Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

Characterizing rainfall–groundwater dynamics in a hard‐rock aquifer system using time series,geographic information system and geostatistical modelling

The aim of this study was to investigate rainfall–groundwater dynamics over space and annual time scales in a hard‐rock aquifer system of India by employing time series, geographic information system and geostatistical modelling techniques. Trends in 43‐year (1965–2007) annual rainfall time series of ten rainfall stations and 16‐year (1991–2006) pre‐monsoon and post‐monsoon groundwater levels of 140 sites were identified by using Mann–Kendall, Spearman rank order correlation and Kendall rank correlation tests. Trends were quantified by Kendall slope method. Furthermore, the study involves novelty of examining homogeneity of pre‐monsoon and post‐monsoon groundwater levels, for the first time, by applying seven tests. Regression analysis between rainfall and post‐monsoon groundwater levels was performed. The pre‐monsoon and post‐monsoon groundwater levels for four periods – 1991–1994, 1995–1998, 1999–2002 and 2003–2006 – were subjected to geographic information system‐based geostatistical modelling. The rainfall showed considerable spatiotemporal variations, with a declining trend at the Mavli rainfall station (p‐value < 0.05). The Levene's tests revealed spatial homogeneity of rainfall at α = 0.05. Regression analyses indicated significant relationships (r² > 0.5) between groundwater level and rainfall for eight rainfall stations. Non‐homogeneity and declining trends in the groundwater level, attributed to anthropogenic and hydrologic factors, were found at 5–61 more sites in pre‐monsoon compared with post‐monsoon season. The groundwater declining rates in phyllite–schist, gneiss, schist and granite formations were found to be 0.18, 0.26, 0.21 and 0.14 m year^?1 and 0.13, 0.19, 0.16 and 0.02 m year^?1 during the pre‐monsoon and post‐monsoon seasons, respectively. The geostatistical analyses for four time periods revealed linkages between the rainfall and groundwater levels. Copyright © 2013 John Wiley & Sons, Ltd.     

A new bounding surface model for thermal cyclic behaviour

To accurately predict soil volume changes under thermal cycles is of great importance for analysing the performance of many earth structures such as the energy pile and energy storage system. Most of the existing thermo‐mechanical models focus on soil behaviour under monotonic thermal loading only, and they are not able to capture soil volume changes under thermal cycles. In this study, a constitutive model is proposed to simulate volume changes of saturated soil subjected to cyclic heating and cooling. Two surfaces are defined and used: a bounding surface and a memory surface. The bounding surface and memory surface are mainly controlled by the preconsolidation pressure (a function of plastic volumetric strain) and the maximum stress experienced by the soil, respectively. Under thermal cycles, the distance of the two surfaces and plastic modulus increase with an accumulation of plastic strain. By adopting the double surface concept, a new elastoplastic model is derived from an existing single bounding surface thermo‐mechanical model. Comparisons between model predictions and experimental results reveal that the proposed model is able to capture soil volume changes under thermal cycles well. The plastic strain accumulates under thermal cycles, but at a decreasing rate, until stabilization. Copyright © 2017 John Wiley & Sons, Ltd.     

Effects of forest roads on the hydrological response of a small‐scale mountain watershed in Greece

The effects of land use changes on the ecology and hydrology of natural watersheds have long been debated. However, less attention has been given to the hydrological effects of forest roads. Although less studied, several researchers have claimed that streamflow changes related to forest roads can cause a persistent and pervasive effect on hillslope hydrology and the functioning of the channel system. The main potential direct effects of forest roads on natural watersheds hydrologic response are runoff production on roads surfaces due to reduced infiltration rates, interruption of subsurface flow by road cutslopes and rapid transfer of the produced runoff to the stream network through roadside ditches. The aforementioned effects may significantly modify the total volume and timing of the hillslope flow to the stream network. This study uses detailed field data, spatial data, hydro‐meteorological records, as well as numerical simulation to investigate the effects of forest roads on the hydrological response of a small‐scale mountain experimental watershed, which is situated in the east side of Penteli Mountain, Attica, Greece. The results of this study highlight the possible effects of forest roads on the watersheds hydrological response that may significantly influence direct runoff depths and peak flow rates. It is demonstrated that these effects can be very important in permeable watersheds and that more emphasis should be given on the impact of roads on the watersheds hydrological response. Copyright © 2014 John Wiley & Sons, Ltd.