Pulp and paper mill pollution and subsequent ecosystem recovery of a large boreal lake in Finland: a paleolimnological analysis

Sedimentary diatom frustules and chironomid remains, in addition to the chemical stratigraphy of 32 elements and resin acids, were studied from short-core samples taken from two basins and a sheltered bay of Lake Päijänne in southern Finland (about 61 °10–62 °15 N, 25 °30 E). The lake was formerly oligotrophic but has been subject to effluent loading from pulp and paper mills during the past century since the opening of the first pulp mill in the 1880s. Four developmental phases were distinguished and named mainly according to the effects found in the basin close to the pollution source: (1) the pre-industrial phase (from the 1800s to ca. 1920), including the early years of industrialization, with low impacts; (2) the phase of increasing pollution (ca. 1920–1969); (3) the phase of severe pollution (1970–1981); and (4) the water protection phase (1982 onwards).Distinct differences were observed between pelagic (diatoms) and benthic (chironomid) ecosystems in their response to pollution. Effluent loading from the pulp and paper mills had a pronounced impact on chironomid assemblages, but only a slight influence on diatoms in the basin close to the pollution source. In the southern basin, approximately 60 km downstream, an increase in acidophilous species was observed in the diatom assemblages during the early years of pollution, but changes in chironomids in this basin were negligible. The water protection work of the past 30 years, which has led to an improvement in water quality and a marked recovery of the profundal biota, has also resulted in a slight increase in primary production of the lake. The decrease in brown-coloured effluent water has led to an increase in thickness of the lake's photic productive layer, while the toxicity of the water has simultaneously diminished. Rapid changes in chironomid assemblages and sedimentation observed in the sheltered bay highlight the importance of local land-use activities as causes of environmental change in this area, and especially their effects on sedimentation and benthic life.     

Interplanetary propagation of relativistic solar protons

Particle fluxes and pitch angle distributions of relativistic solar protons at Earth's orbit have been determined by Monte Carlo calculations. The analysis covers two hours after the release of the particles from the Sun and total of 8 × 10⁶ particle trajectories were simulated. The pitch angle scattering was assumed to be isotropic and the scattering mean free path was varied from 0.1 to 4 AU.The intensity-time profiles after a delta-like injection from the Sun show that the interplanetary propagation is clearly non-diffusive at scattering mean-free paths above 0.5 AU. All pitch angle distributions have a steady minimum at 90 °, and they become similar about 20 min after the arrival of first particles.As an application, the solar injection profile and the interplanetary scattering mean-free path of particles that gave rise to the GLE on 7 May, 1978 were determined. In contrast to the values of 3–5 AU published by other authors, the average scattering mean-free path was found to be about 1 AU.     

Recordings and occurrence of geomagnetically induced currents in the Finnish natural gas pipeline network

A project implemented to study the effects of space weather on the Finnish natural gas pipeline was started in August 1998. The aims of the project were (1) to derive a model for calculating geomagnetically induced currents (GIC) and pipe-to-soil (P/S) voltages in the Finnish natural gas pipeline, (2) to perform measurements of GIC and P/S voltages in the pipeline and (3) to derive statistical predictions for the occurrences of GIC and P/S voltages at different locations in the pipeline network.GIC and P/S voltage were recorded at a compressor station. The GIC measurement was made with two magnetometers, one right above the pipe, and another at the Nurmijärvi Geophysical Observatory about 30 km southwest. The largest GIC since November 1998 has been 30 A. The P/S voltage recording was stopped in May 1999, but GIC is still measured.GIC statistics were derived based on the recordings of the geomagnetic field at Nurmijärvi. The geoelectric field was calculated by using the plane wave model. This field was input to the general pipeline model resulting in the distribution of currents and P/S voltages at selected points in the pipeline. As could be expected, the largest P/S voltage variations occur at the ends of the pipeline network, while the largest GIC flow in the middle parts.     

