Bathymetry of the Tonga Trench and Forearc: a map series

Four new bathymetric maps of the Tonga Trench and forearc between 14 °S and 27 °S display the important morphologic and structural features of this dynamic convergent margin. The maps document a number of important geologic features of the margin. Major normal faults and fault lineaments on the Tonga platform can be traced along and across the upper trench slope. Numerous submarine canyons incised in the landward slope of the trench mark the pathways of sediment transport from the platform to mid- and lower-slope basins. Discontinuities in the trench axis and changes in the morphology of the landward slope can be clearly documented and may be associated with the passage and subduction of the Louisville Ridge and other structures on the subducting Pacific Plate. Changes in the morphology of the forearc as convergence changes from normal in the south to highly-oblique in the north are clearly documented. The bathymetric compilations, gridded at 500- and 200-m resolutions and extending along 500 km of the landward trench slope and axis, provide complete coverage of the outer forearc from the latitude of the Louisville Ridge-Tonga Trench collision to the northern terminus of the Tonga Ridge. These maps should serve as a valuable reference for other sea-going programs in the region, particularly the Ocean Drilling Program (ODP) and the National Science Foundation MARGINS initiative.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Petrology and mineral chemistry of sedimentary rocks from the Western Solomon Sea

Multichannel seismic reflection profiles recorded in the northern Red Sea show structures that we interpret to be a result of the intrusion of uppermost Miocene salt. We believe that the evaporites are underlaid by attenuated continental crust and the flow of salt is due to renewed faulting of basement in the Pliocene when sea floor spreading began between latitudes 21°N and 15°30°N.     

Evaluation of long-term extreme response statistics of jack-up platforms

This paper is concerned with the models appropriate for the dynamic assessment of jack-ups, concentrating particularly on the long-term response due to random ocean waves and on work-hardening plasticity models used for spud-can response. A methodology for scaling of short-term statistics, calculated using a Constrained NewWave technique, is shown in a numerical experiment for an example jack-up and central North Sea location. The difference in long-term extreme response statistics due to various footing assumptions is emphasised. Results for two environmental load conditions are described (one excluding and one including wind and current effects) and the role of sea-state severity in the variation of short-term extreme response statistics is also highlighted.     

Cloning of a chub metallothionein cDNA and development of competitive RT-PCR of chub metallothionein mRNA as a potential biomarker of heavy metal exposure

Metallothionein has been assayed in a range of aquatic animal tissues as an indicator of metal exposure. We sequenced chub (Leuciscus cephalus) metallothionein cDNA which showed over 90% homology to common carp, goldfish and stone loach and 77% homology to rainbow trout sequences for metallothionein. We then used the extended primer method to develop an accurate quantitative competitive RT-PCR assay for metallothionein mRNA. RT-PCR was used to measure metallothionein mRNA in feral chub from a range of field sites, with different levels of heavy metal pollution, in the West Midlands, UK. Measurements were complemented by analysis of liver and gill metallothionein protein by capillary electrophoresis. There was no significant difference in the metallothionein protein levels between fish of different rivers and there was no evidence of elevation of mRNA at the sites of highest metal exposure. The level of metal exposure (e.g. zinc, nickel and cadmium each ranging between 15 and 28 microg/l ) at the pH (7.5-8.5) of these rivers appears insufficient to elevate hepatic or gill metallothionein in chub. A lack of elevation of hepatic metallothionein mRNA in chub exposed to zinc, copper and manganese for 24 h and 10 days in the laboratory also suggests a non-responsiveness of this species.     

