Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan

The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column.     

Seasonal variations of the surface currents in the Tsushima Strait

Seasonal variations of the surface currents in the Tsushima Strait were investigated by analyzing the monthly mean surface currents measured with HF radar. Several new features of the surface currents have been found. One notable feature is the large, complicated seasonal variation in the current structure in the eastern channel of the strait. For example, in the southeastern and northwestern regions of the channel, southwestward countercurrents are found in summer while southeastward acrossshore currents are found in autumn and winter. The wind-driven flow (Ekman flow) as well as surface geostrophic currents are responsible for these complicated variations of the surface currents. To quantify each variation of the flow and current, the wind-driven flow was calculated from the monthly wind (more precisely, the friction velocity) using the monthly speed factor and deflection angle estimated in our previous study, and the surface geostrophic currents were then estimated by subtracting the wind-driven flow from the measured surface currents. It was found that the acrossshore currents are the wind-driven flow, and that the surface geostrophic currents flow almost in the along-shore direction, indicating the validity of the decomposition of the surface velocity into the wind-driven flow and the geostrophic currents using the speed factor and deflection angle. A real-vector empirical orthogonal function (EOF) analysis of the surface geostrophic currents shows a pair of eddies in the lee of Tsushima and Iki Islands as the first mode, which indicates that the southwestward countercurrents in the eastern channel are formed primarily by the incoming Tsushima Warm Current.     

Nd and Sr isotopic variations in acidic rocks formed under a peculiar tectonic environment in Miocene Southwest Japan

Initial Nd and Sr isotopic ratios were obtained for middle Miocene igneous rocks as well as for related rocks from the Outer Zone of Southwest Japan to investigate the petrogenesis of acidic magmas and their relation to a peculiar tectonic environment bearing on the back-arc spreading of the Japan Sea. On the _Nd- _Sr diagram, data points for the acidic rocks fall in the – _Nd, + _Sr quadrant occupying different positions from those for sedimentary and old crustal rocks, and seem to define several subparallel lines which extend towards the lower-righthand sedimentary field. The S-type acidic rocks occupy an intermediate position between I-type rocks and sedimentary ones, a fact suggesting mixing of an igneous component and a sedimentary one. The linear mixing trend observed on the _Nd- _Sr diagram can be attained in the restricted case that the igneous component has similar Sr/Nd concentration ratios to that of the sedimentary one, which implies an intermediate to acidic composition for the igneous component. Inconsistency between the elemental and isotopic variations observed may be reconciled by considering that mixing, probably in the relatively deep part of the crust, might have occured prior to chemical differentiation processes. The episodic igneous activity and the high heat energy required to melt such materials involving sedimentary rocks may be explained by a model in which a hot mantle region probably corresponding to the rising part of the mantle convection supplied the heating energy to the Outer Zone of Southwest Japan when passing beneath Southwest Japan in the course of movement of the hot rising part from the Shikoku basin areas to the Japan Sea area.     

High time resolution monitoring of tropospheric temperature with a Radio Acoustic Sounding System (RASS)

We have observed the time-height variation of the temperature field in the upper troposphere using a Radio Acoustic Sounding System (RASS) which consists of the MU radar and a high-power acoustic transmitter. The fast beam steerability of the MU radar has made it possible to measure temperature profiles in a fairly wide height range in the upper troposphere (5–11 km), even under intense wind conditions. Observations were continued for about 32 hr on 24–26 December, 1986 with a time-height resolution of 30 min and 150 m. During the observation period, the tropospheric jet was so intense that the acoustic wavefronts were severely distorted. Using wind velocity profiles observed by the MU radar we have numerically estimated the propagation of acoustic wavefronts, and further determined favorable pointing directions for the MU radar to receive significant backscattering from refractive index fluctuations produced by the acoustic waves. Conventional radiosonde soundings were carried out every 6 hr, which showed a temperature decrease of 4 K/day in the upper troposphere during the observation period. Temperature profiles taken by RASS agree well with the radiosonde results.     