Structure of the crust and uppermost mantle beneath southern Finland revealed by analysis of local events registered by the SVEKALAPKO seismic array

In 1998–1999, a large-scale seismic array was deployed in Finland as a part of the EUROPROBE/SVEKALAPKO subproject, involving 14 European universities and research institutes. The objective of the project was to map the deep lithosphere structure and thickness beneath the Fennoscandian Shield by means of teleseismic events. In addition, about 580 local seismic events were registered during the data acquisition period. Among them, only eight local earthquakes were recorded, the rest being quarry blasts from mining sites in Russia, Finland, Estonia and Sweden. In this study, we present the analysis of the seismic wave field from the strongest local events registered by the majority of the stations of the SVEcofennian–KArelian–LAPland–KOla Transect (SVEKALAPKO) array with the aim of mapping the structure of the upper mantle beneath the array. For this purpose, we selected the events corresponding to a single source type and compared these recordings with those from wide-angle reflection and refraction experiments in the area to identify the regional phases. The record sections of selected events demonstrate strong reflections (PmP) from the Moho boundary. The refracted Pn phases can be seen as first arrivals at distances of about 200–400 km from the source. At offsets of about 400–800 km, phases reflected from inhomogeneities in the uppermost mantle (P1) and double reflections from the Moho boundary (PmPPmP) were recorded.Results from 2D forward ray trace modeling of reflected and refracted P-waves along four profile swathes from SVEKALAPKO stations demonstrate that the mantle reflections originate from two different groups of boundaries beneath the array: one group of phases arrive from subhorizontal and gently dipping reflectors below the Moho boundary at a depth of 70–90 km, while the other group are phases originating from a depth of 100 to 130 km. Based on the irregular character of the first group of reflections, their different spatial orientation and correlation with the Moho offsets, we interpret the boundaries of this group as relicts of ancient subduction and collision processes. The second group of reflections can be explained by a transition from mechanically strong to mechanically weak lithosphere.     

Geochemistry and mineralogy of platinum-group elements at Hartley Platinum Mine,Zimbabwe

The behaviour of platinum-group elements (PGE) in the exogenic cycle was examined in profiles of oxidized Main Sulfide Zone (MSZ) ores, in which the general metal distribution patterns of the pristine MSZ are grossly preserved. However, at similar Pt grades, significant proportions of Pd have been lost from the system. This indicates that Pd is more mobile than Pt and is dispersed in the supergene environment. Sperrylite and cooperite/braggite are stable in the oxidized MSZ. In contrast, the (Pt,Pd)-bismuthotellurides, common in pristine MSZ ores, have disintegrated, and ill-defined (Pt,Pd)-oxides or (Pt,Pd)-hydroxides have formed. The assemblage of detrital PGM present in the Makwiro River close to the Hartley Platinum Mine indicates further mineralogical changes. Sperrylite largely remains stable whereas most cooperite/braggite grains have been partly altered or completely destroyed. Grains of Pt-Fe alloy are ubiquitous in the alluvial sediments. Most likely, these grains are neo-formations that formed either from pre-existing, unstable PGM or via a solution stage under low-temperature conditions.     

Slope variations on the surface of Phobos

It has been suggested that slope fluctuations on the scale of pixel dimensions could be determined by statistical photoclinometry. A closer study of the surface of Phobos reveals variations in the scattering properties of single particles and micro-structures formed by the particles. In the present context, the photoclinometric method of brightness moments is extended to account for these variations by allowing statistical fluctuations in the phase function of the assumed Lommel-Seeliger scattering law. The mean slope on the investigated regions of Phobos has been found to vary from approximately 12 degrees on a 61m scale to approximately 7 degrees on a 216-272m scale. On the same scales, a value of the order of 2% has been obtained for the standard deviation of the scattering phase function. Hints of a fractal-like scale-invariance have been noticed in the covariance function of brightness.     