Nature of the connection between the Northern and Southern Zechstein Basins across the Mid North Sea High

The seismic expression of a salt-filled channel which cuts across the Mid North Sea High in Quadrant 37 is described, with features interpreted as being produced by salt-edge dissolution forming both eastern and western margins of the channel. The apparent half-graben nature of the channel is shown to be only superficial, and due to complex faulting associated with, but not defining, its western margin. The shallower faulting here is a Mesozoic to early Tertiary growth fault related to local dissolution of Zechstein salt. The dissolution effect appears in turn to have been localized by the presence of a deeper fault that was already downthrown to the east in Zechstein times, when it seems to have limited the eastward progradation of Zechstein shelf carbonates and anhydrites, and had probably ceased to move significantly before the onset of the Late Cimmerian erosional phase. The origin of this arcuate fault is tentatively ascribed to subsidence around a granite batholith. Zechstein salt originally spread some distance to the east and west of the channel; it was dissolved from the edges inwards, mainly before the Late Cretaceous, giving rise to a thicker Mesozoic sequence on parts of the flanks of the channel than in the middle. Besides providing an interesting structural case history, the features described have implications regarding Zechstein sedimentation, reservoir potential, the tectonic history of the North Sea, and the nature of the Mid North Sea High itself.     

Variability of hydrodynamic load predictions for a tension leg platform

A survey of diffraction/radiation analyses has been performed on behalf of the International Ship and Offshore Structures Congress, Committee I.2. This paper presents the results from the survey, including data from 17 organisations plotted in a common format. The variability of the computed hydrodynamic loads and responses is discussed, and it is concluded that there is a degree of uncertainty in results predicted on the basis of commonly used idealisations. Even in long period waves the variability between the computed results is considerable. To obtain reliable results at the shorter periods associated with heave, pitch and roll resonances of a deep water TLP, much finer meshes than those used by most of the participating organisations would be required.     

A finite element model of interaction between viscous free surface waves and submerged cylinders

This paper describes the simulation of the flow of a viscous incompressible Newtonian liquid with a free surface. The Navier–Stokes equations are formulated using a streamline upwind Petrov–Galerkin scheme, and solved on a Q-tree-based finite element mesh that adapts to the moving free surface of the liquid. Special attention is given to fitting the mesh correctly to the free surface and solid wall boundaries. Fully non-linear free surface boundary conditions are implemented. Test cases include sloshing free surface motions in a rectangular tank and progressive waves over submerged cylinders.     

Structure and Quaternary tectonic history of the Woodlark triple junction region,Solomon Islands

The Woodlark triple junction region, a topographically and structurally complex triangular area of Quaternary age, lies east of Simbo Ridge and southwest of the New Georgia island group, Solomon Islands, at the junction of the Pacific, Australian and Solomon Sea plates. SeaMARC II side-scan imagery and bathymetry in conjunction with seismic reflection profiles, 3.5 kHz records, and petrologic, magnetic and gravity data show that the active Woodlark spreading centre does not extend into this region.South of the triple junction region, the Woodlark spreading centre reoriented at about 2 Ma into a series of short ESE-trending segments. These segments continued to spread until about 0.5 Ma, when the lithosphere on their northern sides was transferred from the Solomon Sea plate to the Australian plate. Simultaneously the Simbo transform propagated northwards along the western side of the transferred lithosphere, forming a trench-trench-transform triple junction located NNW of Simbo island and a new leaky plate boundary segment that built Simbo Ridge.As the Pacific plate approached, the area east of northern Simbo Ridge was tilted northwards, sheared by dominantly right-lateral faults, elevated, and intruded by arc-related magmas to form Ghizo Ridge. Calc-alkalic magmas sourced beneath the Pacific plate built three large strato-volcanic edifices on the subducting Australian plate: Simbo at the northern end of Simbo Ridge, and Kana Keoki and Coleman seamounts on an extensional fracture adjoining the SE end of Ghizo Ridge.A sediment drape, supplied in part from Simbo and Kana Keoki volcanoes, mantles the east-facing slopes of northern Simbo and Ghizo Ridges and passes distally into sediment ponded in the trench adjoining the Pacific plate. As a consequence of plate convergence, parts of the sediment drape and pond are presently being deformed, and faults are dismembering Kana Keoki and Coleman seamounts.The Woodlark system differs from other modern or Tertiary ridge subduction systems, which show wide variation in character and behaviour. Existing models describing the consequences of ridge subduction are likely to be predictive in only a general way, and deduced rules for the behaviour of oceanic lithosphere in ridge subduction systems may not be generally applicable.