Late Holocene environmental history on Tristan da Cunha, South Atlantic, based on diatom floristic changes and geochemistry in sediments of a volcanic crater lake

A late Holocene diatom stratigraphy of Bottom Pond (37°05′S, 12°17′W) was studied and interpreted to infer paleolimnological and climate changes on Tristan da Cunha, South Atlantic. The diatom flora of Bottom Pond is dominated by meroplanktonic Aulacoseira alpigena and A. distans and a benthic/epiphytic flora including Achnanthes spp., Naviculadicta spp., Eunotia taxa and Frustulia rhomboides. The flora also includes an important terrestrial and aerophytic component, consisting of several Diadesmis spp., Navicula lapidosa, Nitzschia terrestris and some Pinnularia spp., at times dominating the flora. Peaks of high terrestrial diatom abundances and low abundances and concentrations of Aulacoseira spp., correspond to periods of increased magnetic susceptibility and are interpreted to be the result of increased catchment erosion and/or precipitation leading to enhanced in-wash of species living in the soils around the lake. The diatom record of Bottom Pond most likely registers both local responses to increased erosion in the catchment as well as climatic change of a more regional character. Comparisons with the geochemical record in 2nd Pond on Nightingale Island show a correspondence between the two data sets at 2,000–1,750 cal yrs BP, most likely evidence of increased precipitation in the Tristan da Cunha region. The Tristan da Cunha archipelago is situated at the northern limit of the Southern hemisphere west wind belt and stronger and/or a northward shift of the westerlies, are probably the main causes of the precipitation changes.     

Hydrological and catchment controls on event-scale dissolved organic carbon dynamics in boreal headwater streams

Hydrological events transport large proportions of annual or seasonal dissolved organic carbon (DOC) loads from catchments to streams. The timing, magnitude and intensity of these events are very sensitive to changes in temperature and precipitation patterns, particularly across the boreal region where snowpacks are declining and summer droughts are increasing. It is important to understand how landscape characteristics modulate event-scale DOC dynamics in order to scale up predictions from sites across regions, and to understand how climatic changes will influence DOC dynamics across the boreal forest. The goal of this study was to assess variability in DOC concentrations in boreal headwater streams across catchments with varying physiographic characteristics (e.g., size, proportion of wetland) during a range of hydrological events (e.g., spring snowmelt, summer/fall storm events). From 2016 to 2017, continuous discharge and sub-daily chemistry grab samples were collected from three adjacent study catchments located at the International Institute for Sustainable Development-Experimental Lakes Area in northwestern Ontario, Canada. Catchment differences were more apparent in summer and fall events and less apparent during early spring melt events. Hysteresis analysis suggested that DOC sources were proximal to the stream for all events at a catchment dominated by a large wetland near the outlet, but distal from the stream at the catchments that lacked significant wetland coverage during the summer and fall. Wetland coverage also influenced responses of DOC export to antecedent moisture; at the wetland-dominated catchment, there were consistent negative relationships between DOC concentrations and antecedent moisture, while at the catchments without large wetlands, the relationships were positive or not significant. These results emphasize the utility of sub-daily sampling for inferring catchment DOC transport processes, and the importance of considering catchment-specific factors when predicting event-scale DOC behaviour.     

A pollen record of the last 450 years from a lowland peat bog on Tristan da Cunha,South Atlantic,implying early anthropogenic influence

A pollen diagram from a small peat bog on the island of Tristan da Cunha in the central South Atlantic (37°05'S,12°17'W) is presented. The pollen diagram contains data from both introduced and native plant taxa. The earliest pollen grains from introduced Plantago lanceolata are dated to around AD 1570, and probably represent unintentional introductions of weeds by the earliest Portuguese explorers visiting the islands. After AD 1600, a greater abundance of pollen from introduced plants and declining tree pollen values indicate opening of the lowland vegetation and more intense land use, probably attributable to the effect of seasonal seal and whale hunters. After AD 1800, evidence of increased erosion and more intense land use are inferred from the pollen diagram, reflecting permanent settlement. Copyright © 2011 John Wiley & Sons, Ltd.     

