Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

Evolution of disk galaxies regulated by supernova remnants

Assuming that a disk galaxy is composed of an ambient pervasive gas, small clouds, molecular clouds and stars, its evolution is studied through examining the interchange processes among them. Main results obtained are: (1) The star formation rate is directed by the formation process of molecular clouds. (2) Depending upon the parameters there may be three or four types of evolution of disk galaxies: the no star formation case, the active in the past and inactive at present star formation case, the burst-like star formation case and the very active in star formation case.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan between 30 September–6 October, 1984.     

The paleobiogeographical significance of the Silurian and Devonian trilobites of Japan

Six major groups of trilobites from the Silurian and Devonian of Japan are evaluated for their paleobiogeographical signature. Silurian illaenids and scutelluids show four generic‐level and at least two species‐level links with the Australian segment of the Gondwana paleocontinent; encrinurids also indicate two generic‐level links with Australia and also the South China paleocontinent; whilst Devonian phacopids, and possibly proetids, suggest at least two generic‐level links with the North China paleocontinent. These different patterns may reflect the fragmentary biostratigraphical record of Japanese trilobites, but they also appear to reflect paleoenvironmental parameters associated with lithofacies, and paleoecology. Thus, Japanese assemblages of proetids and phacopids occurring in deep‐water clastic lithofacies have counterparts in similar settings in North China, and Japanese scutelluids and illaenids are strongly associated with shallow marine carbonate lithofacies that are similar to those of their occurrences in Australia. Japanese encrinurids occur in carbonate rocks indicative of shallow marine settings in the Kurosegawa Terrane, and they demonstrate a consistent paleobiogeographical affinity with Australia and South China. Larval ecology cannot be directly assessed for Japanese trilobite groups. However, proetids have consistently been shown to have planktonic protaspides, whereas illaenids, scutelluids, and encrinurids have benthic protaspides. Planktonic protaspides would have a greater propensity for distribution in ocean currents than benthic ones, and therefore may be of more limited paleobiogeographical utility. The combined data from the six different groups indicates that the complex paleobiogeographical patterns of the Japanese trilobite assemblages need to be interpreted with caution, and similarity of taxa does not necessarily denote paleogeographical proximity to other regions.     

Non-equilibrium Condensation ina Primordial Solar Nebula: Formation of Refractory Metal Nuggets

We present a theoretical investigation of non-equilibrium condensation of refractory metalsinthe primordial solar nebula, in relation to the origin of “Fremdlinges” included inCAIs. Todescribe the nucleation process of grains from vapor, weadopted asemi-phenomenological modelmodified fromthe classical nucleation theoryby the introductionof the second virial coefficient of vapor. This modelachieves excellent agreement with nucleation rate experiment. However,the second virial coefficients are unknown for a vapor of refractory metals. To overcome this, weexpress the nucleation rate by theuse of the chemical potential of dimersinsteadof the second virial coefficient.On the basis of this new nucleation theory,we have performed numerical simulations ofnon-equilibrium condensation of refractory metals andfind thattheircondensation temperatures, T_c, decrease considerably in comparison withequilibrium condensation. Even if the characteristiccooling time scale is aslarge as 1×10⁵ years, the decrease in T_c isfrom 200 to 400 Kfor rare elements such as W, Re,and Os. This remarkablenon-equilibrium behaviormainly stemsfromthelow totalpressure in the primordial solar nebula. From our new modelwealso obtainthe typical size ofgrainsformed in condensation. We findthatthe cooling time should be ?1×10⁵ years for sub-micron-sized or largerrefractory metal nuggetsto form.     

Radiative Shock Experiments At Luli

We present the set-up and the results of a supercritical radiative shock experiment performed with the LULI nanosecond laser facility. Using specific designed targets filled with xenon gaz at low pressure, the propagation of a strong shock with a radiative precursor is evidenced. The main measured quantities related to the shock (electronic density, propagation velocities, temperature, radial dimension) are presented and compared with various numerical simulations.     

An oscillator model for stellar variability

The dependence of coupling constants in a coupled oscillator model is examined with simplified methods. The Lyapunov exponents are preliminary introduced for the model. The behaviors of oscillator model are examined in a parameter plane. So-called the Arnold's tongues for phase-locking states are observed in fractal patterns.     

Preparation of fine particles of astrophysical interest by gas evaporation techniques

Fine particles of various chemical substances—carbon, iron, iron oxide and silica—which are expected to exist in interstellar space are prepared in argon gas. The size, shape, and crystal structure of the powder particles are studied by electron microscopy and electron diffraction, and may have some bearing on models of comets and of the solar nebula.The largest size we have obtained is about 0.1 μm and the smallest about 40Å. Generally the size becomes smaller for lower temperature and also for lower pressure. This tendency is discussed in connection with nucleation theories. Except for iron and iron oxide the powder particles have no crystal structure.