The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed.Publication authorized by the Director, U.S. Geological Survey     

Seismic investigation of crust-mantle transition in continental rift systems - Jordan-Dead Sea rift and Rhinegraben

The recent acquisition of high-quality seismic refraction data in the Jordan—Dead Sea rift and adjacent areas has made possible the investigation of the dynamic properties of seismic P-waves refracted and reflected at the crust—upper mantle boundary.

These waves cause high-amplitude arrivals near the outer cusp of the travel-time curve which are followed by an abrupt decrease in amplitudes at increasing distances beyond the cusp.

It has been shown that such amplitude distributions can only be the result of a smooth rapid increase of velocity with depth. In the case of the Jordan—Dead Sea rift the amplitude distribution indicates the presence of a transition zone between the lower crust and upper mantle in which the velocity increases smoothly. The interpretation of seismic refraction data in the Rhinegraben indicates the existence of a similar transition zone. In both rifts the crust—mantle boundary outside the rift is represented by sharp velocity discontinuity.

The comparison of the velocity structure of the crust—upper mantle boundary suggests that a smooth transition zone at the base of the lower crust is a characteristic property of continental rifts which could be interpreted in terms of crust—mantle interaction.     

Sandwaves on the Southeast Vietnam Shelf recorded by high resolution seismic profiles: formation and mechanism

The application of high resolution seismic data using boomer sound source has revealed a wide distribution of large-scale bedforms (sandwaves) on the Southeast Vietnam continental shelf. Bedforms that are a few meters high in wave height and hundreds of meters long in wavelength are primarily developed in the inner shelf (20–40 m) and considered to be formed under the present-day marine hydrodynamic conditions. Those bedforms developed in the deeper water (120 m) of the northernmost part of the continent can be interpreted as the relict morphological features formed during the latest sea-level lowstand of the late Pleistocene period. Two sediment transport paths have been identified on the basis of the bedform’s leeward orientation: northeast-southwest (along-shore) and north-south (cross-shore). A quantitative bottom current map is constructed from sandwave dimensions, surface sediments and measurement data. The strongest current velocities that gradually decrease toward the southwest are indicated by large sandwaves in the north (field B). Water depth, surficial sediment composition and bottom current are three factors that control the development of bedforms.     

The structure of the lower crust at the Argentine continental margin, South Atlantic at 44°S

It is well established that the Argentine passive margin is of the rifted volcanic margin type. This classification is based primarily on the presence of a buried volcanic wedge beneath the continental slope, manifested by seismic data as a seaward dipping reflector sequence (SDRS). Here, we investigate the deep structure of the Argentine volcanic margin at 44°S over 200 km from the shelf to the deep oceanic Argentine Basin. We use wide-angle reflection/refraction seismic data to perform a joint travel time inversion for refracted and reflected travel times. The resulting P-wave velocity-depth model confirms the typical volcanic margin structure. An underplated body is resolved as distinctive high seismic velocity (v_p up to 7.5 km/s) feature in the lower crust in the prolongation of a seaward dipping reflector sequence. A remarkable result is that a second, isolated body of high seismic velocity (v_p up to 7.3 km/s) exists landward of the first high-velocity feature. The centres of both bodies are 60 km apart. The high-velocity lower-crustal bodies likely were emplaced during transient magmatic–volcanic events accompanying the late rifting and initial drifting stages. The lateral variability of the lower crust may be an expression of a multiple rifting process in the sense that the South Atlantic rift evolved by instantaneous breakup of longer continental margin segments. These segments are confined by transfer zones that acted as rift propagation barriers. A lower-crustal reflector was detected at 3 to 5 km above the modern Moho and probably represents the lower boundary of stretched continental crust. With this finding we suggest that the continent–ocean boundary is situated 70 km more seaward than in previous interpretations.     

Weathering and the mobility of phosphorus in the catchments and forefields of the Rhône and Oberaar glaciers, central Switzerland: Implications for the global phosphorus cycle on glacial-interglacial timescales

