Hazardous Waste Pollution Prevention Using Clay with Admixtures

Landfill is the most commonly used method for disposal of waste materials since it is one of the least expensive methods. In order to dispose of any hazardous material to a landfill, a liner is used, which protects the underlying land and groundwater since it acts as a barrier to fluid movement. Of the various methods available for providing improved and more effective properties of landfills, methods involving the use of bentonite, cement, lime, gypsum, etc., have been explored in the laboratory. The aim is to overcome the problem and deficiencies of the existing liners. It is observed from the experimental results that the metal concentrations of the input waste solution can be reduced to 80–98% using a soil‐cement admixture, 60–95% using a soil‐gypsum mixture, 45–95% using a soil‐bentonite mixture, 50–90% for soil, 35–80% using a soil‐lime mixture, as liner materials. The permeation rate of different metals through the different soil‐admixture media depends on various factors. A simple mathematical treatment of the phenomenon related to the permeation of liquid through the admixture of the clay and other components has been developed. The experimental results show satisfactory agreement with the predictions.     

Skills of different mesoscale models over Indian region during monsoon season: Forecast errors

Performance of four mesoscale models namely, the MM5, ETA, RSM and WRF, run at NCMRWF for short range weather forecasting has been examined during monsoon-2006. Evaluation is carried out based upon comparisons between observations and day-1 and day-3 forecasts of wind, temperature, specific humidity, geopotential height, rainfall, systematic errors, root mean square errors and specific events like the monsoon depressions.It is very difficult to address the question of which model performs best over the Indian region? An honest answer is ‘none’. Perhaps an ensemble approach would be the best. However, if we must make a final verdict, it can be stated that in general, (i) the WRF is able to produce best All India rainfall prediction compared to observations in the day-1 forecast and, the MM5 is able to produce best All India rainfall forecasts in day-3, but ETA and RSM are able to depict the best distribution of rainfall maxima along the west coast of India, (ii) the MM5 is able to produce least RMSE of wind and geopotential fields at most of the time, and (iii) the RSM is able to produce least errors in the day-1 forecasts of the tracks, while the ETA model produces least errors in the day-3 forecasts.     

Paleoenvironment of deposition of the Dupi Tila Formation,Lalmai Hills,Comilla, Bangladesh

The Dupi Tila Formation is composed of yellow to light brown medium to very fine moderately hard to loose sandstone, siltstone, silty clay, mudstone and shale with some conglomerates with clasts of petrified wood. The lithofacies of matrix supported conglomerate, trough cross bedded conglomerate, massive sandstone, trough cross bedded sandstone, planar cross bedded sandstone, ripple cross laminated sandstone-siltstone, flaser laminated sandstone-shale, lenticular laminated sandstone-siltstone-shale, parallel laminated sandstone-siltstone, wavy laminated shale, parallel laminated blue shale, and mudstone are delineated within this formation. Based on the grain size, sedimentary structures, water depth and genesis of individual facies, facies are grouped into three types of facies associations like (i) coarse-grained conglomerate facies association in relation to tractive current deposits of alluvial fan set up at the base of litho-succession (FAC), (ii) medium to fine-grained sandstone-siltstone-mudstone facies association or facies association in relation to strong tide (FAT) characterizing the middle part of litho-succession, (iii) very fine-grained sandstone-siltstone-mudstone facies association in relation to less frequent weak tide or heterolithic facies association (FAHL) characterizing upper part of litho-succession and shallow marine facies association (FASM) composing the uppermost litho-succession. Presence of gluconite indicates that the depositional environment was shallow to deep marine. The dominant paleoflow direction during the deposition of Dupi Tila Formation was toward southeast to southwestern direction. The rivers were of braided type at the piedmont alluvial depositional set up at the lower part, which later changed to estuarine-tidal flat type environmental set up in the middle part to upper part and paleo-environment was shallow marine in the uppermost part.     

