Two stage growth of microdiamond in UHP dolomite marble from Kokchetav Massif, Kazakhstan

The abundance and morphology of microdiamond in dolomite marble from Kumdy‐kol in the Kokchetav Massif, are unusual; a previous study estimated the maximum content of diamonds in dolomite marble to be about 2700 carat ton^?1. Microdiamond is included primarily in garnet, and occasionally in diopside and phlogopite pseudomorphs after garnet. They are classified into three types on the basis of their morphology: (1) S‐type: star‐shaped diamond consisting of translucent cores and transparent subhedral to euhedral very fine‐grained outer parts; (2) R‐type: translucent crystals with rugged surfaces; and (3) T‐type: transparent, very fine‐grained crystals. The S‐type is the most abundant. Micro‐Laue diffraction using a 1.6‐µm X‐ray beam‐size demonstrated that the cores of the star‐shaped microdiamond represent single crystals. In contrast, the most fine‐grained outer parts usually have different orientations compared to the core. Laser–Raman studies indicate that the FWHM (Full Width at Half Maximum) of the Raman band of the core of the S‐type diamond is slightly larger than that for the outer parts. Differences in morphology, crystal orientations, and in the FWHM of the Raman band between the core and the fine‐grained outer‐parts of S‐type microdiamond suggest that the star‐shaped microdiamond was formed discontinuously in two distinct stages.     

Pan-African Alkali Granitoids from the Sør Rondane Mountains, East Antarctica

Alkali granitoids (500-550 Ma) representing a prominent Pan-African magmatic event are widely distributed in the Sør Rondane Mountains, Dronning Maud Land, East Antarctica. Geochemically, they are granitic to syenitic in composition and show an alkaline affinity of A-type granites. They are characterized by high K₂O+Na₂O (7-13 wt%) and K₂O/Na₂O (1-2), low to intermediate Mg#, wide ranges of SiO₂ (45-78 wt%), Sr (20-6500 ppm) and Ba (40-13000 ppm) and have Nb and Ti depletion in the primitive mantle normalized diagram. The granitoids are subdivided into Group I granites, Group II granites, Lunckeryggen Syenitic Complex and Mefjell Plutonic Complex. The Group I granites have higher Mg#, Sr/Ba, Sr/Y, (La/Yb)_N and LREE/HREE, lower A/CNK, SREE and initial ⁸⁷Sr/⁸⁷Sr ratios and lack Eu anomalies compared to those with negative Eu anomalies in the Group II granites. The syenitic rocks from the Mefjell Plutonic Complex are higher in alkali, Ga, Zr, Ba, and have lower Mg#, Rb, Sr, Nb, Y, F and LREE/HREE with positive Eu anomaly, whereas the granites from the Mefjell Plutonic Complex have high LREE/HREE ratios with negative Eu anomaly. The Lunckeryggen syenitic rocks have intermediate Mg#, higher K₂O, P₂O₅, TiO₂, Fe₂O₃/FeO, Ba, Sr/Y and LREE/HREE ratios with lack of Eu anomalies and are lower in Al₂O₃, Ga, Y, Nb and Rb/Sr ratios. Based on chemical characteristics combined with isotopic data, we suggest that the Lunckeryggen syenitic body and Group I granitic bodies may be derived from the mantle-derived hot basic magma by fractional crystallization with minor assimilation. We also suggest that the Group II granites may be derived from assimilation with crustal rocks to varing degrees and then fractional crystallization in higher crustal levels (ACF model). The Mefjell Plutonic Complex seems to be derived from a heterogenetic magma source compared with other granitoids from the Sør Rondane Mountains. The syenitic rocks in the Mefjell Plutonic complex have a unique source (iron-enriched) and have a chemical affinity with the charnockites in Gjelsvikjella and western Mühlig-Hofmannfjella, but not like the Yamato syenites in adjacent areas.     

