐岩的勘探始于1989年,直至2005年发现塔中Ⅰ号坡折带奥陶系碳酸盐岩凝析气田,探明加控制石油地质储量1.5×108t(油当量),是我国目前发现的第一个奥陶系生物礁型大油气田。油气的主力产层位于上奥陶统良里塔格组上部,储层为受坡折带控制的陆棚边缘礁滩体石灰岩。油气沿坡折带呈带状展布,为整体含油的大型准层状岩性油气藏。论述了塔中碳酸盐岩大油气田的勘探历程、主要地质特征,以及对海相碳酸盐岩勘探的启示。     

北秦岭丹凤地区产铀花岗岩稀土元素地球化学特征

针对北秦岭丹凤地区产铀花岗岩的区域地层、赋矿围岩、蚀变岩和铀矿石进行稀土元素地球化学研究,结果表明:各类样品具有大体类似的LREE富集及Eu负异常的稀土配分模式,表明它们之间稀土元素特征具有继承性;赋矿黑云母二长花岗岩与区域地层(丹凤岩群变质基性火山岩)稀土元素特征指示,二者均形成于岛弧环境;蚀变花岗岩和铀矿石主要继承了赋矿花岗岩的特征。各类样品Y/Ho值变化范围狭窄,为25.09~33.46,显示它们具有共同的源区。铀矿石具有最高的w_B(∑HREE),且与铀矿石的品位存在正相关关系,暗示HREE与铀的迁移具有同步性。     

威德尔海的重磁场特征及其构造意义

威德尔海是南极洲最大的边缘海。通过搜集威德尔海的重磁资料、历史文献以及总结前人的相关研究成果,介绍了威德尔海的重磁场基本特征以及指示的构造意义。威德尔海最显著的重力特征是在威德尔海的中北部分布着以鲱骨式结构展布的一系列NW-SE向重力异常,其上可见一系列弧形、上凹的以E-W为主要方向的磁力异常。沿南极半岛陆架边缘的重力高一直可延伸到南侧海域,高值区与陆架平行,但是在磁异常上反映不明显。威德尔海原始海盆的形成约在150 Ma,并伴随南北向张裂,随后在140 Ma发生东西向扩张,到约120 Ma异常形成现代南极洲、非洲和南美洲板块的分布格局,鲱骨式结构异常脊也形成于该时期。     

山东北部全新世的人地关系演变: 以海岸变迁和海盐生产为例

根据先秦考古遗址地理分布的分析和郭井子贝壳堤的发掘和调查,复原了6.5~5.0kaB.P. ,4.5~4.0kaB.P.和3.4~2.1kaB.P.的3条海岸线,它们大致与现代海岸线平行分布,年代自南向北逐渐年轻,揭示了山东北部地区全新世海侵和海退过程的主要环节,恢复了全新世海岸变迁的具体历程。对寿光大荒北央遗址出土盔形器内壁凝结物的XRF和XRD分析证明,本区沿海商周时期遗址出土的盔形器应是制盐器具,而沿海盔形器密集分布区与6.5~5.0kaB.P.的海岸线基本重合,表明商周时期海盐生产地域应在6.5~5.0kaB.P.和3.4~2.1kaB.P.的两条海岸线之间。本区的海盐生产与海岸变迁密切相关,人类适应环境和开发资源的主要手段就是从事海盐生产。在6.5~4.0kaB.P. ,人类在滨海地带有了初步的海盐生产,开始了适应环境和利用自然资源的最早尝试,在3.4~2.1kaB.P. ,人类又开始开采地下卤水生产海盐,使现今海拔9~10m以下的广阔地区成为产盐区。本区内陆的山前平原地带则是海盐的主要消费区,也是产盐区所需粮食和各种生产生活用品的供应区。这一分析对研究本区先秦时期的聚落功能演变具有重要意义,也是研究本区全新世人地关系演变的关键视角。     

