Gold in BHVO-1, BIR-1, DNC-1 and BCR-1 by Fire-Assay Preconcentration Neutron Activation Analysis: Sample Size vs. Accuracy

Four mafic USGS rock standards (BHVO-1, BIR-1, DNC-1, BCR-1) were analyzed at three sample sizes (1, 5, and 10 g) for gold by neutron activation analysis subsequent to fire-assay concentration. The results indicate that large samples, in the order of 10 g, are required to produce consistent results, although analyses of variance indicate that sample sizes of 5 g may be used effectively. The analysis of 1 g samples resulted in a large range of values and high standard deviations. BCR-1 was found to be the most homogeneous of the four standards for gold, followed in decreasing order by BIR-1, DNC-1, and BHVO-1. Data for Ir in BIR-1 and DNC-1 are also presented.     

An experimental study of Fe-Mg partitioning between garnet and olivine and its calibration as a geothermometer

The partitioning of Fe and Mg between coexisting garnet and olivine has been studied at 30 kb pressure and temperatures of 900 ° to 1,400 °C. The results of both synthesis and reversal experiments demonstrate that K _D (= (Fe/Mg)_gt/(Fe/Mg)_OI) is strongly dependent on Fe/Mg ratio and on the calcium content of the garnet. For example, at 1,000 °C/30 kb, K _D varies from about 1.2 in very iron-rich compositions to 1.9 at the magnesium end of the series. Increasing the mole fraction of calcium in the garnet from 0 to 0.3 at 1,000 ° C increases K _D in magnesian compositions from 1.9 to about 2.5.The observed temperature and composition dependence of K _D has been formulated into an equation suitable for geothermometry by considering the solid solution properties of the olivine and garnet phases. It was found that, within experimental error, the simplest kind of nonideal solution model (Regular Solution) fits the experimental data adequately. The use of more complex models did not markedly improve the fit to the data, so the model with the least number of variables was adopted.Multiple linear regression of the experimental data (72 points) yielded, for the exchange reaction: 3Fe₂SiO₄+2Mg₃Al₂Si₃O₁₂ olivine garnet 2Fe₂Al₂Si₃O₁₂+3Mg₂SiO₄ garnet olivine H ° (30kb) of –10,750 cal and S ° of –4.26 cal deg^–1 mol^–1. Absolute magnitudes of interaction parameters (W _ij ) derived from the regression are subject to considerable uncertainty. The partition coefficient is, however, strongly dependent on the following differences between solution parameters and these differences are fairly well constrained: W _FeMg ^ol -W _FeMg ^gt 800 cal W _CaMg ^gt -W _CaFe ^gt 2,670 cal.The geothermometer is most sensitive in the temperature and composition regions where K _D is substantially greater than 1. Thus, for example, peridotitic compositions at temperatures less than about 1,300 ° C should yield calculated temperatures within 60 °C of the true value. Iron rich compositions (at any temperature) and magnesian compositions at temperatures well above 1,300 °C could not be expected to yield accurate calculated temperatures.For a fixed K _D the influence of pressure is to raise the calculated temperature by between 3 and 6 °C per kbar.     

Verteilung,Eigenschaften und Entstehung der Auswurfsmassen des Impaktkraters Nördlinger Ries

Regarding the importance of the Ries impact structure in the field of planetary geology an attempt is made to synthesize the presently known results of geologic mapping in the Ries area and of general field and laboratory observations. The ballistic bulk ejecta of the crater (diameter about 23 km) form a continuous blanket of mixed breccia (“Bunte Trümmermassen”). Outside the crater more than 90% of its constituents are derived from unshocked fragments of the 750 m thick pre-Ries sedimentary rock strata. This blanket is overlain with a sharp discontinuity by suevite breccia which forms a continuous layer inside the crater and patch-like isolated occurrences outside the crater. Their pattern of distribution is believed to be primary. Suevite is mainly composed of fragments of all stages of shock metamorphism derived from the crystalline basement. The present asymmetrical distribution of éjecta outside the crater rim results from relatively young erosion during the Pliocene and Pleistocene periods. The erosional history indicates that the primary distribution of ejecta was symmetrical with respect to the center of the crater extending up to a distance of at least some 40 km from the impact center. A number of characteristics of the structure and composition of the Ries ejecta formations are discussed and verified quantitatively by new field data. It is shown that the structure and composition of the ejecta formations can be explained qualitatively by the physics of impact cratering and be duplicated by hypervelocity cratering experiments.     

