Comparing the activity of aluminum in two B horizons developed from volcanic ash deposits in Japan, dominated by short-range ordered aluminosilicates and crystalline clay minerals, respectively

Mechanisms controlling the activity of free aluminum (Al) in Bw1 horizons of soils developed from volcanic ash deposits in Japan were investigated by means of acid-base titrations and kinetic studies. In a Bw1 horizon, with a high content of acid-oxalate extractable Al, soil solution reached equilibrium with short-range ordered aluminosilicates in the order of days. Relatively fast kinetics of the release and precipitation of Al and Si indicate a high reactivity of short-range ordered aluminosilicates in the soil. In the Bw1 horizon of an adjacent soil, with a high content of crystalline clay minerals like halloysite and interlayered vermiculite, solution remained well undersaturated with respect to short-range ordered aluminosilicates and aluminum hydroxide. Apparent equilibrium with respect to halloysite occurred after more than 30 days. This halloysite ( (25 °C)) has a solubility that is less than that reported in the literature ( (25°C)). Our findings suggest that different reactive aluminosilicates may control the activity of free Al in sub-surface horizons of volcanic ash soils with different mineralogy.     

On the Contraction of Protostellar Clouds with Different Metallicities

We examine the thermal and chemical evolution of gravitationally collapsing protostellar clouds with metallicity 0≤Z/Z _⊙≤1.During the first collapse stage, the temperatures are higher for lower metallicity clouds. However, in the course of the adiabatic contraction of transient cores, the evolutionary trajectories of the clouds converge to a curve that is determined only by fundamental physical constants. The trajectories coincide each other thereafter. The size of the stellar core at formation is the same regardless of metallicity. This revised version was published online in July 2006 with corrections to the Cover Date.     

Origin of near-surface high-salinity water observed in the Kuroshio Extension region

Hydrographic data in the Kuroshio Extension (KE) region from 2008 to 2010 show large year-to-year variability in near-surface salinity, including a very large anomalous event in February 2010. During this event, the deep winter mixed layer in the southern KE region had higher salinity than had existed during the previous summer in September 2009. Our analysis shows that advection from the Philippine Sea along the western branch of the North Pacific subtropical gyre, taking approximately 9 months, resulted in this large salinity anomaly in February 2010 and contributes to the interannual salinity variability in the southern KE region.     

Regional climatic effects according to different estimations of biogenic volatile organic compounds during the asian summer monsoon

A series of 60-year numerical experiments starting from 1851 was conducted using a global climate model coupled with an aerosol-cloud-radiation model to investigate the response of the Asian summer monsoon to variations in the secondary organic aerosol (SOA) flux induced by two different estimations of biogenic volatile organic compound (BVOC) emissions. One estimation was obtained from a pre-existing archive and the other was generated by a next-generation model (the Model of Emissions of Gases and Aerosols from Nature, MEGAN). The use of MEGAN resulted in an overall increase of the SOA production through a higher rate of gasto-particle conversion of BVOCs. Consequently, the atmospheric loading of organic carbon (OC) increased due to the contribution of SOA to OC aerosol. The increase of atmospheric OC aerosols was prominent in particular in the Indian subcontinent and Indochina Peninsula (IP) during the pre- and early-monsoon periods because the terrestrial biosphere is the major source of BVOC emissions and the atmospheric aerosol concentration diminishes rapidly with the arrival of monsoon rainfall. As the number of atmospheric OC particles increased, the number concentrations of cloud droplets increased, but their size decreased. These changes represent a combination of aerosol-cloud interactions that were favorable to rainfall suppression. However, the modeled precipitation was slightly enhanced in May over the oceans that surround the Indian subcontinent and IP. Further analysis revealed that a compensating updraft in the surrounding oceans was induced by the thermally-driven downdraft in the IP, which was a result of surface cooling associated with direct OC aerosol radiative forcing, and was able to surpass the aerosolcloud interactions. The co-existence of oceanic ascending motion with the maximum convective available potential energy was also found to be crucial for rainfall formation. Although the model produced statistically significant rainfall changes with locally organized patterns, the suggested pathways should be considered guardedly because in the simulation results, 1) the BVOC-induced aerosol direct effect was marginal; 2) cloud-aerosol interactions were modeldependent; and 3) Asian summer monsoons were biased to a nonnegligible extent.     

Star formation triggered by supernova explosions in young galaxies

We study the evolution of supernova remnants in a low-metallicity medium   Z /Z_⊙= 10⁻⁴ to 10⁻²  in the early universe, using one-dimensional hydrodynamics with non-equilibrium chemistry. Once a post-shock layer is able to cool radiatively, a dense shell forms behind the shock. If this shell becomes gravitationally unstable and fragments into pieces, next-generation stars are expected to form from these fragments. To explore the possibility of this triggered star formation, we apply a linear perturbation analysis of an expanding shell to our results and constrain the parameter range of ambient density, explosion energy and metallicity where fragmentation of the shell occurs. For the explosion energy of  10⁵¹ erg (10⁵² erg)  , the shell fragmentation occurs for ambient densities higher than  ≳10² cm⁻³ (10 cm⁻³  ), respectively. This condition depends little on the metallicity in the ranges we examined. We find that the mode of star formation triggered occurs only in massive  (≳10⁸ M_⊙)  haloes.     