Separating the effects of changes in land management and climatic conditions on long‐term streamflow trends analyzed for a small catchment in the Loess Plateau region,NW China

As an integrated result of many driving factors, significant declines in streamflow were observed in many rivers of the Loess Plateau (NW China). This can aggravate the inherent severe water shortages and threatens the regional development. Therefore, it is urgent to develop adaptive measures to regulate the water yield to ensure water security. A key step for successful implementation of such measures is to separate the response of water yield to the main driving factors of land management and climate change. In this study, the variation of annual streamflow, precipitation, potential evapotranspiration, and climatic water balance in a small catchment in the Loess Plateau (near Pingliang, Gansu province) was examined for over five decades, although the relative contribution of changes in land management and climate on the streamflow reduction were estimated. A statistically significant decreasing trend of ‐1.14 mm y^‐1 in annual streamflow was detected. Furthermore, an abrupt streamflow reduction because of construction of terraces and check‐dams was identified around 1980. Remarkably, 74% of the total reduction in mean annual streamflow can be attributed to the soil conservation measures. Based on a literature review across the Loess Plateau, we found that the impact of changes in land management and climate on annual streamflow diminished with increasing catchment size. This means that there is a dependency on catchment size for the hydrological response to environmental change. This indicates that at least at the local scale well‐considered land management may help ensure the water security at the Loess Plateau. Copyright © 2012 John Wiley & Sons, Ltd.     

Significance of trace elements in syntaxial quartz cement,Haushi Group sandstones,Sultanate of Oman

Trace element contents and distributions in authigenic quartz cement in deeply buried (2500–4000 m) Haushi Group sandstones from wells in Oman have been investigated in order to determine the factors that control trace element uptake during precipitation.Scanning electron microscope-cathodoluminescence images show well developed growth zones within the quartz cement, which correlate with chemical zonations observed in electron microprobe Al distribution maps. The most abundant trace elements are Al (50–3000 μg g^?1), Li (1–100 μg g^?1), Na (1–40 μg g^?1), and Ge (0.3–5 μg g^?1) with a strong linear correlation between Li and Al and a weaker one between Ge and Al. The molar concentration of Li (+ Na) accounts only for ~ 15% of the charge compensation for Al³⁺ substitution of Si⁴⁺. Though H was not measured in this study, these data indicate a major role of H in charge balancing Al³⁺. The samples belong to the same stratigraphic unit and have similar petrography, but show considerable variability in absolute trace element concentrations between different wells. This variability does not correlate with either sample depth or temperature and shows no regional pattern, but seems to reflect petrophysical and tectonic differences within the sedimentary basin.Petrographic observations of the cogenetic mineral assemblages and hydrochemical modelling indicate that a change from the equilibrium assemblage quartz–kaolinite (–dolomite) to quartz–illite (–dolomite) reflects a decrease in the CO₂ concentration and concurrent variations of the Al concentration. It is concluded that changes in the CO₂ concentrations are responsible for fluctuations in fluid Al concentrations and thus likely also in the investigated quartz cements.     

The SOLAS air-sea gas exchange experiment (SAGE) 2004

The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX’s), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO₂, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF₆/³He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments.There was a significant increase in the photosynthetic competence (F_v/F_m) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX’s, rates of net primary production and column-integrated chlorophyll a concentrations had only doubled relative to the unfertilised surrounding waters by the end of the experiment. After 15 days and four iron additions totalling 1.1 ton Fe²⁺, this was a very modest response compared to other mesoscale iron enrichment experiments. An investigation of the factors limiting bloom development considered co-limitation by light and other nutrients, the phytoplankton seed-stock and grazing regulation. Whilst incident light levels and the initial Si:N ratio were the lowest recorded in all FeAXs to date, there was only a small seed-stock of diatoms (less than 1% of biomass) and the main response to iron addition was by the picophytoplankton. A high rate of dilution of the fertilised patch relative to phytoplankton growth rate, the greater than expected depth of the surface mixed layer and microzooplankton grazing were all considered as factors that prevented significant biomass accumulation. In line with the limited response, the enhanced biological draw-down of pCO₂ was small and masked by a general increase in pCO₂ due to mixing with higher pCO₂ waters. The DMS precursor DMSP was kept in check through grazing activity and in contrast to most FeAX’s dissolved dimethylsulfide (DMS) concentration declined through the experiment. SAGE is an important low-end member in the range of responses to iron addition in FeAX’s. In the context of iron fertilisation as a geoengineering tool for atmospheric CO₂ removal, SAGE has clearly demonstrated that a significant proportion of the low iron ocean may not produce a phytoplankton bloom in response to iron addition.     