Geochemical characteristics of zircons in the Ashizuri A‐type granitoids: An additional granite topology tool for detrital zircon studies

Zircon is resistant to alteration over a wide range of geological environments, and isotopic ratios within the mineral provide constraints on ages and their parental magmas. Trace element compositions in zircon are also expected to reflect those of their parent magmas, and have a potential as essential indicators for their host rocks. Because most detrital zircons that accumulate at river mouths are derived primarily from granitoids, the classification of zircon within granitoids is potentially meaningful. This study employs the conventional classification scheme of granites (I‐, S‐, M‐, and A‐types). To clarify geochemical characteristics of zircons in A‐type granites, trace element compositions of zircons extracted from the A‐type Ashizuri granitoids were examined. Zircons from the Ashizuri granitoids commonly show enrichments of heavy rare earth elements and positive Ce anomalies, indicating that these zircons were igneous in origin. In addition, zircons in these A‐type granites are characterized by enrichments of Nb, Y, Ta, Th, and U and strong negative Eu anomalies, which exhibit good positive correlations with those in their whole rocks. This fact indicates that these signatures in zircons reflect well those in their parental bodies and are useful in identifying zircons derived from A‐type granite. Based on compilations of available data, zircons from A‐type granites can be clearly discriminated from other‐types of granites within Nb/Sr–Eu anomaly, U/Sr–Eu anomaly, Nb/Sr–U/Sr, and Nb/Sr–Ta/Sr cross‐plots. All indices used in these diagrams were selected based on the geochemical features of both zircon and whole rock of A‐type granites. Application of these discrimination diagrams to detrital zircons will likely provide further insights. For example, some Hadean detrital zircons plot in similar fields to A‐type granites, implying the existence of A‐type magmatism in the Earth's earliest history.     

Characteristics of coastal trapped waves along the southern and eastern coasts of Australia

The spatial structures and propagation characteristics of coastal trapped waves (CTWs) along the southern and eastern coasts of Australia are investigated using observed daily mean sea level data and results from a high-resolution ocean general circulation model (OGCM), and by conducting sensitivity studies with idealized numerical models. The results obtained from the sea level observations show that shortterm variations, with a typical period of 1 to 2 weeks, dominate the sea level variability in the southern half of Australia. The signal propagates anticlockwise around Australia with a propagation speed of 4.5 m/s or faster in the western and southern coasts and 2.1 to 3.6 m/s in the eastern coast. Strong seasonality of the wave activity, with large amplitude during austral winter, is also observed. It turns out that the waves are mainly generated by synoptic weather disturbances in the southwestern and southeastern regions. The numerical experiment with idealized wind forcing and realistic topography confirms that the propagating signals have characteristics of the CTW both in the southern and eastern coasts. Sensitivity experiments demonstrate that the difference in the phase speed between the coasts and reduction of the amplitude of the waves in the eastern coast are attributed to the different shape of the continental shelf in each region. The structures and the propagation characteristics of the CTWs around Australia are well reproduced in OFES (OGCM for the Earth Simulator) with dominant contribution from the first mode, although meso-scale eddies may modify the structure of the CTWs in the eastern coast. It is also found that generation or reinforcement of the waves by the wind forcing in the southern part of the eastern coast is necessary to obtain realistically large amplitude of the CTWs in the eastern coast.     

Influence of non-photosynthetic pigments on light absorption and quantum yield of photosynthesis in the western equatorial Pacific and the Subarctic North Pacific