Climatic physical snowpack properties for large-scale modeling examined by observations and a physical model

Here we have conducted an integral study using site observations and a model with detailed snow dynamics, to examine the capability of the model for deriving a simple relationship between the density and thermal conductivity of the snowpack within different climatic zones used in large-scale climate modeling. Snow and meteorological observations were conducted at multiple sites in different climatic regions (two in Interior Alaska, two in Japan). A series of thermal conductivity measurements in snow pit observations done in Alaska provided useful information for constructing the relationship. The one-dimensional snow dynamics model, SNOWPACK, simulated the evolution of the snowpack and compared observations between all sites. Overall, model simulations tended to underestimate the density and overestimate the thermal conductivity, and failed to foster the relationship evident in the observations from the current and previous research. The causes for the deficiency were analyzed and discussed, regarding a low density of the new snow layer and a slow compaction rate. Our working relationships were compared to the equations derived by previous investigators. Discrepancy from the regression for the melting season observations in Alaska was found in common.     

The countermeasures against coastal hazards in Japan

The total length of Japanese coastline is about 34,500 km. Most of the coastal lowlands are now so intensively used that a large proportion of the Japanese coast has been artificially modified. Therefore, coastal countermeasures against several kinds of natural and man-induced hazards are the serious problems for Japanese. When we go down to the beaches, there are many kinds of armor blocks, breakwaters and dykes for the shore protection. Among the Japanese coastline, 15,900 km needs some protection of which 9,400 km was protected with some kinds of artificial structures in 1992. It is probable that no nation has used armor blocks so extensively as Japan.     

Pressure dependence of electrical conductivity of (Mg,Fe)SiO<Subscript>3</Subscript> ilmenite

The electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ ilmenite was measured at temperatures of 500–1,200 K and pressures of 25–35 GPa in a Kawai-type multi-anvil apparatus equipped with sintered diamond anvils. In order to verify the reliability of this study, the electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ perovskite was also measured at temperatures of 500–1,400 K and pressures of 30–35 GPa. The pressure calibration was carried out using in situ X-ray diffraction of MgO as pressure marker. The oxidation conditions of the samples were controlled by the Fe disk. The activation energy at zero pressure and activation volume for ilmenite are 0.82(6) eV and −1.5(2) cm³/mol, respectively. Those for perovskite were 0.5(1) eV and −0.4(4) cm³/mol, respectively, which are in agreement with the experimental results reported previously. It is concluded that ilmenite conductivity has a large pressure dependence in the investigated P–T range.     

Binary formation with different metallicities: dependence on initial conditions

The fragmentation process in collapsing clouds with various metallicities is studied using three-dimensional nested-grid hydrodynamics. Initial clouds are specified by three parameters: cloud metallicity, initial rotation energy and initial cloud shape. For different combinations of these parameters, we calculate 480 models in total and study cloud evolution, fragmentation conditions, orbital separation and binary frequency. For the cloud to fragment during collapse, the initial angular momentum must be higher than a threshold value, which decreases with decreasing metallicity. Although the exact fragmentation conditions depend also on the initial cloud shape, this dependence is only modest. Our results indicate a higher binary frequency in lower metallicity gas. In particular, with the same median rotation parameter as in the solar neighbourhood, a majority of stars are born as members of binary/multiple systems for  <10⁻⁴ Z_⊙  . With initial mass  <0.1 M_⊙  , if fragments are ejected in embryo from the host clouds by multibody interaction, they evolve to substellar-mass objects. This provides a formation channel for low-mass stars in zero- or low-metallicity environments.     

Process of the Tsushima Current formation revealed by ADCP measurements in summer

In order to clarify detailed current structures over the continental shelf margin in the East China Sea, ADCP measurements were carried out in summers in 1991 and 1994 by the quadrireciprocal method (Katoh, 1988) for removing diurnal and semidiurnal tidal flows from observed flows, together with CTD measurements. We discussed the process of the Tsushima Current formation in the East China Sea. The Tsushima Current with a volume transport of 2 Sv (1 Sv=10⁶ m³s^–1) was found north of 31°N. A current with a volume transport of 0.4 Sv was clearly found along the 100 m isobath. Between the Kuroshio and the current along the 100 m isobath, southeastward component of velocity was dominant compared to northwestward one. Four eastward to southeastward currents were found over the sea bed shallower than 90 m depth. Total volume transport of these four currents was 1 Sv, and they seemed to be originated from the Taiwan Strait. Intrusion of offshore water into the inner shelf northwest of Amami Oshima was estimated to have a volume transport of 0.6 Sv. It is concluded that the Tsushima Current is the confluence of these currents over the continental shelf margin with the offshore water intruding northwest of Amami Oshima.