The tilt effect for Saturn's rings

Multiple-scattering computations are carried out to explain the variation of the observed brightness of the A and B rings of Saturn with declination of the Earth and Sun. These computations are performed by a doubling scheme for a homogeneous plane-parallel scattering medium. We test a range of choices for the phase function, albedo for single scattering, and optical depth of both the rings. Isotropic scattering and several other simple phase functions are ruled out, and we find that the phase function must be moderately peaked in both the forward and backward directions. The tilt effect can be explained by multiple scattering in a homogeneous layer, but, for ring B, this requires a single-scattering albedo in excess of 0.8. The brightest part of ring B must have an optical depth greater than 0.9. We find that the tilt effect for ring A can be reproduced by particles having the same properties as those in ring B with the optical depth for the A ring in the range 0.4 to 0.6.     

Depositional history of peatland pines (Pinus sylvestris L.) in NW Enontekiö, Finnish Lapland: implications for Middle Holocene drought and temperature fluctuations

High altitude and latitude findings of subfossil peatland pine trees were unearthed from the region of NW Finnish Lapland and dated by ¹⁴C and tree-ring methods. The depositional history of the trees illustrated two distinct peatland pine phases dated to Middle Holocene intervals 4900–4400 and 4100–3400 cal. a BC. It seems evident that both thermal and hydroclimatic fluctuations have played roles of varying importance in the establishment of this pine population and its demise. The presence of these pines, from a site ~60 km north of the coniferous timberline and conditions ~1 °C and 100 degree-days colder than those at the present-day timberline, concurs with previous studies demonstrating the association between the high-latitude summer-temperature cooling and circumpolar timberline retreat since the Middle Holocene due to Milankovitch forcing. On the other hand, the peatland pine recruitment was made possible by drier than present surface conditions during the previously reconstructed Middle Holocene drought anomaly (Hyvärinen-Alhonen event). Our data suggest this event was not continuous but reached its two-phase climax during the peatland pine phases, with an interruption of several centuries with moister surface conditions between 4400 and 4100 cal. a BC. The findings highlight the sensitivity of well-dated peatland tree assemblages in terms of recording past climatic evolution and events and the need for new collections from north and south Fennoscandia and the Baltic region, for more detailed analyses over extended time intervals and regions.     

Particle Size Distribution and Gas-Particle Partition of Polycyclic Aromatic Hydrocarbons in Helsinki Urban Area

Ambient concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured in Helsinki (Finland). Particle mass size distributions were obtained with a cascade impactor (12 stages) with glass fibre filters as substrates. Simultaneously with the impactor measurements, particulate and gaseous PAHs were collected on a quartz filter and XAD-2 adsorbent, respectively, for evaluation of gas-partition coefficients. Samples were analysed for PAHs by on-line coupled supercritical fluid extraction — liquid chromatography — gas chromatography — mass spectrometry. The impactor results showed that most of the PAHs in Helsinki urban area were concentrated in fine particles (<2.5 μm diameter) with unimode peak at about 1 μm. The results were comparable with the number distribution measured with a differential mobility particle sizer. Total amounts of PAHs (gas + particle) varied from 15 (acenaphthylene) to 1990 (fluorene) pg/m³. The PAHs lighter than 202 amu (pyrene and fluoranthene) were exclusively in gas phase, whereas those heavier than 202 amu were mostly associated with particles. A plot of the partition coefficients (logKp) versus the temperature dependent sub-cooled vapour pressures (logp _L ⁰ ) showed a gradient of −0.66, which deviated from equilibrium state (gradient = −1).     

The investigations of aerosol particle formation in urban background area of Helsinki

In this study the possible conditions for new aerosol particle formation in a background area of Helsinki have been analysed. The measurements of aerosol particle size distribution, main gaseous pollutant compounds, UV spectra and meteorological parameters were performed during April–May 1993. The main interest was concentrated on the investigations of photochemical OH radical formation, the oxidation of gas phase SO₂ to H₂SO₄ and the formation of H₂SO₄---H₂O aerosol particles. The measurements were analysed using a model for OH radical formation and aerosol dynamics. The analysis of aerosol size distributions was carried out using positive matrix factorization. The main conclusion is that based on our model analysis no evidence of new particle formation in the vicinity of the measurement station was found. However, the high concentrations of aerosol particles in the ultrafine size range indicate that some other particle formation pathways are to be considered.