耕作措施对陕西耕作土壤碳储量的影响模拟*

鉴于农业生态系统土壤有机碳(SOC)平衡对中国农业可持续发展的重要性,文章以陕西农业生态系统为对象,整合农业生物地球化学模型(DNDC)与陕西农业地理信息系统数据库,利用陕西地区气象和作物资料,对陕西省2000年作物生长发育和土壤碳循环进行了模型模拟,实例探讨了耕作管理对土壤碳储量的影响,并由此评价生物地球化学模型在气候变化、土壤性质及农业耕作管理措施对土壤碳含量影响方面的预测能力。敏感性分析表明土壤性状,尤其是初始有机碳含量是影响模型区域尺度模拟的最主要敏感因素。区域模拟使用灵敏系数分析法,分别采用敏感因子的最大、最小值驱动模型在每一模拟单元内的运算,以产生一个土壤有机碳变化的范围值,土壤有机碳变化的真实值应以较大机率包含在这一范围内。分析模拟结果可以得出3点结论: 1)2000年陕西耕作土壤总有机碳储量约为103TgC,是一个大气CO₂源,向大气释放碳0.5TgC; 2)提高作物秸秆还田率是提高陕西农田碳库储量的有效可行措施,将作物秸秆还田率从当前的15 ％ 提高到50 ％ 或90 ％ 会使陕西农田土壤从大气CO₂源转变为汇,每年分别增加土壤有机碳库储量0.7TgC或2.1TgC; 3)施用有机农肥(500kg/hm²)也会增加土壤碳输入,从而提高土壤碳储量,使陕西农田系统转变为较弱的碳(C)源,每年可多固定0.2TgC。     

基于遗传算法的叠前地震波形反演构建虚拟井曲线

叠前地震波形反演能够提供详细的地下地层特征，但由于其计算量大、数据和模型之间的非线性、目标函数的多极值和反演结果的多解性使叠前地震反演的实施成为一大难点。本文通过叠前和叠后混合反演技术采用遗传算法实现了深海无井地震反演。遗传算法思想简单、易于实现和使用、具有隐含并行性和全局搜索能力等优点，基于遗传算法的叠前地震波形反演得到了与井中实际数据基本吻合的速度和密度数据。     

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

Vertical variation of phosphorus forms in surface sediments from Wuli Bay, Taihu Lake, China

1IntroductionPhosphorus,an essential nutrient for the primaryproductivity in freshwater systems,is an important fac-tor controlling lacustrine eutrophication.Although ex-ternal input of phosphorus has been assumed as the vi-tal responsibility for the eutrophication of lakes(ZhuJun et al.,2005),the remobilization of phosphorus insediments has a distinct influence on it as well(Bostr m et al.,1982).The concentrations of totalphosphorus(Ptotal)in the sediments are often related tothe trophic st…     

Diurnal Variations of Hydrochemistry in a Travertine-depositing Stream at Baishuitai, Yunnan, SW China

Diurnal variations of hydrochemistry were monitored at a spring and two pools in a travertine-depositing stream at Baishuitai, Yunnan, SW China. Water temperature, pH and specific conductivity were measured in intervals of 5 and 30 min for periods of 1 to 2 days. From these data the concentrations of Ca²⁺, HCO₃⁻, calcite saturation index, and CO₂ partial pressure were derived. The measurements in the spring of the stream did not show any diurnal variations in the chemical composition of the water. Diurnal variations, however, were observed in the water of the two travertine pools downstream. In one of them, a rise in temperature (thus more CO₂ degassing) during day time and consumption of CO₂ due to photosynthesis of submerged aquatic plants accelerated deposition of calcite, whereas in the other pool, where aquatic plants flourished and grew out of the water (so photosynthesis was taking place in the atmosphere), the authors suggest that temperature-dependent root respiration underwater took place, which dominated until noon. Consequently, due to the release of CO₂ by the root respiration into water, which dominated CO₂ production by degassing induced by temperature increase, the increased dissolution of calcite was observed. This is the first time anywhere at least in China that the effect of root respiration on diurnal hydrochemical variations has been observed. The finding has implications for sampling strategy within travertine-depositing streams and other similar environments with stagnant water bodies such as estuaries, lakes, reservoirs, pools and wetlands, where aquatic plants may flourish and grow out of water.     

Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.