Petrography and geochemistry of Cretaceous to quaternary siliciclastic rocks in the Tarfaya basin,SW Morocco: implications for tectonic setting,weathering, and provenance

The petrography, heavy mineral analysis, major element geochemical compositions and mineral chemistry of Early Cretaceous to Miocene–Pliocene rocks, and recent sediments of the Tarfaya basin, SW Morocco, have been studied to reveal their depositional tectonic setting, weathering history, and provenance. Bulk sediment compositional and mineral chemical data suggest that these rocks were derived from heterogeneous sources in the Reguibat Shield (West African Craton) including the Mauritanides and the western Anti-Atlas, which likely form the basement in this area. The Early Cretaceous sandstones are subarkosic in composition, while the Miocene–Pliocene sandstones and the recent sediments from Wadis are generally carbonate-rich feldspathic or lithic arenites, which is also reflected in their major element geochemical compositions. The studied samples are characterized by moderate SiO₂ contents and variable abundances of Al₂O₃, K₂O, Na₂O, and ferromagnesian elements. Binary tectonic discrimination diagrams demonstrate that most samples can be characterized as passive continental marginal deposits. Al₂O₃/Na₂O ratios indicate more intense chemical weathering during the Early Cretaceous and a variable intensity of weathering during the Late Cretaceous, Early Eocene, Oligocene–Early Miocene, Miocene–Pliocene and recent times. Moreover, weathered marls of the Late Cretaceous and Miocene–Pliocene horizons also exhibit relatively low but variable intensity of chemical weathering. Our results indicate that siliciclastics of the Early Cretaceous were primarily derived from the Reguibat Shield and the Mauritanides, in the SW of the basin, whereas those of the Miocene–Pliocene had varying sources that probably included western Anti-Atlas (NE part of the basin) in addition to the Reguibat Shield and the Mauritanides.     

Comparative Studies of Population Synthesis Models in the Framework of Modified Strömgren Filters

Evolutionary models form a vital part of stellar population research in understanding their evolution, but despite their long history of development, they are often misrepresented and the properties of stellar population observed through broadband and spectroscopic measurements are also misinterpreted. With growing numbers of these synthesis models, model comparison becomes an important analysis to choose a suitable model for understanding stellar populations and model up-gradation. Along with model comparison, we reinvestigate the technique of modified Strömgren photometry to measure reliable parameter-sensitive colours and estimate precise model ages and metallicities. The assessment of Rakos/Schulz models with GALEV and Worthey’s Lick/IDS model find smaller colour variation: Δ(uz ? vz) ≤ 0.056, Δ(bz ? yz) ≤ ?0.05 and Δ(vz ? yz) ≤ 0.061. The study conveys a good agreement of GALEV models with modified Strömgren colours but with poor UV model predictions and observed globular cluster data, while the spectroscopic models perform badly because of outdated isochrone and stellar spectral libraries with inaccurate/insufficient knowledge of various stellar phases and their treatment. Overall, the assessment finds modified Strömgren photometry well suited to study different types stellar populations by mitigating the effects of age-metallicity degeneracy.     

Loads on Sprayed Waterproof Tunnel Linings in Jointed Hard Rock: A Study Based on Norwegian Cases

A composite tunnel lining system based on a sprayed waterproofing membrane combined with sprayed concrete is currently being considered for future Norwegian rail and road tunnels. Possible loading of the tunnel linings caused by water pressure is being investigated. This tunnel lining system consists of a waterproof membrane which, during application on the sprayed concrete lining, bonds mechanically to the sprayed concrete on either side. Hence, a continuous, sealing, and non-draining structure from the rock mass to the interior tunnel surface is formed in the walls and crown. Experiences from some successful recent projects with this lining system in Europe are reviewed. However, these experiences are not directly comparable to the Scandinavian hard rock tunnel lining approach, which utilizes a relatively thin sprayed and irregular concrete layer for permanent lining. When considering the sprayed membrane and sprayed concrete composite lining concept, introducing a partially sealing and undrained element in the lining, the experiences with the traditionally used lining systems in Norway need to be reconsidered and fully understood. A review of several hard rock tunnels with adverse conditions, in which the tunnel lining has been subject to load monitoring, shows that only very small loads in the tunnel linings occur. Recent investigations with in situ water pressure testing, including two sites with the composite sprayed membrane in a partially drained waterproof tunnel lining, are discussed. In a case with a cavern located in a hydraulically saturated rock mass subjected to approximately 8 bar hydrostatic pressure, a negative pressure gradient towards the tunnel lining has been measured. The investigation results from the Norwegian test sites indicate that no significant loading of the tunnel lining takes place in a hydraulically saturated rock when applying this composite waterproof tunnel lining in parts of the tunnel perimeter.