In this study we evaluate the dynamics of the biophile element phosphorus (P) in the catchment and proglacial areas of the Rhône and Oberaar glaciers (central Switzerland). We analysed erosion and dissolution rates of P-containing minerals in the subglacial environment by sampling water and suspended sediment in glacier outlets during three ablation and two accumulation seasons. We also quantified biogeochemical weathering rates of detrital P in proglacial sedimentary deposits using two chronosequences of samples of fresh, suspended, material obtained from the Oberaar and Rhône water outlets, Little-Ice-Age (LIA) moraines and Younger Dryas (YD) tills in each catchment. Subglacial P weathering is mainly a physical process and detrital P represents more than 99% of the precipitation-corrected total P denudation flux (234 and 540 kg km⁻² yr⁻¹ for the Rhône and Oberaar catchments, respectively). The calculated detrital P flux rates are three to almost five times higher than the world average flux. The precipitation-corrected soluble reactive P (SRP) flux corresponds to 1.88-1.99 kg km⁻² yr⁻¹ (Rhône) and 2.12-2.44 kg km⁻² yr⁻¹ (Oberaar), respectively. These fluxes are comparable to those of tropical rivers draining transport-limited, tectonically inactive weathering areas.In order to evaluate the efficiency of detrital P weathering in the Rhône and Oberaar proglacial areas, we systematically graded apatite grains extracted from the chronosequence in each catchment relative to weathering-induced changes in their surface morphologies (grades 1-4). Fresh apatite grains are heavily indented and dissolution rounded (grade 1). LIA grains from two 0-10 cm deep moraine samples show extensive dissolution etching, similar to surface grains from the YD profile (mean grades 2.7, 3.5 and 3.5, respectively). In these proglacial deposits, the weathering front deepens progressively as a function of time due to biocorrosion in the evolving acidic pedosphere, with mechanical indentations on grains acting as sites of preferential dissolution. We also measured iron-bound, organic and detrital P concentrations in the chronosequence and show that organic and iron-bound P has almost completely replaced detrital P in the top layers of the YD profiles. Detrital P weathering rates are calculated as 310 and 280 kg km⁻² yr⁻¹ for LIA moraines and 10 kg km⁻² yr⁻¹ for YD tills. During the first 300 years of glacial sediment exposure P dissolution rates are shown to be approximately 70 times higher than the mean global dissolved P flux from ice-free continents. After 11.6 kyr the flux is 2.5 times the global mean. These data strengthen the argument for substantial changes in the global dissolved P flux on glacial-interglacial timescales. A crude extrapolation from the data described here suggests that the global dissolved P flux may increase by 40-45% during the first few hundred years of a deglaciation phase.     

A late Holocene paleo-productivity record in the western Gulf of Maine,USA, inferred from growth histories of the long-lived ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>)

To investigate environmental variability during the late Holocene in the western Gulf of Maine, USA, we collected a 142-year-old living bivalve (Arctica islandica) in 2004, and three fossil A. islandica shells of the Medieval Warm Period (MWP) and late MWP / Little Ice Age (LIA) period (corrected ¹⁴C_AMS = 1030 ± 78 ad; 1320 ± 45 ad; 1357 ± 40 ad) in 1996. We compared the growth record of the modern shell with continuous plankton recorder (CPR) time-series (1961–2003) from the Gulf of Maine. A significant correlation (r ² = 0.55; p < 0.0001) exists between the standardized annual growth index (SGI) of the modern shell and the relative abundance of zooplankton species Calanus finmarchicus. We therefore propose that SGI data from A. islandica is a valid proxy for paleo-productivity of at least one major zooplankton taxa. SGIs from these shells reveal significant periods of 2–6 years (NAO-like) based on wavelet analysis, multitaper method (MTM) analysis and singular spectrum analysis (SSA) during the late Holocene. Based on established physical oceanographic observation in the Gulf of Maine, we suggest that slope water variability coupled with North Atlantic Oscillation (NAO) dynamics is primarily responsible for the observed SGI variability. Special Issue: AGU OS06 special issue “Ocean’s role in climate change—a paleo perspective”.     

Delimiting the eastern extent of the Altyn Tagh Fault: Insights from structural analyses of seismic reflection profiles

The Altyn Tagh Fault (ATF) serves as a key continental‐scale controlling structural element of the Tibetan Plateau. However, its eastward extent remains controversial. Here we use high‐resolution seismic reflection profiles to investigate the subsurface structures of the easternmost ATF and use these to delimit the easternmost extent of the fault. The structural analyses show an eastward geometric change from transpressional positive flower structures to compressional thrusts, with transpression‐induced shortening magnitudes decreasing eastwards from a maximum of ~5.3 km to being absent. Stratigraphic controls indicate that the deformation took place over the last ~<1.2 Ma. Our wider findings lead us to: (a) reject the suggestion that the ATF previously extended beyond the Kuantan Shan‐Hei Shan to link with the Alxa‐East Mongolia Fault; and (b) propose that the rigid block model used to describe the Tibetan Plateau crust is not consistent with the extent and structural details of the easternmost ATF.     

Burning molten metallic spheres: One class of ball lightning?

Abrahamson and Dinniss [2000. Ball lightning caused by oxidation of nanoparticle networks from normal lightning strikes on soil. Nature 403, 519–521] proposed a theory of ball lighting in which silicon nanoparticles undergo slow oxidation and emit light. Paiva et al. [2007. Production of ball-lightning-like luminous balls by electrical discharges in silicon. Physical Review Letters 98, 048501] reported that an electric arc to silicon produced long-lasting luminous white spheres showing many characteristics of ball lightning. We show experimentally that these consist of burning molten silicon spheres with diameters in the 0.1–1 mm range. The evidence of our experiments leads us to propose that a subset of ball lightning events may consist of macro-scale molten spheres of burning metallic materials likely to be ejected from a conventional lightning strike to earth.     

Arma models for earthquake ground motions

This paper outlines the use of discrete, autoregressive/moving-average (ARMA) models for identification and estimation of parameters in models derived from analysis of uniformly digitized earthquake ground motion acceleration data. Such models are of equal generality as compared to continuous-time models and have a number of significant advantages for purposes of digital analysis and simulation. The structure of ARMA models is briefly described, their relation to continuous models noted, and results of their application to a number of recorded accelerograms summarized.