Removal of cationic dye methylene blue (MB) from aqueous solution by ground raw and base modified pine cone powder

The adsorption capacity of raw and sodium hydroxide-treated pine cone powder in the removal of methylene blue (MB) from aqueous solution was investigated in a batch system. It was found that the base modified pine cone exhibits large adsorption capacity compared with raw pine cone. The extent of adsorption capacity was increased with the increase in NaOH concentration. Overall, the extent of MB dye adsorption increased with increase in initial dye concentration, contact time, and solution pH but decreased with increase in salt concentration and temperature for both the systems. Surface characteristics of pine cone and base modified pine cone were investigated using Fourier transform infrared spectrophotometer and scanning electron microscope. Equilibrium data were best described by both Langmuir isotherm and Freundlich adsorption isotherm. The maximum monolayer adsorption capacity was found to be 129.87 mg g^?1 at solution pH of 9.02 for an initial dye concentration of 10 ppm by raw pine cone. The base modified pine cone showed the higher monolayer adsorption capacity of 142.25 mg g^?1 compared with raw pine cone biomass. The value of separation factor, R _L, from Langmuir equation and Freundlich constant, n, both give an indication of favourable adsorption. The various kinetic models, such as pseudo-first-order model, pseudo-second-order model, intraparticle diffusion model, double-exponential model, and liquid film diffusion model, were used to describe the kinetic and mechanism of adsorption process. Overall, kinetic studies showed that the dye adsorption process followed pseudo-second-order kinetics based on other models. The different kinetic parameters, including rate constant, half-adsorption time and diffusion coefficient, were determined at different physicochemical conditions. A single-stage bath adsorber design for the MB adsorption onto pine cone and modified pine cone has been presented based on the Langmuir isotherm model equation. Thermodynamic parameters, such as standard Gibbs free energy (ΔG ⁰), standard enthalpy (ΔH ⁰) and standard entropy (ΔS ⁰), were also calculated.     

Hydraulic significance of fracture correlated lineaments in precambrian rocks in Purulia district, West Bengal

Filter analysis of lineaments in Precambrian metamorphic rocks was used to delineate fracture-correlated lineaments and hydraulically significant fractures. The unfiltered analysis technique fails to show correlation between major lineaments and fractures. Domain-based and discrete filtering techniques successfully identify fracture-correlated lineaments within the brittle-ductile shear zone in conjunction with fractures characterized by high fracture frequencies (>10/m). The locales of hydraulically significant fractures can thus be assessed if the geological controls governing the spatial distribution of fracture frequencies are computed using structural domain approach. The concurrence of fracture-correlated lineaments and hydraulically significant fractures within the brittle-ductile shear zone is evident.     

Removal of Cadmium from Aqueous Solution Using Castor Seed Hull: A Kinetic and Equilibrium Study

The effects of various parameters such as initial concentration, adsorbent loading, pH, and contact time on kinetics and equilibrium of adsorption of Cd²⁺ metal ion from its aqueous solution by castor seed hull (CSH) and also by activated carbon have been investigated by batch adsorption experiments. The amount of adsorption increases with initial metal ion concentration, contact time, solution pH, and the loading of adsorbent for both the systems. Kinetic experiments indicate that adsorption of cadmium metal ion on both CSH and on activated carbon consists of three steps – a rapid adsorption of cadmium metal ion, a transition phase, and an almost flat plateau region. This has also been confirmed by the intraparticle diffusion model. The lumped kinetic results show that the cadmium adsorption process follows a pseudo‐second order rate law. The kinetic parameters including the rate constant are determined at different initial metal ion concentrations, pH, amount, and type of adsorbent, respectively. The Langmuir and Freundlich adsorption isotherm models are used to describe the experimental data. The Langmuir model yields a better correlation coefficient than the other model. A comparison of the monolayer adsorption capacity (q_m) of CSH, activated carbon, and several other reported adsorbents has been provided. The value of separation factor (R_L) calculated from the Langmuir equation also gives an indication of favorable adsorption of the metal ion. From comparative studies, it has been found that CSH is a potentially attractive adsorbent than commercial activated carbon for cadmium metal ion (Cd²⁺) removal.     

