An assessment of geologic sequestration potential in the panhandle of Florida USA

One alternative to reduce global greenhouse gas emissions is to store the emissions in underground geologic sequestration repositories. The efficacy of this approach has been favorably evaluated by numerous authors over the last 15 years. This paper discusses an assessment of the overall feasibility of storing emissions in three different repositories in the Florida panhandle located in the Southeastern United States. The feasibility assessment evaluates both saline aquifers and oil reservoirs located in the panhandle region. The overall feasibility is driven by the available geologic sequestration capacity, the transportation cost to deliver emissions to a respective repository, and other engineering and regulatory issues. The geologic sequestration capacity is generally controlled by the so-called storage efficiency, a variable dependent on the site-specific geology, reservoir conditions, and the injected fluid characteristics. For this paper, storage efficiency for saline repositories was assessed in more detail using numerical modeling. Based on the work completed, the 3 repositories studied have at least 4.55 gigatonnes of capacity to sequester CO₂.     

Some evidence of climate change in twentieth-century India

The study of climate changes in India and search for robust evidences are issues of concern specially when it is known that poor people are very vulnerable to climate changes. Due to the vast size of India and its complex geography, climate in this part of the globe has large spatial and temporal variations. Important weather events affecting India are floods and droughts, monsoon depressions and cyclones, heat waves, cold waves, prolonged fog and snowfall. Results of this comprehensive study based on observed data and model reanalyzed fields indicate that in the last century, the atmospheric surface temperature in India has enhanced by about 1 and 1.1°C during winter and post-monsoon months respectively. Also decrease in the minimum temperature during summer monsoon and its increase during post-monsoon months have created a large difference of about 0.8°C in the seasonal temperature anomalies which may bring about seasonal asymmetry and hence changes in atmospheric circulation. Opposite phases of increase and decrease in the minimum temperatures in the southern and northern regions of India respectively have been noticed in the interannual variability. In north India, the minimum temperature shows sharp decrease of its magnitude between 1955 and 1972 and then sharp increase till date. But in south India, the minimum temperature has a steady increase. The sea surface temperatures (SST) of Arabian Sea and Bay of Bengal also show increasing trend. Observations indicate occurrence of more extreme temperature events in the east coast of India in the recent past. During summer monsoon months, there is a decreasing (increasing) trend in the frequency of depressions (low pressure areas). In the last century the frequency of occurrence of cyclonic storms shows increasing trend in the month of November. In addition there is increase in the number of severe cyclonic storms crossing Indian Coast. Analysis of rainfall amount during different seasons indicate decreasing tendency in the summer monsoon rainfall over Indian landmass and increasing trend in the rainfall during pre-monsoon and post-monsoon months.     

Suitable gravity interpolation technique for large data gaps in Africa

Studia Geophysica et Geodaetica - The gravity database for the IAG African Geoid Project contains significantly large data gaps. These large data gaps affect the interpolation precision of the...     

Site effect on vulnerability of high-rise shear wall buildings under near and far field earthquakes

Worldwide experience repeatedly shows that damages in structures caused by earthquakes are highly dependent on site condition and epicentral distance. In this paper, a 21-storey shear wall-structure built in the 1960s in Hong Kong is selected as an example to investigate these two effects. Under various design earthquake intensities and for various site conditions, the fragility curves or damage probability matrix of such building is quantified in terms of the ductility factor, which is estimated from the ratio of storey yield shear to the inter-storey seismic shear. For high-rise buildings, a higher probability of damage is obtained for a softer site condition, and damage is more severe for far field earthquakes than for near field earthquakes. For earthquake intensity of VIII, the probability of complete collapse (P) increases from 1 to 24% for near field earthquakes and from 1 to 41% for far field earthquakes if the building is moved form a rock site to a site consisting a 80 m thick soft clay. For intensity IX, P increases from 6 to 69% for near field earthquake and from 14 to 79% for far field earthquake if the building is again moved form rock site to soft soil site. Therefore, site effect is very important and not to be neglected. Similar site and epicentral effects should also be expected for other types of high-rise structures.     

Searches for very high energy gamma rays from blazars with CANGAROO-III telescope in 2005-2009

We have searched for very high energy (VHE) gamma rays from four blazars using the CANGAROO-III imaging atmospheric Cherenkov telescope. We report the results of the observations of H 2356-309, PKS 2155-304, PKS 0537-441, and 3C 279, performed from 2005 to 2009, applying a new analysis to suppress the effects of the position dependence of Cherenkov images in the field of view. No significant VHE gamma ray emission was detected from any of the four blazars. The GeV gamma-ray spectra of these objects were obtained by analyzing Fermi/LAT archival data. Wide range (radio to VHE gamma-ray bands) spectral energy distributions (SEDs) including CANGAROO-III upper limits, GeV gamma-ray spectra, and archival data, even though they are non-simultaneous, are discussed using a one-zone synchrotron self-Compton (SSC) model in combination with a external Compton (EC) radiation. The HBLs (H 2356-309 and PKS 2155-304) can be explained by a simple SSC model, and PKS 0537-441 and 3C 279 are well modeled by a combination of SSC and EC model. We find a consistency with the blazar sequence in terms of strength of magnetic field and component size.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain

Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss.     

Energetic protons from the solar flare of March 24, 1966

Ten to 100 meV protons from the solar flare of March 24, 1966 were observed on the University of California scintillation counter on OGO-I. The short rise and decay times observed in the count rates of the 32 channels of pulse-height analysis show that scattering of the protons by the interplanetary field was much less important in this event than in previously observed proton flares. A diffusion theory in which D = M _r is found to be inadequate to account for the time behavior of the count rates of this event. Small fluctuations of the otherwise smooth decay phase may be due to flare protons reflected from the back of a shock front, which passed the earth on March 23.     

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.