Post-Cyclone Sidr nutritional status of women and children in coastal Bangladesh: an empirical study

Cyclone Sidr, a Category 4 storm, struck the southwestern coast of Bangladesh on November 15, 2007, causing 3,406 deaths, 2.51 million acres of crop damage, and aggregated damage of US$1.7 billion. It significantly damaged household food availability and increased post-cyclone nutritional insecurity. This study assesses the nutritional status of household and explores influences of various socioeconomic variables on nutritional security. More specifically, it explores the impact of the cyclone on short-term nutritional status of women of reproductive age and children under 5?years. For this study, 331 households living in three villages devastated by Cyclone Sidr were selected. The nutritional status of women of reproductive age was measured based on body mass index, and that of children aged 6?C59?months was measured based on weight-for-height (wasting), height-for-age (stunting), and weight-for-age (underweight). This study found that the nutritional status, along with other household characteristics, of the study groups was not remarkably different across the three selected villages. Findings of this study further suggest that the nutritional security situation was not much changed in the post-cyclone period compared with the pre-cyclone period primarily because of rapid and effective distribution of essential food items among cyclone survivors by the government of Bangladesh along with donor and other organizations. However, nutritional insecurity was more prevalent in the island village relative to inland and coastline villages. Similarly, fishermen were found to be the most vulnerable to nutritional insecurity in the post-cyclone period. Several recommendations are made to improve food aid distribution in the aftermath of a cyclone.     

Exploring probable reasons for record fatalities: the case of 2011 Joplin, Missouri, Tornado

On the evening of 22 May 2011, an EF-5 tornado tore a path six miles long across Joplin, Missouri, USA, killing 162 people as it passed through the heart of the city. This tornado stands as the deadliest single tornado to hit the United States since modern recordkeeping began in 1950, surpassing the tornado of 8 June 1953 that claimed 116 lives in Flint, Michigan. The record number of deaths caused by the single tornado in Joplin was far higher than the average annual number of US tornado deaths over the last three decades. This study explores the reasons for the high number of fatalities caused by the 2011 Joplin tornado. Questionnaire surveys administered among tornado survivors and informal discussions with emergency management personnel and others suggest that five reasons are associated with the high number of tornado fatalities experienced in Joplin: (1) the sheer magnitude of this event; (2) its path through commercial and densely populated residential areas; (3) the relatively large size of damage area; (4) the physical characteristics of affected homes in Joplin; and (5) the fact that some residents ignored tornado warnings. Several recommendations are offered, the implementation of which should reduce future tornado fatalities not only in Joplin, but elsewhere in the United States.     

A unified earthquake catalogue for South Asia covering the period 1900–2014

Seismicity analysis is very much pertinent for Indian subcontinent and its adjoining region which is seismically active including many great earthquakes associated with collision and subduction tectonics in the northern, north-eastern part of the subcontinent and in the Andaman and Nicobar Island. An earthquake catalogue has been generated for South Asia covering the period 1900–2014 by compiling the records of earthquake occurrences from International Seismological Center, Global Centroid Moment Tensor (GCMT), US Geological Survey, India Meteorological Department and published literature. The uniform magnitude scaling in moment magnitude M _W,GCMT is achieved through connecting relationships between different magnitude types. These relationships are derived by orthogonal standard regression analysis on available data pairs. The derived relationships have been compared with the existing equations already reported by others. The catalogue is subsequently subjected to a seismicity declustering algorithm to identify the foreshocks, main-shocks and aftershocks. The catalogue thus compiled is envisaged to be a useful resource for seismotectonic and seismic hazard studies in the region.

     

Exploration of geothermal activity using time series analysis of subsurface gases data from Bakreswar hot springs area,eastern India

Geothermal power seems to be a potential source of green energy in India. But these renewable energy resources are still ignored in India even after having a lot of potential sources as seen in more than 300 hot springs scattered throughout different geothermal areas of the country. Many of them could be utilized for power generation using the earth’s internal heat. More hours are needed to explore these geothermal areas using geochemical, geophysical techniques, and statistical analysis to qualitatively estimate power harnessing capabilities and sustainability of the areas for generation of geothermal power. In the present paper, attention has been focused to investigate Bakreswar geothermal field of India by continuous (24*7) and online monitoring of terrestrial gases such as He and radioactive gases (²²²Rn) in hot spring emanations of the geothermal area for more than 5 years along with discrete measurement of some other geochemical and geophysical parameters. The discrete measures imply that the seven hot spring vents at the study area are linked to the aquifer through different ways covering non-uniform rock assemblies and ascertain the presence of high amount of radioactive minerals at the underneath terrains. Stable activities with a high-out flux of ²²²Rn and He for a prolonged time period is expected within the reservoir present at the study area as consequence of analysis of the temporal variations and statistical measures of the continuous data sets. Seasonal variation of time series data also recommends that the high amount of radioactive sources present at the crust of the reservoir is able to produce enough quantity of heat irrespective of meteorological effects. The investigation on the power spectra interferes that the geothermal system is still in quite active phase on the influence of tectonic activities. Therefore, the geothermal reservoir present at the Bakreswar geothermal area may be utilized as a constant and continuous heat source for a long time period to run a geothermal power plant.     