Water and sediment quality parameters in the Chalan Beel,the largest wetland of Bangladesh

A study was conducted to investigate the status of the water and sediment quality in the Chalan Beel——a major fresh water fish reservoir of the country for a period of one year from July 2007 to June 2008. The mean values of water quality parameters(depth: 214.73±152.22 cm, temperature 27.68±4.26℃, transparency 123±82 cm, p H 9.7±0.47, total alkalinity 137±42 mg/L, conductivity 307±147 μs/cm, total dissolved solids 183±89 mg/L, ammonia-N 0.27±0.39 mg/L, nitrate-N 0.09±0.07 mg/L, phosphate-P 2.01±2.53 mg/L) and sediment quality parameters(p H 7.21±0.35, organic matter 2.59±0.52%, total nitrogen 0.09±0.04%, available phosphorus 5.4±3.6 Meq./100 g and exchangeable potassium 0.43±0.14 Meq./100 g) were within the range recommended for most of the inland fishes of Bangladesh. Although the water and sediment quality parameters except ammonia and phosphate are in the suitable range, the overall results suggest that better management techniques should be practiced in order to overcome the declining trend of associated aquatic life(fauna and flora) of this important fresh water body of Bangladesh.     

Opportunities and challenges in rebuilding tornado-impacted Greensburg,Kansas as “stronger,better, and greener”

A May 2007 tornado destroyed 95% of aging, declining Greensburg, Kansas. The city took the opportunity to build back “stronger, better, and greener,” enforcing upgraded codes, requiring city-owned buildings to meet LEED Platinum level standards, and recommending energy-efficiency housing in a new Sustainable Comprehensive Plan. Using information collected from surveys of Greensburg tornado survivors, interviews, and publications, we examined the housing-related recovery, including the emergency provision of temporary shelter and rebuilding permanently. Although temporary shelter kept residents nearby for rebuilding, given the gap between insurance policy limits on the aging housing stock and rebuilding costs, housing affordability is a critical issue in Greensburg’s recovery. Local, state, and federal support have made construction of municipal buildings at LEED Platinum level and some affordable and green housing projects possible. However, far greater public and private sector funding for affordable workforce housing, in conjunction with broader economic and job development, is needed.     

Understanding of the biochemical events in a chemo-bioreactor during continuous acid mine drainage treatment

Spent mushroom compost (SMC) is widely used as reactor matrix in passive bioreactor involving sulfate reducing bacteria (SRB) for acid mine drainage (AMD) treatment. Follow-up our previous report, recent work has been established the extent of activity, sustained organic carbon availability, and the biochemical events of successive alkalinity producing system-based chemo-bioreactor for continuous performance using SMC. Removal of iron and sulfate from influent was over 77 and 90%, respectively, for first 13 weeks, while sulfate removal efficiency suddenly dropped down to 31% thereafter. Ahead of 13th week, process failure was beginning to be noticed when available dissolved organic carbon (DOC) value dropped down to 50 mg/L. SRB population was mostly affected with DOC drought at this stage. Sulfur was one of the major elements found with other tested metals in blackish green effluent precipitate. Sulfide compounds of the tested metals were formed on both exhausted chemo-bioreactor bed and precipitate. FTIR analysis indicated that SMC was responsible for metal binding and available nutrients supply. The present study revealed the feasibility of SMC as a host for treating AMD by this chemo-bioreactor that will assist in designing the continuous treatment practice.     

Linking Coastal Disasters and Migration: A Case Study of Kutubdia Island,Bangladesh

On 4 August 2012, the southeastern part of Kutubdia Island, Bangladesh, experienced coastal erosion and flooding associated with tidal waves, storms, and continuous heavy rainfall for two days. This provided a unique opportunity to study the relationship between rapid-onset disasters and migration decisions of individual households perpetually living under environmental risk. Using Kutubdia Island as a case study, this article examines the migration decisions of respondents in the immediate aftermath of two extreme natural events. Relevant data were primarily collected from a questionnaire survey conducted nearly two months after the occurrence of the event. The study's findings support the view that both environmental and nonenvironmental factors lead to migration. The article outlines several areas for further research on the links between migration and environmental stress.     

Factors Affecting Evacuation Behavior: The Case of 2007 Cyclone Sidr,Bangladesh

Cyclone Sidr, a Category 4 storm, struck the southwestern coast of Bangladesh on 15 November 2007. Despite early cyclone warnings and emergency evacuation orders for coastal residents, thousands of individuals stayed in their homes. This study examines Sidr victims’ responses to cyclone warnings and evacuation orders, and explores the factors that would explain why the victims did or did not comply with the orders. Based on survey data collected from 277 Sidr survivors living in the four most severely impacted coastal districts, this study found that more than 75 percent of all respondents were aware of the cyclone warnings and evacuation orders before Sidr's landfall. Despite the efforts of the Bangladesh government, there were lapses in cyclone warnings and evacuation procedures. Field data also reveal several reasons cited by respondents for not complying with evacuation orders. Multivariate analyses of survey data show that trust in warning messages was the most important determinant in the decision to seek refuge in safer shelters, followed by distance to nearest shelter and annual level of education. Several recommendations have been made to improve cyclone warnings and the use of public shelters for similar future events.