中国东部新生代玄武岩的地球化学（Ⅱ）Sr、Nd、Ce同位素组成

对有代表性的中国东部新生代玄武岩的Ｓｒ、Ｎｄ和Ｃｅ同位素组成进行了系统的研究，结合系统的微量元素研究结果，进一步阐明其地幔源区同位素组成的不均一性；利用Ｃｅ、Ｎｄ同位素地球化学给出的信息，探讨富集Ⅰ型（ＥＭⅠ）地幔端元的成因。     

Subaqueous eruption and emplacement of the Shinjima Pumice, Shinjima (Moeshima) Island, Kagoshima Bay, SW Japan

The Shinjima Pumice is a fines-depleted pumice lapilli tuff emplaced several thousands years ago at about 100–140 m below sea level. This 40-m-thick deposit comprises many poorly defined flow units, which are 1–10 m thick, diffusely stratified and showing upward-coarsening of pumice clasts with a sharp to transitional base. Parallel to wavy diffuse stratifications are commonly represented by alignment of pumice clasts, especially in the lower half of the flow units. Pumice clasts of block to coarse-lapilli size commonly have thermal-contraction cracks best developed on the surfaces, demonstrating that they were hot but cooled down to the ambient temperatures prior to their emplacement. These features are suggestive of the direct origin of the Shinjima Pumice from subaqueous eruptions. A theoretical consideration on the behavior of subaqueous eruption plumes and hot and cold pumice clasts suggests that subaqueous eruption plumes commonly collapse by turbulent mixing with the ambient water and are transformed into water-logged mass flows.     

Possible europium-normal rare-earth abundances estimated from the lunar samples,and the terrestrial analogue

From the mathematical analysis of the rare-earth data on some of the Apollo 12 samples studied by Hubbard et al. (1971), the possible europium-normal primitive rare-earth pattern, in which europium is normal with respect to the adjacent rare-earth elements, has been estimated. A fact that the igneous rocks (Japanese geosynclinal basalts) appearing to reflect the analogous effect occur locally on the earth enhances our interests in the pattern resulting from the above estimation.     

Rare earth elements in metagabbros from the Mid-Atlantic Ridge and their possible implications for the genesis of alkali olivine basalts as well as the lizard peridotite

Two foliated metagabbros from the Mid-Atlantic Ridge near 30° N were analyzed for rare earth elements. The chondrite-normalized rare earth pattern for one of them is quite similar to those for abyssal tholeiites. The pattern for another sample, however, is somewhat different from the above one. A new set of bulk partition coefficients for rare earth elements has been estimated correspondingly. This set throws a new light on the interpretation that many alkali olivine basalts were produced by a zone melting or partial melting of primary-liquid-type material. Also the same partition coefficients lead us to an inference that the high-temperature peridotite intrusion in the Lizard area, Cornwall, England, is a secondary-solid-type material which was once in equilibrium with a primary-solid-type material, whereas the pyroxenite, Canyon Mountain, Oregon, is a primary-solid-type material.Both of the metagabbros studied show positive europium anomaly.     

Rare-earth and trace elements in the Quaternary volcanic rocks of Hokkaido,Japan

Seven rare-earth elements (La, Ce, Sm, Eu, Tb, Yb, Lu) and Co, Cr, Sc, Ba, Hf and Th have been determined by non-destructive neutron activation analysis on the Quaternary volcanic rocks in Hokkaido, Japan. The trace-element abundances are discussed in terms of the petrological problems, particularly the origin of calc-alkali magma. On the basis of the La/Sm ratio and the contents of K, Ba, Th and La, lateral variations in the contents of trace elements exist across the Kurile and the northern Honshū arcs. The calc-alkali rocks can be classified into three types which correspond to Kuno's three basalt-magma types. There is no essential difference in the rare-earth patterns between the basaltic rocks and the associated calc-alkali rocks in each petrographic province. This suggests that the calcalkali rocks may be derived from the basaltic magmas by fractional crystallization under certain conditions.