Anomalous induction in the Carpathians

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A substantial part of this paper was presented at the IAGA symposium Relations between External and Internal Magnetic Variations, XVI. IUGG General Assembly, August–September 1975, Grenoble.     

The variation of crustal thickness across the Swiss Alps based on gravity and explosion seismic data

Summary Recently determined gravity anomalies along the NW-SE oriented Swiss Geotraverse from Basel to Bellinzona are used in combination with seismic refraction data to deduce a crustal section across the Swiss Alps. Topographic, Bouguer, free air, isostatic and geological corrections were applied to the data. Geological features considered in the corrections are the Swiss Molasse basin filled with sediments and the Ivrea body of high-density material. The resultant Bouguer anomaly over the Gotthard massif is 130 mgal lower than the Bouguer anomaly at the northern end of the profile near Basel. The Alpine region is associated with negative isostatic anomalies down to –20 mgal. The crustal thickness is found to increase gradually from the northern end of the profile (thicknessH=30 km) towards the Helvetic nappes at the northern margin of the Alps (H=38 km) and more rapidly towards the Gotthard massif (H=50 km) and further south to Biasca down to a depth of 58 km. From Biasca southward the crustal thickness thins quite rapidly to reach a depth of 30 km at the southern end of the profile near Bellinzona. Thus the Alps have a distinct asymmetric crustal root whose maximum thickness is almost twice the average crustal thickness in Central Europe. With the Mohorovii-discontinuity deduced from seismic observations an average constant density contrast of –0.33 gcm^–3 is found between the lower crust and upper mantle underneath the Alps.Institut für Geophysik, ETH Zürich, Contribution No. 130.     

Demographic aspects of urbanization

Urban growth and urbanization can be defined, measured and studied in a variety of ways but there is little doubt that the demographic dimension is of paramount importance for both the general public and interested scholars. It seem appropriate that this aspect should be given a particular attention during the symposium organized during the International Geographical Congress as well as a special publication resulting therefrom. The present assay attempts to discuss the demographic issues at a very high level of generalization. The basic data used were derived from the latest UN estimates.     

OPTIMUM CHANNEL GEOMETRY AND MINIMUM ENERGY DISSIPATION RATE

1. INTRODUCTIONA natural river adjusts its roughness, channel geometry, slope I length, and Pattern to changing hydrologic, geologic, and manmade conditions. However, some sort of mean condition or quasi-equilibriumcondition appears to exist for natural streams. The earliest attempts to describe the quasi--equlibrium geometry of rivers were the empirical approaches, such as the regime approach proposed by Lacey (1929) andLeoPOld et al. (1953 ). Later, theoretical approaches based on the…     

Biokinetics of Nitrification in the Activated Sludge Process with Bioaugmentation

A laboratory study was conducted to determine the effect of bioaugmentation on nitrification performance in activated sludge process for treating municipal wastewaters. Two continuous flow bench-scale activated sludge systems consisting of 3 reactors each were operated for 30 months. The bacterial culture product used in bioaugmentation contained supplementary heterotrophic and nitrifying microorganisms. Parameters investigated included wastewater strength, hydraulic detention time, and sludge age in an activated sludge reactor system, which were low, medium and high strength; 6, 12, and 24 hours detention time; and 5, 10, and 20 days sludge age. A first reaction order mathematical model was developed for the nitrification process. Statistical fitting of the experimental data to the mathematical model allowed for determination of nitrification rate constant, decay coefficients, minimum aeration time required for initiation of the nitrification process, and the ability of the system to perform nitrification for the applied operation conditions. The results indicated that bioaugmentation improved nitrification at higher influent strength and at longer sludge age, did initiate nitrification earlier in the reactors, and did not affect the nitrification rate nor the decay coefficients.