Atmospheric ionic species in PM2.5 and PM1 aerosols in the ambient air of eastern central India

This study elucidates the characteristics of ambient PM_2.5 (fine) and PM₁ (submicron) samples collected between July 2009 and June 2010 in Raipur, India, in terms of water soluble ions, i.e. Na⁺, NH ₄ ⁺ , K⁺, Mg²⁺, Ca²⁺, Cl^?, NO ₃ ^? and SO ₄ ^2? . The total number of PM_2.5 and PM₁ samples collected with eight stage cascade impactor was 120. Annual mean concentrations of PM_2.5 and PM₁ were 150.9?±?78.6 μg/m³ and 72.5?±?39.0 μg/m³, respectively. The higher particulate matter (PM) mass concentrations during the winter season are essentially due to the increase of biomass burning and temperature inversion. Out of above 8 ions, the most abundant ions were SO ₄ ^2? , NO ₃ ^? and NH ₄ ⁺ for both PM_2.5 and PM₁ aerosols; their average concentrations were 7.86?±?5.86 μg/m³, 3.12?±?2.63 μg/m³ and 1.94?±?1.28 μg/m³ for PM_2.5, and 5.61?±?3.79 μg/m³, 1.81?±?1.21 μg/m³ and 1.26?±?0.88 μg/m³ for PM₁, respectively. The major secondary species SO ₄ ^2? , NO ₃ ^? and NH ₄ ⁺ accounted for 5.81%, 1.88% and 1.40% of the total mass of PM_2.5 and 11.10%, 2.68%, and 2.48% of the total mass of PM₁, respectively. The source identification was conducted for the ionic species in PM_2.5 and PM₁ aerosols. The results are discussed by the way of correlations and principal component analysis. Spearman correlation indicated that Cl^? and K⁺ in PM_2.5 and PM₁ can be originated from similar type of sources. Principal component analysis reveals that there are two major sources (anthropogenic and natural such as soil derived particles) for PM_2.5 and PM₁ fractions.     

Determination of nitrogen dioxide in ambient air employing diffuse reflectance Fourier transform infrared spectroscopy

This paper presents the development of a simple and precise analytical method for the determination of nitrogen dioxide in ambient air. In this method nitrogen dioxide is determined in the form of nitrite. The determination of nitrogen dioxide needs no reagents except for a solution of sodium hydroxide mixed with sodium arsenite (NaOH–Na₂As₂O₃) which is used as an absorbing reagent for trapping the nitrogen dioxide from the atmosphere in the form of nitrite, i.e., a prior analysis step. The determination of submicrogram levels of nitrogen dioxide is based on the selection of a strong and sharp quantitative analytical peak at 1380 cm^− 1 using diffuse reflectance infrared spectroscopy (DRS-FTIR). The limit of detection (LOD) and the limit of quantification of the method are found to be 0.008 μg g^− 1 NO₂⁻ and 0.05 μg g^− 1 NO₂⁻, respectively. The precision in terms of standard deviation and relative standard deviation value at a level of 2 μg NO₂⁻ / 0.1 g KBr for n = 10 is found to be 0.036 μg NO₂⁻ and 1.8%, respectively. The relative standard deviation (n = 10) for the determination of nitrogen dioxide in ambient air was observed to be in the range 2.6–3.8%. The method proposed is time-saving and eliminates the slow and cumbersome steps of pH maintenance of the reaction mixture and color formation of the EPA recommended spectrophotometric and other methods for quantitative determination of nitrogen dioxide.