Regional variations in the contribution of non-photosynthetic pigments (ā _np^*) to the total light absorption of phytoplankton (ā _ph^*) and its influence on the maximum quantum yield of photosynthesis (φ _m) were investigated. In the western equatorial Pacific, the surface ā _np^* : ā _ph^* ratio was higher in the western warm pool than that in the upwelling region. This difference appears to be attributable to severe nitrate depletion and higher percentage of prokaryotes, which can accumulate very high concentrations of zeaxanthin in the western warm pool. In the subarctic North Pacific, the ā _np^* : ā _ph^* ratio was expected to be higher in the Alaskan Gyre where the thermocline is sharper and iron limitation may possibly be more severe than in the Western Subarctic Gyre. However, the ratio was actually higher in the Western Subarctic Gyre, contradictory to our expectations. This east-west variation appears to be attributable to changes in the taxonomic composition; cyanobacteria were more abundant in the Western Subarctic Gyre. The values of ā _np^* : ā _ph^* and its vertical variations were relatively small in the subarctic North Pacific compared to those in the western equatorial Pacific. These inter-regional variations appear to be attributable to the lower solar radiation intensity, smaller percentage of cyanobacteria, and relatively strong vertical mixing in the subarctic North Pacific. The spatial variations in ā _np^* : ā _ph^* significantly influence φ _m. In comparison with φ _m based on the total light absorption (φ _{m ph}), the values corrected for the contribution of non-photosynthetic pigments (φ _{m ps}) showed an increase in both the western equatorial Pacific and the subarctic North Pacific.     

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.     

Morphodynamics of deltas under the influence of humans

A consistent database was established to characterize key environmental factors known to control delta morphology. The database includes the location, basin morphology, fluvial and sediment discharge to the deltas, delta morphology, ocean energy, and shelf depth reached by the sub-aqueous delta. Fifty-one deltas were selected to cover the global parameter range of rivers entering all major oceans and coastal seas. Seasonal satellite images of the deltas were processed (IKONOS, SPOT, LANDSAT, and MODIS). Predictive statistical relationships were obtained, suitable for hypothesis testing or to constrain/verify numerical models used to simulate the evolution of coastal systems. The area of a delta is best predicted from average discharge, the total sediment load feeding the delta, and the offshore accommodation space. The gradient of a delta plain, measured from the apex of the delta to the coast along the main channel, is best predicted with a ratio of sediment supply to sediment retention, sediment concentration used as a proxy of delta plain sedimentation, and mean water discharge. Widths of distributary channels form a lognormal distribution, with the cumulative width of the river mouths directly related to the maximum discharge, tidal and wave energy. The grain size of topset deposits scales with the river length. Hundreds of millions of people occupy deltas and human engineering is now a major influence on the growth and evolution of many deltas, through control of the flow path of distributary channels, and mitigation of the seasonal flood wave with concomitant change in the delivery of sediment load. More and more deltas are moving away from their pre-Anthropocene morphology, as influenced by pristine sediment supply and sediment dispersal.     

Medium-scale traveling ionospheric disturbances observed by GPS receiver network in Japan: a short review

Medium-scale traveling ionospheric disturbances (MSTID) are wave-like perturbations of the ionospheric plasma with wavelengths of several hundred kilometres and velocities of several hundred metres per second. MSTID is one of the most common ionospheric phenomena that generally induce the perturbations of ionospheric total electron content (TEC) by ∼10¹⁶ electron/m², which corresponds to ∼54 ns (16.2 cm) delay at GPS L1 signal. In the past decade, several new characteristics on MSTIDs have been revealed by the TEC observations using the dense GPS receiver network in Japan. In this paper, we provide a short review of these new observations and summarize the morphological characteristics of MSTIDs in Japan.     

Influence of the east-west component of the interplanetary magnetic field on the intensity of the auroral electrojet

Analysis of interplanetary data has been made to evaluate the influence of the Biny component of the IMF on the magnitude of the AL index, especially with reference to the contribution of B_y in the reconnection process between the IMF and geomagnetic fields in the dayside part of the magnetosphere. The results of the analysis showed that the effect of Biny on AL is predominantly of a different type from that expected by the current theory of reconnection, and the B_y effect of the latter type was found to be much less significant in magnitude than the theory predicts. The discrepancy may be resolved if the region where the reconnection takes place has an elongated shape.